全文获取类型
收费全文 | 1027篇 |
免费 | 22篇 |
国内免费 | 18篇 |
专业分类
安全科学 | 30篇 |
废物处理 | 81篇 |
环保管理 | 118篇 |
综合类 | 148篇 |
基础理论 | 221篇 |
环境理论 | 1篇 |
污染及防治 | 280篇 |
评价与监测 | 106篇 |
社会与环境 | 75篇 |
灾害及防治 | 7篇 |
出版年
2023年 | 22篇 |
2022年 | 70篇 |
2021年 | 54篇 |
2020年 | 32篇 |
2019年 | 24篇 |
2018年 | 62篇 |
2017年 | 47篇 |
2016年 | 60篇 |
2015年 | 45篇 |
2014年 | 59篇 |
2013年 | 78篇 |
2012年 | 48篇 |
2011年 | 75篇 |
2010年 | 36篇 |
2009年 | 40篇 |
2008年 | 44篇 |
2007年 | 42篇 |
2006年 | 36篇 |
2005年 | 18篇 |
2004年 | 30篇 |
2003年 | 28篇 |
2002年 | 25篇 |
2001年 | 21篇 |
2000年 | 12篇 |
1999年 | 7篇 |
1998年 | 2篇 |
1997年 | 7篇 |
1996年 | 6篇 |
1995年 | 4篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 8篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1986年 | 3篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1977年 | 1篇 |
1974年 | 1篇 |
1969年 | 1篇 |
1964年 | 1篇 |
1963年 | 1篇 |
1961年 | 1篇 |
1953年 | 1篇 |
1951年 | 1篇 |
1944年 | 1篇 |
排序方式: 共有1067条查询结果,搜索用时 62 毫秒
151.
Dóra B. Huszár Rasmus S. Larsen Sarah Carlsen Jacobus J. Boomsma Jes Søe Pedersen 《Behavioral ecology and sociobiology》2014,68(11):1859-1870
Ant supercolonies (large networks of interconnected nests) represent the most extreme form of multi-queen breeding (polygyny) and have been found across ant lineages, usually in specific long-term stable populations. Many studies on the genetic population structure and demography of ant supercolonies have been done in recent decades, but they have lacked multicolonial control patches with separated colonies headed by a single or few queens so the origin of the supercolonial trait syndrome has remained enigmatic. Here, we set out to compare sympatric supercolonial and multicolonial patches in two natural Danish populations of the common red ant Myrmica rubra. We used DNA microsatellites to reconstruct genetic colony/population structure and obtained morphological and density measurements to estimate life history and ecology covariates. We found that supercolonies in both populations completely dominated their patches whereas colonies in multicolonial patches coexisted with other ant species. Supercolony patches had very low genetic differentiation between nests, negligible relatedness within nests, and lower inbreeding than multicolonial patches, but there were no significant morphological differences. One population also had nests that approached true outbred monogyny with larger workers and males but smaller queens than in the two other social nest types. Our results suggest that once smaller colonies start to adopt additional queens, they also gain the potential to ultimately become supercolonial when the habitat allows rapid expansion through nest budding. This is relevant for understanding obligate polygyny in ants and for appreciating how and why introduced North American populations of M. rubra have recently become invasive. 相似文献
152.
Baki Hazer Bahattin M. Baysal Ay?e G. K?seo?lu Necati Be?irli Elif Ta?k?n 《Journal of Polymers and the Environment》2012,20(2):477-484
The synthesis of polylactide (PLA)-b-poly (dimethyl siloxane) (PDMS) linear block copolymers and their use in blends with pure-PLA are described. PLA-b-PDMS linear block copolymers were obtained by the transesterification reaction in chloroform solution between poly(dimethyl siloxane) bis (2-aminopropyl ether) (molecular weight 2,000?Da) with PLA in the presence of stannous octoate. Molecular weights (Mw) of the block copolymers were varied from 53,800 to 63,600?Da while that of pristine PLA was 73,600?Da. The copolymers obtained were purified by fractional precipitation and then characterized by 1H NMR, FTIR, GPC, viscometry and DSC techniques. Blends of pure PLA with PLA-b-PDMS block copolymers displayed improved elastic properties (elongation up to 140%) compared to pure PLA (elongation ~9%). Thermal, mechanical and morphological characterization of the blends were also conducted. 相似文献
153.
Soil ingestion can be an important route of exposure to contaminants present in the environment. This study examined the effects of exposure to contaminants in aqueous soil extracts from an industrial urban settlement in renal biochemical parameters of treated rats. Male Wistar rats were gavaged with an aqueous soil extract, from the municipality of Rio Grande, Southern Brazil. After exposure, plasma and urine concentrations and plasma protein were assessed compared to rats treated with aqueous soil from relatively unpolluted site (control soil). There was increase in plasma creatinine and total protein in urine, and a decreased glomerular filtration rate in treated rats compared to control. It is possible that Cd, Cr, As, Cu, Pb, Zn, and Ni analyzed in the soil samples and unidentified components may have provoked the observed changes in renal biochemistry of the exposed rat. This may suggest that exposure to contaminated soils can cause damage to the viscera in mammals and it is of public health importance. 相似文献
154.
Miguel Costa Leal Patricia N. Pochelon Teresa Lopes da Silva Alberto Reis Rui Rosa Ricardo Calado 《Marine Biology》2013,160(4):763-772
Offspring quality of decapod crustaceans has been widely studied, with special emphasis on the sources of variability determining embryonic and larval quality. Nevertheless, maternal provisioning has commonly been overlooked as a potential source of offspring within-brood variability. In the present study, the existence of variable maternal provisioning was assessed through the analysis of the fatty acid (FA) profile of newly extruded embryos from different regions of the brooding chamber of Homarus gammarus. Significant differences in the FA profile of embryos sampled from different pleopods and sides of the brooding chamber were recorded. Significant deviations of the overall mean of each surveyed female were also observed for essential FA, particularly 20:4n-6, 20:5n-3 and 22:6n-3. Lipid energy available to fuel embryogenesis also varied among embryos sampled from different regions of the brooding chamber. Results suggest variable female investment at oocyte production, which may be amplified during the incubation period of developing embryos by differential lipid catabolism. For the first time, maternal provisioning is evidenced as an additional source for within-brood variability in the FA profile of embryos. 相似文献
155.
G. L. Carneiro D. Braz E. F. de Jesus S. M. Santos K. Cardoso A. A. Hecht Moore K. Dias da Cunha 《Environmental geochemistry and health》2013,35(3):333-340
The aim of this study was to evaluate the public and occupational exposure to radon and metal-bearing particles in museums and public buildings located in the city of Rio de Janeiro, Brazil. For this study, four buildings were selected: two historic buildings, which currently house an art gallery and an art museum; and two modern buildings, a chapel and a club. Integrated radon concentration measurements were performed using passive radon detectors with solid state nuclear track detector-type Lexan used as nuclear track detector. Air samplers with a cyclone were used to collect the airborne particle samples that were analyzed by the particle-induced X-ray emission technique. The average unattached-radon concentrations in indoor air in the buildings were above 40 Bq/m3, with the exception of Building D as measured in 2009. The average radon concentrations in indoor air in the four buildings in 2009 were below the recommended reference level by World Health Organization (100 Bq/m3); however, in 2011, the average concentrations of radon in Buildings A and C were above this level, though lower than 300 Bq/m3. The average concentrations of unattached radon were lower than 148 Bq/m3 (4pCi/L), the USEPA level recommended to take action to reduce the concentrations of radon in indoor air. The unattached-radon average concentrations were also lower than the value recommended by the European Union for new houses. As the unattached-radon concentrations were below the international level recommended to take action to reduce the radon concentration in air, it was concluded that during the period of sampling, there was low risk to human health due to the inhalation of unattached radon in these four buildings. 相似文献
156.
The Piratininga Lagoon is a coastal, choked, and brackish ecosystem in SE Brazil, where uncontrolled discharge of domestic sewage led to eutrophication, increasing massive proliferation of benthic macroalgae, and decrease of the lagoon mean depth. In 1992, a dam was constructed by the local Municipality at its tidal channel aiming at stabilising its water level. Main physico-chemical parameters, together with macroalgae biomass, nutrient concentrations in the water column, particulate organic carbon, and chlorophyll a were recorded monthly at 4 sampling stations within the Piratininga lagoon from April 1994 to April 1995. The data, compared with “before-lock” existing studies, show that nutrients and chlorophyll a concentrations significantly increased after the lock construction. Based on the functioning of the ecosystem, we propose to harvest the algal mats before their decomposition period in order to partly remove the nutrient stocks from the lagoon and the future ecosystem modelling to predict the impact of natural and anthropogenic eutrophication. 相似文献
157.
Reis AP Patinha C Ferreira da Silva E Sousa AJ 《Environmental geochemistry and health》2012,34(2):229-241
The Marrancos gold mineralisation has a chemical assemblage of Fe–As–Se–Bi–Au–Ag–Te–(Cu–Pb–Zn–Sn–W). The −200 mesh of 144
topsoil samples was analysed by ICP–MS to determine total contents of 53 elements that include potentially harmful elements
like Cd, As and Pb. The soil geochemistry shows that some trace elements occur in considerably high concentrations. On the
basis of data for total metal concentrations, 10 topsoil samples were selected to carry out a metal fractionation study using
a selective extraction method. A set of four leaches of increasing strength was used sequentially in the soil samples. Across
the study area, there is some evidence of past mining and exploration activity, indicating that these soils may be locally
disturbed. The shallow mineralised quartz veins were exploited for gold by the Romans. Several galleries were constructed
during the 2nd World War, probably for the exploration of quartz–cassiterite–wolframite veins. However, the main mineralised
body in depth was never explored. The results of metal fractionation show different partitions for the three elements. Total
Cd concentrations in these soils are low, with a median value of 0.1 mg/kg. In average, 12% of total Cd is adsorbed by clays
and/or co-precipitated with carbonates, and 19% is bounded to Fe–Mn oxyhydroxides. However, the low concentrations indicate
that the metal does not represent an immediate risk to human health. For Pb, metal fractionation shows that, on average, 22%
of Pb is adsorbed by amorphous Fe and Mn oxides, but the samples from the northern part of the area have the major fractions
of Pb in soluble forms. The low probability of exposure in this part of the study area decreases the risk posed by this heavy
metal. Total As concentrations in the Marrancos soils are extremely high. A large area has As concentrations above 1,000 mg/kg.
For As, metal fractions in the sulphide phase vary between 84 and 98% in the studied samples. But one sample has 20% of total
As in easily reducible forms, corresponding to a partial concentration of 1,800 mg/kg that has a high probability of being
bioavailable. The most labile As forms occur at the southern part of the area, where the probability of exposure is higher
and the risk of human health increases in the same order. From the three studied potentially harmful elements, As is certainly
the element of concern. 相似文献
158.
Stable isotope ratios of a tropical marine predator: confounding effects of nutritional status during growth 总被引:1,自引:1,他引:0
Larisa Lee Cruz Rona A. R. McGill Simon J. Goodman Keith C. Hamer 《Marine Biology》2012,159(4):873-880
Stable isotope analysis of carbon and nitrogen is frequently used to study the diets and foraging ecology of marine predators.
However, isotopic values may also be affected by an individual’s nutritional status and associated physiological processes.
Here, we use C and N stable isotopes in blood and feathers of blue-footed booby chicks at the Galápagos Islands to examine
how isotopic values are related to body condition and growth rate, and to assess the consistency in the isotope ratios of
individuals during growth. Size dimorphism in blue-footed boobies provided an additional opportunity to examine how isotope
ratios differ between sexes in relation to body size and growth rate. There was no significant difference between sexes but
both C and N stable isotopes were significantly negatively related to the body condition of chicks. These data were consistent
with individual variation in physiological processes affecting fractionation, although we cannot rule out the possibility
that they were also influenced to some extent by population-level variation in the stable isotope ratios of prey fed to chicks,
for instance related to prey size, depth or lipid content. Our results highlight the need for methods that take proper account
of confounding physiological factors in isotopic studies of foraging ecology and diet. 相似文献
159.
da Cunha K. Moore Dias Dalia Pereira K. C. Guimarães J. R. D. Lima C. Nascimento J. E. C. Lima R. Hecht A. A. Fiel J. C. B. 《Environmental geochemistry and health》2018,40(5):2037-2048
Environmental Geochemistry and Health - The objective of this study was to assess worker exposure to mineral dust particles, and a metabolic model, based on the model adopted by ICRP, was applied... 相似文献
160.
Spherical TiO2 nanoparticles (npTiO2) were prepared by controlled hydrolysis of tetraethoxy orthotitanate under a nitrogen atmosphere. ZnO nanoparticles (npZnO) were prepared using hydrothermal methods. The crystal structure, chemical, thermal and morphological properties of npZnO and npTiO2 were characterised using Fourier Transform Infrared Spectrometer, enery-dispersive X-ray spectroscopy, X-ray diffraction, and scanning electron microscope techniques. The short- and long-term experiments were started with neonates taken from the same culture and laboratory condition. In the acute experiments, npTiO2, npZnO, and cocktail concentrations were applied. 96h-LC50 values were 1.8, 0.7, and 0.1?mg?L?1, respectively (p?<?.05). For the chronic experiments, different npTiO2 concentrations were performed. 21d-LC50 value was 1.0?mgL?1 (p?<?.05). Morphometry became progressively worse in concentrations of more than 1?mgL?1 npTiO2. Neonate and young individuals were more sensitive to death because of their low tolerance. This result was affected by population progeny and growth rates (p?<?.05). While control and 0.5?mgL?1 npTiO2 groups were determined as growing population, 1.5 and 2?mgL?1 npTiO2 groups had decreased population size as R0 values. Consequently, the relationships between nanoparticle accumulation within Daphnia magna and its population structure and body morphometry for each concentration were important indicators. Its tolerance level to nanoparticles under laboratory conditions reflected its replacement and behaviour in the ecosystem. 相似文献