Uptake of nitroaromatic compounds in plants

The uptake of nitroaromatic compounds by plants from the soil was studied at an ammunition site. After the development of analytical methods for 2,4,6-trinitrotoluene, aminodinitrotoluenes and dinitrotoluenes in plant material, we could show that these substances accumulated in the roots of plants and are found to a lesser extent inleaves and stems. We observed only moderate differences between various plant species. It is likely that a metabolic transformation in plants leads to the formation of dinitrotoluenes which are considered to be potent carcinogens. Results from soils with a wide range of explosive concentrations show a good correlation between the plant and soil concentrations. The relative accumulation in plant material is higher at lower soil concentrations. At low soil concentrations of about 1 mg trinitrotoluene/kg soil, an accumulation factor of about 0.5 can be derived. These data are an important input for the risk assessment of ammunition sites.     

A stakeholder dialogue on European vulnerability

A stakeholder dialogue was embedded in the ATEAM project to facilitate the development and dissemination of its European-wide vulnerability assessment of global change impacts. Participating stakeholders were primarily ecosystem managers and policy advisers interested in potential impacts on ‘Agriculture’, ‘Forestry’, ‘Water’, ‘Carbon storage’, ‘Biodiversity’ and ‘Mountain environments’ sectors. First, stakeholder dialogue approaches to integrated assessment are introduced. Methodological considerations on stakeholder selection and dialogue implementation and evaluation follow. The dialogue content and process are evaluated from the perspectives of stakeholders and scientists. Its usefulness in the research process and the relevance of outcomes for stakeholders are particularly considered. The challenging compromises required to perform innovative research, which seeks to achieve both peer scientific credibility and societal relevance, are emphasized. Effective stakeholder dialogues play a substantial role in raising the visibility and meaningfulness of vulnerability assessments as critical means to improve awareness on global change and its potential worrying impacts on society. They further provide scientists with critical information on ecosystem management and sectoral adaptive capacity. These processes of mutual learning and knowledge exchange moreover foster a better understanding of the potential and limits of global change modelling and vulnerability assessment for policy and ecosystem management.

Kinship recognition and grouping in hatchling green iguanas

Summary The research addressed two questions: (1) doIguana iguana hatchlings recognize their kin, and (2) what are the recognition mechanisms? Eggs were collected from wild and captive-raised females and hatched in semi-natural incubators. In the first experiment we used eggs from two females. One of the clutches was subdivided to be placed in different incubators. Immediately after emergence one of these hatchling groups was introduced into a 10 m x 10 m enclosure. At the same time we introduced hatchlings from another female. The remaining hatchling group was kept separate for 3 weeks and was then introduced into the same cage. Unrelated hatchlings separated from each other. Related but separated hatchlings grouped according to introduction date. In the second experiment we maintained eight kin groups in individual cages and two hatchlings per kin group in an additonal cage. Hatchlings from the mixed group showed no preference for their kin before physical contact with pure kin groups had occurred. After physical contact hatchling recognized their kin by feces smell. Body odor is likely to be also involved.     

UN/ECE ICP Materials Dose-response Functions for the Multi-pollutant Situation

A “multi-pollutant exposure programme” reflecting the new pollution situation where SO₂ is no longer the dominating pollutant has been performed by the International Co-operative Programme on Effects on Materials, including Historic and Cultural Monuments (ICP Materials) within the activities of the Convention on Long-range Transboundary Air Pollution. The main results obtained in the period 1997–2003 are summarised. Dose-response functions are presented for carbon steel, zinc, copper, bronze and limestone. Parameters involved in the functions include besides SO₂ and pH, which were included in the previously developed functions from ICP Materials, also the effect of particulate matter and HNO₃.     

Assessment of solid waste generation and greenhouse gas emission potential in Yangon city,Myanmar

Due to booming economy, growing population and rapid urbanization, solid waste generation in the cities of developing countries has significantly increased. Yangon is the largest and most densely populated city, with over five million residents in Myanmar. Open dumping is the major waste disposal method and recycling sector remains at an early development stage. With increasing waste generation, current waste management activities in Yangon have significant environmental impacts. Therefore, the study developed two linear models to predict annual solid waste generation, regarding per capita waste generation, population growth scenarios, literacy rates and gross domestic products. The Intergovernmental Panel on Climate Change and Institute for Global Environmental Strategies calculation methods were used for greenhouse gas (GHG) emission prediction from recycling, waste transportation and final disposal sites (FDSs). As a result, the total annual waste generation and GHG emission in 2015 may double over the next decade. Two major FDSs, Htawe Chaung and Hteinpin, may contribute waste disposal of 272–797 kilotons per year and emit 177–518 Gg of CO₂-eq per year by 2025. The assessment of annual solid waste generation and GHG emission potential may offer advantages in assisting development of waste management plans in Yangon.     

Impact of agglomeration and different dispersions of titanium dioxide nanoparticles on the human related in vitro cytotoxicity and genotoxicity

The published results on nanoparticles cytotoxicity and genotoxicity such as titanium dioxide nanoparticles (TiO(2) NPs) are inconsistent, and often conflicting and insufficient. Since different parameters may have impact on the toxicity results, there is need to lay stress on detailed characterization of NPs and the use of different testing conditions for assessment of NPs toxicity. In order to investigate whether dispersion procedures influence NP cytotoxicity and genotoxicity, we compared two protocols giving TiO(2) NP dispersions with different stability and agglomeration states. Detailed primary and secondary characteristics of both TiO(2) NP dispersions in culture media were carried out before toxicological testing; TK6 human lymphoblast cells, EUE human embryonic epithelial cells and Cos-1 monkey kidney fibroblasts were used to assess cytotoxicity (by trypan blue exclusion, proliferation activity and plating efficiency assays) and genotoxicity (by the comet assay). DNA strand breaks were detected by the alkaline comet assay. DNA oxidation lesions (especially 8-oxo-7,8-dihydroguanine, 8-oxoG) were measured with a modified comet assay including incubation with specific repair enzyme formamidopyrimidine DNA glycosylase (FPG). The TiO(2) NPs dispersion with large agglomerates (3 min sonication and no serum in stock solution) induced DNA damage in all three cell lines, while the TiO(2) NPs dispersed with agglomerates less than 200 nm (foetal serum in stock solution and sonication 15 min) had no effect on genotoxicity. An increased level of DNA oxidation lesions detected in Cos-1 and TK6 cells indicates that the leading mechanism by which TiO(2) NPs trigger genotoxicity is most likely oxidative stress. Our results show that the dispersion method used can influence the results of toxicity studies. Therefore at least two different dispersion procedures should be incorporated into assessment of cyto- and genotoxic effects of NPs. It is important, when assessing the hazard associated with NPs, to establish standard testing procedures and thorough strategies to consider the diverse conditions relevant to possible exposures.     

Multi-criteria assessment of socio-environmental aspects in shrinking cities. Experiences from eastern Germany

Demographic change and economic decline produce modified urban land use pattern and densities. Compared to the beginning of the 90s after the German reunification, nowadays massive housing and commercial vacancies followed by demolition and perforation come to pass in many cities of the former GDR. In consequence, a considerable surplus of urban brownfields has been created. Furthermore, the decline in the urban fabric affects social infrastructure and urban greenery of local neighbourhoods. Here, urban planning enters into ‘uncharted territory’ since it needs to assess the socio-environmental impact of shrinkage.In order to carry out such an evaluation quantitatively, a multi-criteria assessment scheme (MCA) was developed and applied. Firstly, we identified infrastructure and land use changes related to vacancy and demolition. Secondly, demolition scenarios for the coming 20 years were applied in order to give an idea for a long-term monitoring approach at the local district level. A multi-criteria indicator matrix quantifies the socio-environmental impact on both urban greenery and residents. Using it, we set demolition scenarios against urban ‘quality of life’ targets. Empirical evidence comes from Leipzig, in eastern Germany, a representative case study for urban shrinkage processes.The results show that shrinkage implies socio-environmental changes of residential livelihoods, however, does not simply increase or decrease the overall urban quality of life. The integrated assessment of all indicators identifies environmental and social opportunities, as well as the challenges a shrinking city is faced with.     

Arsenic concentration and speciation of the marine hyperaccumulator whelk Buccinum undatum collected in coastal waters of Northern Britain

European whelks (Buccinum undatum) have shown to accumulate high levels of arsenic. Since the accumulation process is not well understood it is necessary to gain information about the geographical variability of the arsenic concentration in them. Here we show that the mean arsenic concentrations of the whelks are site specific and vary by a factor of 3.5 in ten different geographical locations. At fishing grounds where whelks exhibited low arsenic concentrations the arsenic concentration increased linearly with size, whereas the whelks with high arsenic levels from a different location showed no correlation. Although the overall arsenic concentration in the whelks differed between 45 and 655 mg kg(-1) d.w., the inorganic arsenic concentration did not exceed 0.4 mg kg(-1) d.w. The main arsenic compound is arsenobetaine, which is widely considered as non-toxic. The exposure to toxic inorganic arsenic when eating whelks cannot be estimated from their size or their total arsenic concentration.     

A Quantitative Review of Urban Ecosystem Service Assessments: Concepts,Models, and Implementation

Although a number of comprehensive reviews have examined global ecosystem services (ES), few have focused on studies that assess urban ecosystem services (UES). Given that more than half of the world’s population lives in cities, understanding the dualism of the provision of and need for UES is of critical importance. Which UES are the focus of research, and what types of urban land use are examined? Are models or decision support systems used to assess the provision of UES? Are trade-offs considered? Do studies of UES engage stakeholders? To address these questions, we analyzed 217 papers derived from an ISI Web of Knowledge search using a set of standardized criteria. The results indicate that most UES studies have been undertaken in Europe, North America, and China, at city scale. Assessment methods involve bio-physical models, Geographical Information Systems, and valuation, but few study findings have been implemented as land use policy.

Electronic supplementary material

The online version of this article (doi:10.1007/s13280-014-0504-0) contains supplementary material, which is available to authorized users.     

Effect of biochar addition on the improvement of the quality parameters of compost used for land reclamation

Environmental Science and Pollution Research - The 5% addition of biochar in composting in rows contributes significantly to reducing volatile organic compound(VOC) emissions. When composting with...