Effect of the spionid polychaeteBoccardia syrtis on the distribution and survival of juvenileMacomona liliana (Bivalvia: Tellinacea)

The tellinid bivalveMacomona liliana (Iredale) occurs at relatively low densities on a sandbank (Te Tau bank) in Manukau Harbour, New Zealand. Te Tau bank is dominated by polychaetes, including the tube-building spionidBoccardia syrtis (Rainer). JuvenileM. liliana are known to disperse as post-settlement juveniles by byssus-drifting. Laboratory experiments were conducted to assess whether the low abundance ofM. liliana on Te Tau bank was due to the presence ofB. syrtis, or to some reaction to the sediment itself. In particular, we, examined how juvenileM. liliana survived after exposure to Te Tau bank sediments with and without the spionid tube-mat for 1 mo in still-water conditions, and how they responded when given a choice of different sediment/tube-mat treatments in moving water. JuvenileM. liliana did not appear to have a strong aversion to settling and burrowing in sediments from Te Tau bank. Sediments without the tube-mat did not adversely affect the survivorship of the bivalves, but survival was significantly lower amongst theB. syrtis tube-mat. In the presence of a current, the juvenile bivalves settled in Te Tau bank sediments without a tube-mat, but avoided settling amongst liveB. syrtis. An artificial tube-mat enhanced settlement. Avoidance of liveB. syrtis appears to be an avoidance of the worms themselves rather than a response to the physical presence of their tubes.     

Persistent organochlorine residues in soils from tropical and sub-tropical Asian countries

Soil samples from paddy fields, uplands, and urban areas (gardens and roadsides) collected from Vietnam, Thailand, and Taiwan were analysed to determine the residual levels of persistent organochlorine compounds such as DDTs, HCHs, and PCBs. DDT concentration in soil samples from Vietnam were found to be highest, with a mean value of 110 ng g(-1), and were followed by those in Taiwanese soils with a mean value of 20 ng g(-1). HCH concentrations were highest in soil samples from Vietnam (a mean value of 4.8 ng g(-1)) and were followed by those from Taiwan (a mean value of 1.4 ng g(-1)). Concentrations of PCBs were found to be highest in Taiwanese soil samples, with a mean of 95 ng g(-1). Interestingly, relatively high concentrations of PCBs in rural cultivated-soil samples from Vietnam were recorded with a mean value of 25 ng g(-1), probably suggesting PCB release from different kinds of weapons used during the Second Indochina war. The lowest concentrations of DDTs, HCHs, and PCBs were obtained in soil samples from Thailand, with mean values of 8.3 ng g(-1), 0.4 ng g(-1), and 2.7 ng g(-1), respectively.     

Determination of F2-isoprostanes in cultured human lung epithelial cells after exposure to metal oxide and silica nanoparticles by high-performance liquid chromatography/tandem mass spectrometry

The environmental impact of nanotechnology has caused a great concern. Many in vitro studies showed that many types of nanoparticles were cytotoxic. However, whether these nanoparticles caused cell membrane damage was not well studied. F₂-isoprostanes are specific products of arachidonic acid peroxidation by nonenzymatic reactive oxygen species and are considered as reliable biomarkers of oxidative stress and lipid peroxidation. In this article, we investigated the cytotoxicity of different nanoparticles and the degree of cellular membrane damage by using F₂-isoprostanes as biomarkers after exposure to nanoparticles. The human lung epithelial cell line A549 was exposed to four silica and metal oxide nanoparticles: SiO₂ (15 nm), CeO₂ (20 nm), Fe₂O₃ (30 nm), and ZnO (70 nm). The levels of F₂-isoprostanes were determined by using high-performance liquid chromatography/mass spectrometry. The F₂-isoprostanes’ peak was identified by retention time and molecular ion m/z at 353. Oasis HLB cartridge was used to extract F₂-isoprostanes from cell medium. The results showed that SiO₂, CeO₂, and ZnO nanoparticles increased F₂-isoprostanes levels significantly in A549 cells. Fe₂O₃ nanoparticle also increased F₂-isoprostanes level, but was not significant. This implied that SiO₂, CeO₂, ZnO, and Fe₂O₃ nanoparticles can cause cell membrane damage due to the lipid peroxidation. To the best of our knowledge, this is the first report on the investigation of effects of cellular exposure to metal oxide and silica nanoparticles on the cellular F₂-isoprostanes levels.     

Scavenging of atmospheric formaldehyde by wet precipitation

Despite the great importance that formaldehyde has in atmospheric photochemistry, few studies have been reported on rain water. In this paper, concentrations of HCHO in rain fractions within rain events are presented. Two sampling sites were chosen: one at Mexico City, a great polluted urban area, and the second at Rancho Viejo, a forested area under the meteorological influence of the city. The results show a general decrease during the early portion of the rain event. This seems to indicate that below-cloud scavenging is the most important mechanism while, from the small variations observed in the latter portion of the rainfall, it is possible to assume within-cloud scavenging as the predominant mechanism. Using the HCHO concentrations in rain water, the mixing ratios were estimated for the two sampling sites. The values were 0.68 ppb and 0.44 ppb at Mexico City and Rancho Viejo, respectively. Measurements at ground level in Mexico City gave a mean HCHO concentration in air of 24 ppb, much higher than the estimated mixing ratio. The high levels of HCHO found in ambient air and in rain water reflect anthropogenic emissions as the potential atmospheric sources.     

Space perception as a factor in land use decision making

Land use decisions involve the allocation of space to competing demands. Space is perceived subjectively, particularly in respect to recreational use. Five groups involved in the decision-making process were asked to select from a list of acreages or percentages the closest approximation for each of five land use categories. The responses produced considerable variation from the correct answers. Designated park areas tended to be overestimated and designated forest lands underestimated. While some differences were associated with group affiliation; visibility of areas, political importance, experience of individual, mode of access, proximity, and role of group member may also have been important determinants. The importance of space perception is dependent on type of process in decision making; in particular whether the process is incremental or comprehensive.     

Managing Alberta's water: the decision-making process

Land and water are Canada's most valuable renewable natural resources. Canada possesses one-quarter of the world's known volume of fresh water. Fresh water covers 75369000 hectares of 7.1% of the country's surface. This area represents a very substantial number oflakes, rivers, streams, deltas and bays and is perhaps Canada's most vital and strategic resource. Canada has to have ab overall plan of management which provides direction, coordination, and assistance for the management of its water resources at the provincial and regional levels.     

PHYSICAL PROCESSES AND EUTROPHICATION1

ABSTRACT: Biological responses to physical-chemical processes were examined in Toronto and Hamilton Harbours of Lake Ontario. Nutrient loadings to the harbors are large and are of similar magnitude, yet the trophic conditions of the harbors were considerably different. Lake oscillations were found to determine the flushing rates and environmental stability of the harbors. LOW residence times (<10 days) resulted in homogenous chemical conditions in Toronto Harbour, and prevented the establishment of large phytoplankton crops. The longer retention time of Hamilton Harbour permitted the establishment of huger phytoplankton crops. There probably exists a critical retention time where nutrient input events persist for a sufficient period of time for the algal community to adapt to and exploit the environmental conditions of nearshore areas.     

SIMPLE TROPHIC STATE CLASSIFICATION OF THE CANADIAN NEARSHORE WATERS OF THE GREAT LAKES1

ABSTRACT: Trophic classification of the Canadian nearshore waters of the Great Lakes is attempted using summer, surface water quality data for the early 1970's. A generalized Composite Trophic Index is developed using paired linear relationships for total phosphorus, chlorophyll a, and Secchi depth data for 66 defined nearshore regions. The chlorophyll a and total phosphorus relationship indicates that the nearshore waters contain a low chlorophyll a concentration for a given total phosphorus concentration than observed for the open waters of the Great Lakes or for smaller Canadian lakes. The most eutrophic nearshore regions occur in areas of relatively restricted circulation and/or high nutrient loadings. These include the Bay of Quinte, Toronto and Hamilton harbours, and portions of Lake We's Western Basin. Lakes Huron and Superior are generally oligotrophic, except for some embayments. Although nearshore water quality is highly variable, this apprach represents a reasonable compromise with respect to analytical complexity. The Composite Trophic Index removes biases introduced through the use of a single trophic state indicator and uniquely describes the nearshore water quality in terms generally comparable to other water bodies.     

COMPARING METHODS OF HYDROLOGIC REGIONALIZATION1

ABSTRACT: Data splitting is used to compare methods of determining “homogeneous” hydrologic regions. The methods compared use cluster analysis based on similarity of hydrologic characteristics or similarity of characteristics of a stream's drainage basin. Data for 221 stations in Arizona are used to show that the methods, which are a modification of DeCoursey's scheme for defining regions, improve the fit of estimation data to the model, but that is is necessary to have an independent measure of predictive accuracy, such as that provided by data splitting, to demonstrate improved predictive accuracy. The methods used the complete linkage algorithm for cluster analysis and computed weighted average estimates of hydrologic characteristics at ungaged sites.     

INSTANTANEOUS PEAK FLOW ESTIMATION PROCEDURES FOR NEWFOUNDLAND STREAMS1

ABSTRACT: A procedure of estimating instantaneous flood flows for various return periods on the Island of Newfoundland is presented. The procedure is based on annual maximum instantaneous flows rather than annual maximum daily-mean flows, as the latter requires the conversion of estimated daily-mean flows into instantaneous flows. Regression equations were developed for each of three homogeneous regions for the desired return periods. The flood flow estimation capability of the presented procedure is demonstrated to be better than any other currently available procedure on the Island.