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791.
R. Maurício C. J. Dias N. Jubilado F. Santana 《Environmental monitoring and assessment》2013,185(10):8125-8133
In this report, the development of an online, noninvasive, measurement method of the biofilm thickness in a liquid phase is presented. The method is based in the analysis of the ultrasound wave pulse-echo behavior in a liquid phase reproducing the real reactor conditions. It does not imply the removal of the biomass from the support or any kind of intervention in the support (pipes) to detect and perform the measurements (non-invasiveness). The developed method allows for its sensor to be easily and quickly mounted and unmounted in any location along a pipe or reactor wall. Finally, this method is an important innovation because it allows the thickness measurement of a biofilm, in liquid phase conditions that can be used in monitoring programs, to help in scheduling cleaning actions to remove the unwanted biofilm, in several application areas, namely in potable water supply pipes. 相似文献
792.
J. L. F. Angeli T. H. Trevizani A. Ribeiro E. C. Machado R. C. L. Figueira B. Markert S. Fraenzle S. Wuenschmann 《Environmental monitoring and assessment》2013,185(10):8333-8342
Concentrations of arsenic and four additional trace elements (Cu, Cr, Ni, and Zn) were determined by inductively coupled plasma–optical emission spectrometry in the muscular tissue of the yellow catfish (Cathorops spixii) and the urutu catfish (Genidens genidens) from Paranaguá Estuarine Complex, Brazil (PEC). The PEC can be characterized by an environment of high ecological and economic importance in which preserved areas of rainforest and mangroves coexist with urban activities as ports and industries. The average concentrations (in milligram per kilogram dry weight) of elements in the muscle tissue of C. spixii are as follows: Zn (31), As (17), Cu (1.17), Cr (0.62), and Ni (0.28). Similar concentrations could be found in G. genidens with exception of As: Zn (36), As (4.78), Cu (1.14), Cr (0.51), and Ni (0.14). Fish from the geographic northern rural region (Guaraqueçaba–Benito) display higher As concentrations in the muscle tissues than fish found in the south-western (urban) part of the PEC. An international comparison of muscle tissue concentrations of trace elements in fish was made. Except for Ni in C. spixii, a tendency of decrease in element concentration with increasing size (age) of the fish could be observed. According to the National Health Surveillance Agency of Brazil, levels of Cr and As exceeded the permissible limits for seafood. An estimation of the provisional tolerable weekly intake of As was calculated with 109 % for C. spixii and with 29 % for G. genidens. 相似文献
793.
C. M. Oliveira M. F. Camões P. Bigus A. A. Fachado R. B. Silva 《Environmental monitoring and assessment》2015,187(6):380
In this work, particulate matter was collected using an active sampling system consisting of a PM10 (<10 μm) inlet coupled to a multifold device containing six channels, connected to a vacuum pump. Each channel was equipped with a filter holder fitted with adequately chosen filters. The system was fixed on a metallic structure, which was placed on the roof of the laboratory building, at the Faculty of Sciences, in Lisbon. Sampling took place under flow-controlled conditions. Aerosols were extracted from the filters with water, in defined conditions, and the water-soluble fraction was quantified by ion chromatography (IC) for the determination of inorganic anions (Cl?, NO3 ? and SO4 2?). Equivalent sampling through the various channels was validated. Validation was based on the metrological compatibility of the content results for the various filters. Ion masses are metrologically equivalent when their absolute difference is smaller than the respective expanded uncertainty. When this condition is verified, the studied multifold device produces equivalent samples. 相似文献
794.
Alam R Munna G Chowdhury MA Sarkar MS Ahmed M Rahman MT Jesmin F Toimoor MA 《Environmental monitoring and assessment》2012,184(1):573-580
In rural areas in Bangladesh, groundwater is the principal source of water supply. This underground water is available in
considerable amount in shallow aquifers. It is free from pathogenic microorganisms and hence water-borne diseases. In plain
lands, other than hilly areas, water supply to 97% rural population comes from tube-wells, which is regarded to be a phenomenal
achievement in preserving public health. Besides, a dependable water supply system all throughout the country is offset by
two factors: (a) high salinity in surface plus groundwater in coastal areas; (b) want of suitable groundwater aquifers in
hilly areas and the high cost of setting up tube-wells due to deep underground water table and stony layers. However, presence
of arsenic in underground water now poses a serious threat to the success once made in water supply by setting up of manually
operated tube-wells in the village areas—the achievement is now on the brink of total collapse. In about 61 districts out
of 64, presence of arsenic exceeds a quantity of 0.05 mg/1, a permissible limit as per Bangladeshi water quality standard.
Harvesting rainwater can be a pragmatic solution to this problem, which is common in many places in Sylhet especially in the
hilly areas on the north eastern part of the city. This can be an alternative source of drinking water because of availability
of rainwater from March to October. Heavy rain occurs from end of May till mid September, which is commonly known as the rainy
season. This paper focuses on the possibility of harvesting rainwater in rural communities and thickly populated urban areas
of Sylhet. It also demonstrates the scopes of harvesting rainwater using simple and low-cost technology. With setting up of
a carefully planned rainwater storage tank, a family can have all of its drinking water from rain. Planned use of rainwater
through rainwater harvesting in the roof catchments may fulfill the entire annual domestic water demand of a family in the
rural areas of Bangladesh. 相似文献
795.
Chlorinated paraffins (CPs) are straight chain hydrocarbons that are produced as complex mixtures and are used as flame retardants
and paint additives. These mixtures are extremely difficult to characterize using conventional chromatographic methods, as
conventional gas chromatography results in unresolved complex chromatograms that preclude the identification and quantification
of individual congeners or any reasonable assessment of the average carbon chain length. Carbon chain length is an important
parameter for assessing physical properties and the toxicity of these materials. We have modified and improved a previously
published gas chromatography–flame ionization detector method that uses Pd catalyst held in the gas chromatograph injector
to simultaneously dechlorinate the CPs and separate the resulting alkanes. In addition, we have adapted this method to gas
chromatography–mass spectrometry. Dehalogenation of other compounds was also studied with this system to investigate potential
application to other complex halogenated mixtures. 相似文献
796.
Mayack DT 《Environmental monitoring and assessment》2012,184(4):2497-2516
Many non-linear processes link atmospheric emissions to the bioavailability of metals; consequently, the monitoring of metals
in ecosystem components is required to model their ecodynamics. American mink (Neovison vison) and river otter (Lontra canadensis) have the potential to serve as an upper-level-consumer component in monitoring metals bioavailability. However, the relationship
of bioaccumulated metals to various environmental factors has not been explored nor have the effects of demographic factors
been resolved. To address these limitations, mink and otter, collected throughout New York State during 1998–2002, were analyzed
for hepatic concentrations of total mercury (Hg), cadmium (Cd), and lead (Pb). Relationships were investigated between metals
concentrations and landscape-level factors (physiographic zone, hydrologic unit, and elevation) and demographic factors (gender
and age). Considerable variation in Hg and Cd concentrations was observed relative to both physiographic zone and hydrologic
unit for both species. In contrast with Hg, Cd concentration increased predictably with increasing elevation. Mercury concentrations
were greater, but for Cd less, in otter than mink. Lead concentrations showed little landscape heterogeneity and were independent
of elevation. Age-related bioaccumulation was evident for Hg and Cd, but not for Pb, in both species. Mercury and Cd concentrations
were greater in female than male mink; however, Pb concentrations were greater in males than females. Inverse relationships
of relative growth (weight/length) to metals concentrations explained gender differences in Hg and Cd in mink. For otter,
no gender-related differences in metals concentrations were apparent. The suitability of mink and otter for monitoring programs
is discussed. 相似文献
797.
Voss KA Pohlman A Viswanathan S Gibson D Purohit J 《Environmental monitoring and assessment》2012,184(3):1603-1616
Environmental agencies across the United States have searched for adequate methods to assess anthropogenic impacts on the
environment. Biological assessments, which compare the taxonomic composition of an aquatic assemblage to relevant biocriteria,
have surfaced as an effective method to assess the ecological integrity of US waterbodies. In this study, bioassessment data
were collected and analyzed in conjunction with physical habitat and chemical stressor data for streams and rivers within
the San Diego basin from 1998 through 2005. Physical stressors such as sediment loading, riparian destruction, and in-stream
habitat homogenization affect many locations in the region. However, physical habitat measures alone were found to frequently
overestimate the biological integrity of streams in the region. Many sites within the San Diego Basin, although unaffected
by physical stressors, continue to exhibit low biological integrity scores. Sites with low biological integrity tend to possess
higher specific conductance and salinity compared to sites with high biological integrity. We suggest that one possible reason
for these differences is the source water used for municipal purposes. 相似文献
798.
José A. Murillo Pulgarín Luisa F. García Bermejo Armando Carrasquero Durán 《Environmental monitoring and assessment》2013,185(1):573-580
A flow injection analysis method based on ion chromatography and luminol chemiluminescence detection was used for the simultaneous determination of copper (II) and cobalt (II) trace levels in soils and sediments following microwave-assisted acid digestion. Detection was based on chemiluminescence (CL) of the luminol–perborate system in an alkaline medium, which is catalyzed by both transition metals. The concentration and pH of the eluent (oxalic acid) was found to affect CL intensities and retention times, both of which were inversely proportional to the oxalic acid concentration. The calibration curves for both metal ions were linear and allowed a limit of detection of 0.003 μg l?1 for cobalt (II) and 0.014 μg l?1 for cooper (II) to be calculated. The proposed method was successfully used to determine both metal ions in certified reference materials of stream and river sediments and soil samples. Based on the results, the determination is free of interferences from the usual concomitant ions. 相似文献
799.
Rui Galhano dos Santos Noemi F. Acero Sandro Matos Ricardo Carvalho Mário Vale Ana C. Marques João C. Bordado Maria M. Mateus 《Journal of Polymers and the Environment》2018,26(1):91-100
The use of petroleum-derived products should be avoided regarding the principles of green and sustainable chemistry. The work reported herein, is aimed at the liquefaction of pine shavings for the production of an environmentally-friendly polyol suitable to be used in the formulations of sprayable polyurethane foams. The biopolyols were obtained in high yield and were used to replace those derived from fossil sources, to produce more “greener” polyurethane foams and therefore, less dependent on petroleum sources, since the polyol component was substituted by products resulting from biomass liquefaction. The partial and fully exchange of the polyols was accomplished, and the results compared with a reference foam. The foams were afterward, chemical, physical, morphological, and mechanically characterized. The complete replacement of polyether polyol and polyol polyester has presented some similar characteristics as that used as a reference, validating that the path chosen for the development of more sustainable materials is on the right track for the contribution to a cleaner world. 相似文献
800.
Luiz F. Maldonado Pablo A. R. Muñoz Guilhermino J. M. Fechine 《Journal of Polymers and the Environment》2018,26(8):3187-3196
Here, the influence of graphene as a coating on the biodegradation process for two different polymers is investigated, poly(butylene adipate-co-terephthalate) (PBAT) (biodegradable) and low-density polyethylene (LDPE) (non-biodegradable). Chemical vapor deposition graphene was transferred to the surface of two types of polymers using the Direct Dry Transfer technique. Polymer films, coated and uncoated with graphene, were buried in a maturated soil for up to 180 days. The films were analyzed before and after exposure to microorganisms in order to obtain information about the integrity of the graphene (Raman Spectroscopy), the biodegradation mechanism of the polymer (molecular weight and loss of weight), and surface changes of the films (atomic force microscopy and contact angle). The results prove that the graphene coating acted as a material to control the biodegradation process the PBAT underwent, while the LDPE covered by graphene only had changes in the surface properties of the film due to the accumulation of solid particles. Polymer films coated with graphene may allow the production of a material that can control the microbiological degradation, opening new possibilities in biodegradable polymer packaging. Regarding the possibility of graphene functionalization, the coating can also be selective for specific microorganisms attached to the surface. 相似文献