Polybrominated diphenyl ethers in plastic products,indoor dust,sediment and fish from informal e-waste recycling sites in Vietnam: a comprehensive assessment of contamination,accumulation pattern,emissions, and human exposure

Residue concentrations of polybrominated diphenyl ethers (PBDEs) in different kinds of samples including consumer products, indoor dust, sediment and fish collected from two e-waste recycling sites, and some industrial, urban and suburban areas in Vietnam were determined to provide a comprehensive assessment of the contamination levels, accumulation pattern, emission potential and human exposure through dust ingestion and fish consumption. There was a large variation of PBDE levels in plastic parts of obsolete electronic equipment (from 1730 to 97,300 ng/g), which is a common result observed in consumer plastic products reported elsewhere. PBDE levels in indoor dust samples collected from e-waste recycling sites ranged from 250 to 8740 ng/g, which were markedly higher than those in industrial areas and household offices. Emission rate of PBDEs from plastic parts of disposed electronic equipment to dust was estimated to be in a range from 3.4 × 10^?7 to 1.2 × 10^?5 (year^?1) for total PBDEs and from 2.9 × 10^?7 to 7.2 × 10^?6 (year^?1) for BDE-209. Some fish species collected from ponds in e-waste recycling villages contained elevated levels of PBDEs, especially BDE-209, which were markedly higher than those in fish previously reported. Overall, levels and patterns of PBDE accumulation in different kinds of samples suggest significant emission from e-waste sites and that these areas are potential sources of PBDE contamination. Intakes of PBDEs via fish consumption were generally higher than those estimated through dust ingestion. Intake of BDE-99 and BDE-209 through dust ingestion contributes a large proportion due to higher concentrations in dust and fish. Body weight normalized daily intake through dust ingestion estimated for the e-waste recycling sites (0.10–3.46 ng/day/kg body wt.) were in a high range as compared to those reported in other countries. Our results highlight the potential releases of PBDEs from informal recycling activities and the high degree of human exposure and suggest the need for continuous investigations on environmental pollution and toxic impacts of e-waste-related hazardous chemicals.     

黄河小浪底水库南山水质自动监测站站址方案探讨

在小浪底水库中新建黄河南山水质自动监测站,是为了实现黄河小浪底水库水质实时监测,及时掌握国家考核断面水质状况;同时,为了完成生态环境部加快推进国家地表水环境质量监测网水质自动监测站(以下简称水站)建设,建立健全以自动监测为主、手工监测为辅的地表水环境质量监测体系。本文主要研究南山水站站址的选择方案,得出恰当合理的方案,既满足水站安全运行的要求和水库调水调沙期间,确保采集到具备代表性。     

Air pollution modeling at road sides using the operational street pollution model--a case study in Hanoi, Vietnam

In many metropolitan areas, traffic is the main source of air pollution. The high concentrations of pollutants in streets have the potential to affect human health. Therefore, estimation of air pollution at the street level is required for health impact assessment. This task has been carried out in many developed countries by a combination of air quality measurements and modeling. This study focuses on how to apply a dispersion model to cities in the developing world, where model input data and data from air quality monitoring stations are limited or of varying quality. This research uses the operational street pollution model (OSPM) developed by the National Environmental Research Institute in Denmark for a case study in Hanoi, the capital of Vietnam. OSPM predictions from five streets were evaluated against air pollution measurements of nitrogen oxides (NO(x)), sulfur dioxide (SO2), carbon monoxide (CO), and benzene (BNZ) that were available from previous studies. Hourly measurements and passive sample measurements collected over 3-week periods were compared with model outputs, applying emission factors from previous studies. In addition, so-called "backward calculations" were performed to adapt the emission factors for Hanoi conditions. The average fleet emission factors estimated can be used for emission calculations at other streets in Hanoi and in other locations in Southeast Asia with similar vehicle types. This study also emphasizes the need to further eliminate uncertainties in input data for the street-scale air pollution modeling in Vietnam, namely by providing reliable emission factors and hourly air pollution measurements of high quality.     

Evaluation of the Daphnia magna reproduction test for detecting endocrine disruptors

The Daphnia 21 d reproduction test is considered as a comprehensive and decisive test in the OECD Conceptual Framework for testing and assessment of endocrine disrupting chemicals (EDCs). However, how to interpret results of the Daphnia 21 d reproduction test for identification, risk assessment and testing strategy of EDCs remains an unsolved issue. This study analysed a total number of 135 published studies encompassing 86 known EDCs and non-EDCs with different modes of action. Our results show that the majority of effects on apical endpoints (survival, molting, growth, time to reproductive maturity, brood size, the number of broods, and the total number of offspring) do not seem to be EDC-specific. In contrast, the endpoint sex ratio is likely specific to juvenile hormones and their mimics. Variability is quantified for three most reported endpoints survival, the total number of offspring and sex ratio. Quantification of the endpoint sensitivity shows that the sensitivity of the sex ratio is lower than that of the total number of offspring. The Daphnia 21 d reproduction test gives insufficient information to conclude if a substance is an EDC or not. EDCs that are potent in assays in vitro may not be potent in the Daphnia 21 d reproduction test. We conclude that the Daphnia 21 d reproduction test is important for deriving No Observed Effect Concentrations for risk assessment but may produce false negatives in identification of EDCs when used on its own. A targeted testing strategy for selection of species, tests, and endpoints is suggested for identifying EDCs.     

Analysis of polychlorinated dibenzo-p-dioxins and furans in various aqueous samples in Taiwan

Twenty-one fresh water samples were taken from reservoirs, wells and drinking water treatment plants in Taiwan for measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) concentrations. Due to low concentration of PCDD/Fs, water samples (400-1000 L) were collected by using the on-site large volume pre-concentration system and analyzed by high resolution gas chromatography (HRGC)/high resolution mass spectrometer (HRMS). Different characteristics of dioxin profiles in surface water and groundwater are observed. The PCDD/F concentrations in fresh water samples varied from 0.001 to 0.265 pg WHO₉₈-TEQ/L which are lower than the standard (12 pg WHO₉₈-TEQ/L) set by the Taiwan Environmental Protection Administration (TEPA) for drinking water. Only a small fraction (<5%) of the total PCDD/F concentration in fresh water samples was water-soluble. As a result of their hydrophobicity, PCDD/Fs are effectively removed along with suspended solid via the water treatment process (average 98% removal efficiency).     

两株稠油高效降解菌的筛选鉴定及其降解性能研究

从广州石化厂曝气池周围的油泥中筛选驯化出2株可以降解稠油的菌株GSO2和GSO7,经16S rDNA序列分析鉴定这两株菌均属于不动杆菌属(Acinetobacter sp.).通过摇瓶振荡实验,对GSO2和GSO7在以稠油为唯一碳源时的生长情况、降解率及环境条件对降解率的影响进行了研究.结果表明,菌株GSO2和GSO7...     

Managing flood risks in the Mekong Delta: How to address emerging challenges under climate change and socioeconomic developments

Climate change and accelerating socioeconomic developments increasingly challenge flood-risk management in the Vietnamese Mekong River Delta—a typical large, economically dynamic and highly vulnerable delta. This study identifies and addresses the emerging challenges for flood-risk management. Furthermore, we identify and analyse response solutions, focusing on meaningful configurations of the individual solutions and how they can be tailored to specific challenges using expert surveys, content analysis techniques and statistical inferences. Our findings show that the challenges for flood-risk management are diverse, but critical challenges predominantly arise from the current governance and institutional settings. The top-three challenges include weak collaboration, conflicting management objectives and low responsiveness to new issues. We identified 114 reported solutions and developed six flood management strategies that are tailored to specific challenges. We conclude that the current technology-centric flood management approach is insufficient given the rapid socioecological changes. This approach therefore should be adapted towards a more balanced management configuration where technical and infrastructural measures are combined with institutional and governance resolutions. Insights from this study contribute to the emerging repertoire of contemporary flood management solutions, especially through their configurations and tailoring to specific challenges.     

Environment and sustainability of the Middle Route,South-to-North Water Transfer Project in China: a close look

In many arid and semiarid regions, water scarcity, population increase and frequent droughts are exerting great pressures on water resources. Presently, the Mid-route of the South-to-North Water Transfer Project (MRSN) was built to mitigate the water crisis in the north of China by long-distance transfer of water from the Yangtze River in southern China. This study investigated the running condition of the MRSN, including operation management, freezing situation and water quality. Water samples were also taken from different sites and then analyzed in laboratory. Results suggest that the project was reasonably designed and the project management was excellent. Closed management was adopted in the project to protect water quality. The sediment concentrations and water turbidities of the water samples were in the range of 0.2–0.8 kg/m³ and 0.8–1.7 NTU, respectively, which met or were close to the standards of drinking water in China. Water freezing is also not a problem, since the thickest ice was only 0.9 cm even in the coldest season as the authors measured the investigation, and at the same time, the ice booms worked well. In the future, it is promising that to effectively integrate the methods of self-rescuing and water importing could fundamentally conquer water shortage, reasonably allocate water resources and finally achieve the harmonious development of economics, ecology and society.     

How do local communities adapt to climate changes along heavily damaged coasts? A Stakeholder Delphi study in Ky Anh (Central Vietnam)

The Central Vietnamese coast faces increasing impacts on the local livelihoods of coastal communities as a result of the increasing natural hazards which include tropical storms, heavy rains, and floods. A challenge for the local populations is improving their adaptation capacity to climate change hazards in a sustainable way. This study deals with the impacts of climate change-associated hazards and adaptation capacity in coastal communes of the Ky Anh district, Ha Tinh province along the coast in Central Vietnam. A combination of the Stakeholder Delphi technique and the DPSIR (drivers–pressures–states–impacts–responses) framework was used. Delphi questionnaires allowed assessing the consensus among the respondents of a stakeholder group. Twenty questions and 20 statements were listed reflecting the DPSIR components. Thirty-six panel members, which were randomly selected from four stakeholder groups which included local authorities, farmers, fishermen, and fish traders, were involved in a two-round Delphi process. The results show that, both agricultural and non-agricultural sectors are main drivers (D); migration, calamities, population growth, mineral mining, aquaculture processing, and agriculture are main pressures (P); changes in the frequency of extreme weather events, increasing intensity of storms, floods, and droughts indicate main states (S); changes in agricultural land use and productivity are main impacts (I); construction of and upgrading dykes and irrigation systems should be the principal responses (R) in the vision of the local stakeholders. The Kendall’s W value for the second round is 0.681, indicating a high degree of consensus among the panel members and confidence in the ranks. Overall, the study advocates developing sustainable ecosystems, an upgraded New Rural Planning, and renewable energy strategies as the main local adaptations to climate change hazards in this area.