粉末活性炭吸附工艺处理苯酚污染水试验

采用含苯酚的试验水样模拟城市取水水源发生苯酚水污染事故,测定粉末活性炭(PAC)对水样中苯酚的吸附性能,考察PAC炭种、吸附时间、苯酚初始浓度和PAC投加量等因素对苯酚的吸附量和脱除率的影响。试验结果表明:应急处理一般的苯酚水污染事故,PAC吸附苯酚的最佳条件为:吸附时间60 min,PAC投加量为80～100 mg.L-1;PAC对苯酚的吸附过程符合Langmuir等温式。     

Fate of microplastics in a coastal wastewater treatment plant: Microfibers could partially break through the integrated membrane system

• Fate of microplastics in integrated membrane system for water reuse was investigated. • Integrated membrane system has high removal efficiency (>98%) for microplastics. • Microplastics (>93%) were mainly removed through membrane bioreactor treatment. • Small scale fiber plastics (<200 μm) could break through reverse osmosis (RO) system. • The flux of microplastics maintained at 2.7 × 10¹¹ MPs/d after the RO treatment. Rare information on the fate of microplastics in the integrated membrane system (IMS) system in full-scale wastewater treatment plant was available. The fate of microplastics in IMS in a coastal reclaimed water plant was investigated. The removal rate of microplastics in the IMS system reached 93.2% after membrane bioreactor (MBR) treatment while that further increased to 98.0% after the reverse osmosis (RO) membrane process. The flux of microplastics in MBR effluent was reduced from 1.5 × 10¹³ MPs/d to 10.2 × 10¹¹ MPs/d while that of the RO treatment decreased to 2.7 × 10¹¹ MPs/d. Small scale fiber plastics (<200 μm) could break through RO system according to the size distribution analysis. The application of the IMS system in the reclaimed water plant could prevent most of the microplastics from being discharged in the coastal water. These findings suggested that the IMS system was more efficient than conventional activated sludge system (CAS) for the removal of microplastics, while the discharge of small scale fiber plastics through the IMS system should also not be neglected because small scale fiber plastics (<200 μm) could break through IMS system equipped with the RO system.     

Removal of steroid hormones from mariculture system using seaweed Caulerpa lentillifera

•Steroid hormones could be removed efficiently from mariculture system using seaweed; • Caulerpa lentillifera was the most efficient seaweed for removal of steroid hormones; • More than 90% of E₂ or EE₂ were removed within 12 h using Caulerpa lentillifera; • The removal included the rapid biosorption and the slow bio-accumulation; •The hormones and nutrients in mariculture wastewater could be simultaneously removed. The removal of steroid hormones from the mariculture system using seaweeds (Caulerpa lentillifera, Ulva pertusa, Gracilaria lemaneiformis, and Codium fragile) was investigated. The results illustrated that both 17β-estradiol (E₂) and 17α-ethinylestradiol (EE₂) could be removed by the seaweeds at different levels, and the Caulerpa lentillifera was the most efficient one. More than 90% of E₂ or EE₂ at concentration of 10 μg/L was removed by Caulerpa lentillifera within 12 h. Processes including initial quick biosorption, the following slow accumulation, and biodegradation might explain the removal mechanisms of E₂/EE₂ by Caulerpa lentillifera. E₂/EE₂ removal was positively related to the nutrient level and the initial concentration of steroid hormone. A significant linear relationship for E₂ and EE₂ existed between the initial pollutant concentration and the average removal rate. The highest removal kinetic constant (k) value was obtained at 30°C as 0.34 /h for E₂ and at 20°C as 0.28 /h for EE₂, demonstrating the promising application potential of Caulerpa lentillifera in the water purification of the industrialized mariculture system with relatively high water temperature. Simultaneous and efficient removal of E₂ and EE₂ by Caulerpa lentillifera was still achieved after 3 cycles in the pilot-scale experiment. The steroid hormones and nutrients in mariculture wastewater could also be simultaneously removed using Caulerpa lentillifera. These findings demonstrated that Caulerpa lentillifera was the promising seaweed for the removal of steroid hormones in mariculture systems.     

Effects of phosphorus-containing material application on soil cadmium bioavailability: a meta-analysis

Environmental Science and Pollution Research - Diverse phosphorus-containing materials (PCMs) were widely applied in remediation of cadmium-contaminated soils, and their effects on the change of...     

Enhanced photocatalytic activity of Cu2O for visible light-driven dye degradation by carbon quantum dots

Environmental Science and Pollution Research - Cuprous oxide (Cu2O), a p-type semiconductor material, plays an important role in photocatalysis, which has narrower band gap (~2.1 eV), abundant...     

Urinary concentrations of polycyclic aromatic hydrocarbon and phthalate metabolite mixtures in relation to semen quality among men attending an infertility clinic

Environmental Science and Pollution Research - Previous studies have reported that exposure to phthalates and polycyclic aromatic hydrocarbons (PAHs) is individually associated with altered semen...     

Investigation on oxygen-controlled sewage sludge carbonization with low temperature: from thermal behavior to three-phase product properties

Environmental Science and Pollution Research - A comprehensive study was conducted on the characteristics of oxygen-controlled carbonization process of sewage sludge (SS) using thermogravimetric...     

臭氧前驱体物监测用氮气中多组分VOCs气体标准物质的研制

介绍了瓶装1μmol/mol臭氧前驱体物监测用氮气中57组分挥发性有机物(VOCs)气体标准物质的研制过程,该气体标准物质严格按照《气体分析 校准用混合气体的制备 第1部分:称量法制备一级混合气体》(GB/T 5274.1-2018)所规定的配制气体标准物质的方法采用称量法制备。建立了GC-MS联用结合选择离子扫描(SIM)的分析方法,研究了目标化合物在气瓶中的均匀性和稳定性。57种目标化合物完全满足美国环保署光化学评估监测站(PAMS)关于臭氧前驱体物VOCs在线监测的技术要求。将气体标准物质分别送至中国环境监测总站和英国国家物理实验室(NPL)进行比对分析,结果良好,表明研制的气体标准物质具有较好的压力均匀性和稳定性,符合使用要求。相对扩展不确定度为5%(k=2),使用有效期为1年,取得国家二级标准物质证书,证书编号为GBW(E)083966。     

Epichlorohydrin Crosslinked 2,4-Dihydroxybenzaldehyde Schiff Base Chitosan@SrFe12O19 (EP-DBSB-CS@SrFe12O19) Magnetic Nanocomposite for Efficient Removal of Pb(II) and Cd(II) from Aqueous Solution

Journal of Polymers and the Environment - In this paper, new epichlorohydrin crosslinked 2,4-dihydroxybenzaldehyde Schiff base chitosan@SrFe12O19 magnetic nanocomposite (EP-DBSB-CS@SrFe12O19) was...     

Population dynamics of farmland ladybug resources and dominant species in Nyingchi,Tibet, China北大核心CSCD

捕食性瓢虫是重要的天敌昆虫,有利于害虫的生物防治.为查清西藏林芝地区农田瓢虫资源与种群现状,明确优势种类及种群动态和规律,对林芝不同生态区域的青稞、小麦、油菜3种作物农田开展瓢虫资源调查研究,同时选取固定样地定期进行种群动态分析.结果显示:林芝地区农田瓢虫分为2个亚科4个族10个属,共13种,其中11种为捕食性瓢虫.主要优势瓢虫种类为横斑瓢虫、多异瓢虫、二星瓢虫.其中横斑瓢虫在全部调查样地中均有分布,在农田中总体优势度指数、相对多度为最高.3种优势瓢虫在不同作物中种群动态变化规律存在差异,其中横斑瓢虫虫口密度长期高于其余优势瓢虫,且与蚜虫密度曲线有较为明显的重合现象.横斑瓢虫种群密度峰值主要集中在6月中旬至7月上旬,但在不同作物农田中具体峰值时期存在差异.可见,林芝地区农田不同种类瓢虫之间有较大数量差异,在不同生态区域与作物环境下具有不同的种群特征,但是优势瓢虫种类与种群规律较为明确,可用于农田蚜虫生物防治;结果可为保护当地重要昆虫资源及开展生物防治提供基础数据支撑.(图4表6参23)