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481.
N. Jane Harms Graham D. Fairhurst 《Environmental pollution (Barking, Essex : 1987)》2010,158(3):841-848
In the Athabasca oil sands region of northern Alberta, mining companies are evaluating reclamation using constructed wetlands for integration of tailings. From May to July 2008, reproductive performance of 40 breeding pairs of tree swallows (Tachycineta bicolor), plus growth and survival of nestlings, was measured on three reclaimed wetlands on two oil sands leases. A subset of nestlings was examined for i) feather corticosterone levels, ii) delayed-type hypersensitivity response, and iii) innate immune function. Nestlings on one of two wetlands created with oil sands process affected material (OSPM) were heavier and had greater wing-lengths, and mounted a stronger delayed-type hypersensitivity response compared those on the reference wetland. Corticosterone was significantly higher in male nestlings on one of two OSPM-containing wetland compared to the reference wetland. Body condition of 12-day-old female nestlings was inversely related to feather corticosterone. Under ideal weather conditions, reclaimed wetlands can support healthy populations of aerially-insectivorous birds. 相似文献
482.
E. Lombi D.P. Stevens M.J. McLaughlin 《Environmental pollution (Barking, Essex : 1987)》2010,158(6):2110-2116
Water treatment residuals (WTRs) are produced by the treatment of potable water with coagulating agents. Beneficial recycling in agriculture is hampered by the fact that WTRs contain potentially toxic contaminants (e.g. copper and aluminium) and they bind phosphorus strongly. These issues were investigated using a plant bioassay (Lactuca sativa), chemical extractions and an isotopic dilution technique. Two WTRs were applied to an acidic and a neutral pH soil at six rates. Reductions in plant growth in amended soils were due to WTR-induced P deficiency, rather than Al or Cu toxicity. The release of potentially toxic Al from WTRs was found to be mitigated by their alkaline nature and pH buffering capacity. However, acidification of WTRs was shown to release more soluble Al than soil naturally high in Al. Copper availability was relatively low in all treatments. However, the lability of WTR-Cu increased when the WTR was applied to the soil. 相似文献
483.
Virender K. Sharma Nigel J. D. Graham Xiang-Zhong Li Bao-Ling Yuan 《Environmental science and pollution research international》2010,17(2):453-461
Background, aim and scope
Photocatalytic oxidation using UV irradiation of TiO2 has been studied extensively and has many potential industrial applications, including the degradation of recalcitrant contaminants in water and wastewater treatment. A limiting factor in the oxidation process is the recombination of conduction band electrons (e − cb) with electron holes (hvb+) on the irradiated TiO2 surface; thus, in aqueous conditions, the presence of an effective electron scavenger will be beneficial to the efficiency of the oxidation process. Ferrate (FeO42−) has received much recent attention as a water treatment chemical since it behaves simultaneously as an oxidant and coagulant. The combination of ferrate [Fe(VI)] with UV/TiO2 photocatalysis offers an oxidation synergism arising from the Fe(VI) scavenging of e − cb and the corresponding beneficial formation of Fe(V) from the Fe(VI) reduction. This paper reviews recent studies concerning the photocatalytic oxidation of problematic pollutants with and without ferrate. 相似文献484.
Ikechukwu D. Anyaogu Paul M. Ejikeme John A. Ibemesi 《Journal of Polymers and the Environment》2010,18(2):104-115
Soybean oil (SBO) was dimerized and the crude dimer acid product reacted with 1,2-phenylene diamine at 210 ± 5 °C under inert
atmosphere to obtain fatty polyamide (FPA). The FPA was used to modify a commercial alkyd resin by reacting a mixture of the
alkyd resin with 5 wt% of FPA at 120 °C for 80 min under inert atmosphere. The FTIR spectrum of the FPA modified resin showed
evidence of higher degree of H-bonding than was found for the unmodified alkyd. White gloss coatings of 15, 20, 25, and 30%
solids were formulated from the modified and unmodified resins and examined for performance with respect to: leveling, sag
resistance, drying time, pigment settling, skinning tendency and film hardness. Results showed that the unmodified alkyd coatings
exhibited good leveling but poor sag resistance at all solid contents. In contrast, FPA modified alkyd coatings combined good
leveling with high sag resistance indicating their thixotropic nature. A strong tendency to pigment settling was observed
for unmodified alkyd coatings but was not observed in the FPA modified alkyd coatings. The modified alkyd coatings showed
skinning while the unmodified alkyd coatings did not skin. A 30% solids coating formulation of the FPA modified resin showed
shorter surface dry time but longer hard dry time than the unmodified alkyd resin coating. 相似文献
485.
Chuan-Yao Lin C.-C. Chang C.Y. Chan C.H. Kuo W.-C. Chen D. Allen Chu Shaw C. Liu 《Atmospheric environment (Oxford, England : 1994)》2010,44(2):182-193
To quantify the possible sources of the high ambient ozone concentration in the low troposphere over Taiwan, ozone sounding data from a two-year intensive field measurement program conducted in April and early May of 2004 and 2005 in northern Taiwan has been examined. We found that the vertical ozone distributions and occurrence of enhanced ozone in the lower troposphere (below 6 km) mainly resulted from (1)Type NE: the long-range transport of ozone controlled by the prevailing northeasterly winds below 2 km, (2)Type LO: the local photochemical ozone production process, and (3)Type SW: the strong southwest/westerly winds aloft (2–6 km). In the boundary layer (BL), where Asian continental outflow prevails, the average profile for type NE is characterized by a peak ozone concentration of nearly 65 ppb at about 1500 m altitude. For type LO, high ozone concentration with an average ozone concentration greater than 80 ppb was also found in the BL in the case of stagnant atmospheric and sunny weather conditions dominated. For type SW, significant ozone enhancement with average ozone concentration of 70–85 ppb was found at around 4 km altitude. It is about 10 ppb greater than that of the types NE and LO at the same troposphere layer owing to the contribution of the biomass burning over Indochina. Due to Taiwan's unique geographic location, the complex interaction of these ozone features in the BL and aloft, especially features associated with northeasterly and south/southwesterly winds, have resulted in complex characteristics of ozone distributions in the lower troposphere over northern Taiwan. 相似文献
486.
D. Vienneau K. de Hoogh R. Beelen P. Fischer G. Hoek D. Briggs 《Atmospheric environment (Oxford, England : 1994)》2010,44(5):688-696
Land-use regression models have increasingly been applied for air pollution mapping at typically the city level. Though models generally predict spatial variability well, the structure of models differs widely between studies. The observed differences in the models may be due to artefacts of data and methodology or underlying differences in source or dispersion characteristics. If the former, more standardised methods using common data sets could be beneficial. We compared land-use regression models for NO2 and PM10, developed with a consistent protocol in Great Britain (GB) and the Netherlands (NL).Models were constructed on the basis of 2001 annual mean concentrations from the national air quality networks. Predictor variables used for modelling related to traffic, population, land use and topography. Four sets of models were developed for each country. First, predictor variables derived from data sets common to both countries were used in a pooled analysis, including an indicator for country and interaction terms between country and the identified predictor variables. Second, the common data sets were used to develop individual baseline models for each country. Third, the country-specific baseline models were applied after calibration in the other country to explore transferability. The fourth model was developed using the best possible predictor variables for each country.A common model for GB and NL explained NO2 concentrations well (adjusted R2 0.64), with no significant differences in intercept and slopes between the two countries. The country-specific model developed on common variables for NL but not GB improved the prediction.The performance of models based upon common data was only slightly worse than models optimised with local data. Models transferred to the other country performed substantially worse than the country-specific models. In conclusion, care is needed both in transferring models across different study areas, and in developing large inter-regional LUR models. 相似文献
487.
B. Miljevic K.E. Fairfull-Smith S.E. Bottle Z.D. Ristovski 《Atmospheric environment (Oxford, England : 1994)》2010,44(18):2224-2230
Reactive oxygen species (ROS) and related free radicals are considered to be key factors underpinning the various adverse health effects associated with exposure to ambient particulate matter. Therefore, measurement of ROS is a crucial factor for assessing the potential toxicity of particles. In this work, a novel profluorescent nitroxide, BPEAnit, was investigated as a probe for detecting particle-derived ROS. BPEAnit has a very low fluorescence emission due to inherent quenching by the nitroxide group, but upon radical trapping or redox activity, a strong fluorescence is observed. BPEAnit was tested for detection of ROS present in mainstream and sidestream cigarette smoke. In the case of mainstream cigarette smoke, there was a linear increase in fluorescence intensity with an increasing number of cigarette puffs, equivalent to an average of 101 nmol ROS per cigarette based on the number of moles of the probe reacted. Sidestream cigarette smoke sampled from an environmental chamber exposed BPEAnit to much lower concentrations of particles, but still resulted in a clearly detectible increase in fluorescence intensity with sampling time. It was calculated that the amount of ROS was equivalent to 50 ± 2 nmol per mg of particulate matter; however, this value decreased with ageing of the particles in the chamber. Overall, BPEAnit was shown to provide a sensitive response related to the oxidative capacity of the particulate matter. These findings present a good basis for employing the new BPEAnit probe for the investigation of particle-related ROS generated from cigarette smoke as well as from other combustion sources. 相似文献
488.
Kai-Chung Cheng Marian D. Goebes Lynn M. Hildemann 《Atmospheric environment (Oxford, England : 1994)》2010,44(16):2062-2066
The effect of foot traffic on indoor particle resuspension was evaluated by associating non-prescribed foot traffic with simultaneous size-resolved airborne particulate matter (PM) concentrations in a northern California hospital. Foot traffic and PM were measured every 15 min in a carpeted hallway over two 27-h periods. The PM concentration in the hallway was modeled based on the foot traffic intensity, including the previous PM concentration via an autocorrelation regression method based on the well-mixed box model. All 5 size ranges of PM, ranging from 0.75–1 μm to 5–7.5 μm, were highly correlated with foot traffic measurements for both monitoring periods (p < 0.001, R2 = 0.87–0.90). However, correlations during daytime hours were less significant than nighttime. Coefficients found via this autoregressive analysis can be interpreted to reveal (i) time-independent contributions of walking activities on PM levels for a specific location; and (ii) size-specific characteristics of the resuspended PM. 相似文献
489.
490.
Carbon Storage in Soil Size Fractions Under Two Cacao Agroforestry Systems in Bahia, Brazil 总被引:1,自引:0,他引:1
Emanuela F. Gama-Rodrigues P. K. Ramachandran Nair Vimala D. Nair Antonio C. Gama-Rodrigues Virupax C. Baligar Regina C. R. Machado 《Environmental management》2010,45(2):274-283
Shaded perennial agroforestry systems contain relatively high quantities of soil carbon (C) resulting from continuous deposition
of plant residues; however, the extent to which the C is sequestered in soil will depend on the extent of physical protection
of soil organic C (SOC). The main objective of this study was to characterize SOC storage in relation to soil fraction-size
classes in cacao (Theobroma cacao L.) agroforestry systems (AFSs). Two shaded cacao systems and an adjacent natural forest in reddish-yellow Oxisols in Bahia,
Brazil were selected. Soil samples were collected from four depth classes to 1 m depth and separated by wet-sieving into three
fraction-size classes (>250 μm, 250–53 μm, and <53 μm)—corresponding to macroaggregate, microaggregate, and silt-and-clay
size fractions—and analyzed for C content. The total SOC stock did not vary among systems (mean: 302 Mg/ha). On average, 72%
of SOC was in macroaggregate-size, 20% in microaggregate-size, and 8% in silt-and-clay size fractions in soil. Sonication
of aggregates showed that occlusion of C in soil aggregates could be a major mechanism of C protection in these soils. Considering
the low level of soil disturbances in cacao AFSs, the C contained in the macroaggregate fraction might become stabilized in
the soil. The study shows the role of cacao AFSs in mitigating greenhouse gas (GHG) emission through accumulation and retention
of high amounts of organic C in the soils and suggests the potential benefit of this environmental service to the nearly 6
million cacao farmers worldwide. 相似文献