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1.
J. B. Harcum Jim C. Loftis Robert C. Ward 《Journal of the American Water Resources Association》1992,28(3):469-478
ABSTRACT: The use of nonparametric tests for monotonic trend has flourished in recent years to support routine water quality data analyses. The validity of an assumption of independent, identically distributed error terms is an important concern in selecting the appropriate nonparametric test, as is the presence of missing values. Decision rules are needed for choosing between alternative tests and for deciding whether and how to pre-process data before trend testing. Several data pre-processing procedures in conjunction with the Mann-Kendall tau and the Seasonal Kendall test (with and without serial correlation correction) are evaluated using synthetic time series with generated serial correlation and missing data. A composite test (pre-testing for serial correlation followed by one of two trend tests) is evaluated and was found to perform satisfactorily. 相似文献
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María L. Pignata Martha S. Cañas Hebe A. Carreras Liliana Orellana 《Environmental management》1997,21(5):793-801
Ligustrum lucidum Ait. f. tricolor (Rehd.) Rehd. in relation to atmospheric pollutants in Córdoba city, Argentina. The study area receives
regional pollutants and was categorized taking into account traffic level, industrial density, type of industry, location
of the sample point in relation to the street corner, treeless condition, and topographic level. Dried weight/fresh weight
ratio (DW/FW) and specific leaf area (SLA) were calculated, and concentrations of chlorophylls, carotenoids, total sulfur,
soluble proteins, malondialdehyde (MDA), and hydroperoxy conjugated dienes (HPCD) were determined in leaf samples. Sulfur
content correlates positively with traffic density and SLA correlates negatively with some combinations of the categorical
variables; MDA correlates positively with topographic level and total protein concentration correlates negatively with treeless
condition. On the basis of our results, traffic, location of trees, type of industry, situation of a tree with respect to
others, and topographic level are the environmental variables to bear in mind when selecting analogous sampling points in
a passive monitoring program. An approximation to predict tree injury may be obtained by measuring DW/FW ratio, proteins,
pigments, HPCD, and MDA as they are responsible for the major variability of data. 相似文献
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Danny Reible David Lampert David Constant Robert D. Mutch Jr. Yuewei Zhu 《补救:环境净化治理成本、技术与工艺杂志》2006,17(1):39-53
An active capping demonstration project in Washington, D.C., is testing the ability to place sequestering agents on contaminated sediments using conventional equipment and evaluating their subsequent effectiveness relative to conventional passive sand sediment caps. Selected active capping materials include: (1) AquaBlokTM, a clay material for permeability control; (2) apatite, a phosphate mineral for metals control; (3) coke, an organic sequestration agent; and (4) sand material for a control cap. All of the materials, except coke, were placed in 8,000‐ft test plots by a conventional clamshell method during March and April 2004. Coke was placed as a 1.25‐cm layer in a laminated mat due to concerns related to settling of the material. Postcap sampling and analysis were conducted during the first, sixth, and eighteenth months after placement. Although postcap sampling is expected to continue for at least an additional 24 months, this article summarizes the results of the demonstration project and postcap sampling efforts up to 18 months. Conventional clamshell placement was found to be effective for placing relatively thin (six‐inch) layers of active material. The viability of placing high‐value or difficult‐to‐place material in a controlled manner was successfully demonstrated with the laminated mat. Postcap monitoring indicates that all cap materials effectively isolated contaminants, but it is not yet possible to differentiate between conventional sand and active cap layer performance. Monitoring of the permeability control layer indicated effective reductions in groundwater seepage rates through the cap, but also showed the potential for gas accumulation and irregular release. All of the cap materials show deposition of new contaminated sediment onto the surface of the caps, illustrating the importance of source control in maintaining sediment quality. © 2006 Wiley Periodicals, Inc. 相似文献
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Garey A. Fox George J. Sabbagh Robert W. Malone Ken Rojas 《Journal of the American Water Resources Association》2007,43(6):1359-1372
Abstract: Few studies exist that evaluate or apply pesticide transport models based on measured parent and metabolite concentrations in fields with subsurface drainage. Furthermore, recent research suggests pesticide transport through exceedingly efficient direct connections, which occur when macropores are hydrologically connected to subsurface drains, but this connectivity has been simulated at only one field site in Allen County, Indiana. This research evaluates the Root Zone Water Quality Model (RZWQM) in simulating the transport of a parent compound and its metabolite at two subsurface drained field sites. Previous research used one of the field sites to test the original modification of the RZWQM to simulate directly connected macropores for bromide and the parent compound, but not for the metabolite. This research will evaluate RZWQM for parent/metabolite transformation and transport at this first field site, along with evaluating the model at an additional field site to evaluate whether the parameters for direct connectivity are transferable and whether model performance is consistent for the two field sites with unique soil, hydrologic, and environmental conditions. Isoxaflutole, the active ingredient in BALANCE® herbicide, was applied to both fields. Isoxaflutole rapidly degrades into a metabolite (RPA 202248). This research used calibrated RZWQM models for each field based on observed subsurface drain flow and/or edge of field conservative tracer concentrations in subsurface flow. The calibrated models for both field sites required a portion (approximately 2% but this fraction may require calibration) of the available water and chemical in macropore flow to be routed directly into the subsurface drains to simulate peak concentrations in edge of field subsurface drain flow shortly after chemical applications. Confirming the results from the first field site, the existing modification for directly connected macropores continually failed to predict pesticide concentrations on the recession limbs of drainage hydrographs, suggesting that the current strategy only partially accounts for direct connectivity. Thirty‐year distributions of annual mass (drainage) loss of parent and metabolite in terms of percent of isoxaflutole applied suggested annual simulated percent losses of parent and metabolite (3.04 and 1.31%) no greater in drainage than losses in runoff on nondrained fields as reported in the literature. 相似文献
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Summary The leaf gland volatile oils of ten sweet gale plants from a Scottish population were extracted in early summer. The results differed notably from reports of other populations in respect of the sesquiterpenes, -elemenone and germacrone, which were major components of the volatile oil. Three dihydrochalcones were also detected in the volatile oil. Variation within the population existed, particularly with respect to the relative importance of germacrone. Five plants were resampled in late summer and exhibited a marked reduction in -elemenone, a lesser reduction in germacrone and changes in the proportions of some monoterpenes. 相似文献
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Pickson Robert Becker He Ge Boateng Elliot 《Environment, Development and Sustainability》2022,24(3):3907-3925
Environment, Development and Sustainability - This study examined the effects of climate change on rice production in 30 Chinese provinces spanning 1998–2017. The study used the pooled mean... 相似文献