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Boqiang Cui Yin Liu Jinwen Bai Xianjie Du Changxiang Wang 《International Journal of Green Energy》2020,17(12):730-741
ABSTRACT In order to study the effect of fly ash content in cemented paste backfill (CPB) on its anti-sulfate erosion, the apparent phenomenon, strength development, and hydration products change the law of CPB with different fly ash content under long-term soaking of 5% sodium sulfate solution were studied by the macrotest and microanalysis, in addition, the mechanism of CPB anti-sulfate attack was analyzed by combining with a scanning electron microscope (SEM). The results indicated that the effect of sulfate environment on the strength of fly ash cemented paste backfill (FCPB) was mainly determined by the hydration products in the FCPB at different soaking times. In the early soaking stage, the formation of ettringite (AFt) in FCPB could improve its compactness, which was conducive to improving the strength of FCPB. In the late soaking stage, there were ettringite-type erosion damage and gypsum erosion-type damage internal of the FCPB with low content fly ash, resulting in microfracture, cracking of the FCPB, and reducing the strength. CPB with an appropriate content of fly ash could improve the internal structure of the FCPB to achieve the purpose of anti-sulfate erosion. 相似文献
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基于移民、牧民访谈和问卷调查,对青海三江源泽库县生态移民的生活情况进行调查,分析移民对草地资源依赖性变化,以了解生态移民政策的成效与不足,并探讨现有政策中存在的相关问题,对三江源生态补偿政策和制度的制定完善提供参考和研究基础。研究结果显示:生态移民家庭经济收入有所提高,畜牧业收入占家庭总收入比例下降,生态补偿、务工、经商对于家庭收入的作用已明显显现。移民家庭从事畜牧业降为20.1%,务工家庭增加到37%,30.5%的移民参加过技能培训,但能源使用经济负担有所增加。53.90%的牧民愿意移民,但对移民后就业及生活设施建设仍有较大顾虑。总体而言,生态移民生活整体情况有所改观,移民后草地资源不再是家庭主要收入的基础。政府应完善技能培训体系,加快后续产业培育,重视生态移民工程前期规划,加大生态补偿资金支持力度。 相似文献
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生态文明是继农业、工业文明之后,适应新形势而提出的.以直接解决与人类生存相关的生态问题为己任,用于指引人们实现可持续发展为目标.在内蒙古地区,草原是最具内蒙古特色和开发价值的资源,然而在近几十年的开发中严重违反了生态文明理念,以致出现草场退化、生物生存危机等状况.在当前内蒙古草原出现的严重问题的情况下,很有必要去探寻生态文明理念的重要价值.结合中国传统文化中天时地利人和的重要思想,实现在“因时制宜、因地制宜、以人为本及各方因素协调共促”理念下新的草原开发. 相似文献
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ZnBiYO4 was synthesized by a solid-state reaction method for the first time. The structural and photocatalytic properties of ZnBiYO4 were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy and UV-Vis diffuse reflectance. ZnBiYO4 crystallized with a tetragonal spinel structure with space group I41/A. The lattice parameters for ZnBiYO4 were a = b = 11.176479 Å and c= 10.014323 Å. The band gap of ZnBiYO4 was estimated to be 1.58 eV. The photocatalytic activity of ZnBiYO4 was assessed by photodegradation of methyl orange under visible light irradiation. The results showed that ZnBiYO4 had higher catalytic activity compared with N-doped TiO2 under the same experimental conditions using visible light irradiation. The photocatalytic degradation of methyl orange with ZnBiYO4 or N-doped TiO2 as catalyst followed first-order reaction kinetics, and the first-order rate constant was 0.01575 and 0.00416 min-1 for ZnBiYO4 and N-doped TiO2, respectively. After visible light irradiation for 220 min with ZnBiYO4 as catalyst, complete removal and mineralization of methyl orange were observed. The reduction of total organic carbon, formation of inorganic products, SO42- and NO3-, and evolution of CO2 revealed the continuous mineralization of methyl orange during the photocatalytic process. The intermediate products were identified using liquid chromatography- mass spectrometry. The ZnBiYO4/(visible light) photocatalysis system was found to be suitable for textile industry wastewater treatment and could be used to solve other environmental chemical pollution problems. 相似文献
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A 1-dodecanethiol-based phase-transfer protocol is developed for the extraction of noble metal ions from aqueous solution to a hydrocarbon phase, which calls for first mixing the aqueous metal ion solution with an ethanolic solution of 1-dodecanethiol, and then extracting the coordination compounds formed between noble metal ions and 1-dodecanethiol into a non-polar organic solvent. A number of characterization techniques, including inductively coupled plasma atomic emission spectroscopy, Fourier transform infrared spectroscopy, and thermogravimetric analysis demonstrate that this protocol could be applied to extract a wide variety of noble metal ions from water to dichloromethane with an efficiency of >96%, and has high selectivity for the separation of the noble metal ions from other transition metals. It is therefore an attractive alternative for the extraction of noble metals from water, soil, or waste printed circuit boards. 相似文献
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采用聚合硫酸铁作为化学调理剂,对浓缩池污泥进行调理.以污泥比阻为主要指标考察了投药量、调理剂浓度、pH值和搅拌强度对污泥过滤脱水性能的影响;同时,考察了污泥经过沉降后上清液的浊度变化.调理实验结果表明,PFS的适宜调理参数为:投加量1mL,浓度6%,pH为7(未调节),快速搅拌速度120 rpm,慢速搅拌速度50 rpm.污泥经PFS调理后,比阻降低到1.56×10-14 m/kg,显然,调理剂影响污泥调理脱水效果和它们的种类、浓度和投加量等条件相关. 相似文献
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针对污水处理过程中存在的难降解有机物问题,介绍了芬顿的概念和特点,探讨了均相芬顿氧化在原位产生芬顿试剂的机理及应用.目前均相芬顿氧化技术总体可归纳为超声-芬顿氧化技术、微波-芬顿氧化技术、光-芬顿氧化技术、电-芬顿氧化技术.这些技术的应用能促进有机物的降解,提高芬顿技术的处理效率.通过介绍芬顿氧化技术降解废水中污染物的机理,综述了均相芬顿氧化技术在废水处理中的应用,分析了各种方法的适用范围和优缺点. 相似文献