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461.
Few would now deny that the use of organobromine compounds to achieve fire retardancy in a diverse array of products and materials has led to contamination of the ecosphere on a widespread scale. This environmental prevalence and persistence of the brominated flame retardants, coupled with growing evidence of their potential for harm, present all too familiar parallels with the previous generation of persistent organic pollutants. Indeed, given the intrinsic properties of these brominated chemicals, the nature and extent of the current problem could well have been predicted in advance. The question is then whether we are prepared to let history repeat itself once more or to take precautionary action now to switch to more sustainable alternatives. The choice facing society is not between brominated flame retardants and unsafe products, but between fire safety leading to global contamination or fire safety achieved in less polluting ways. If we look beyond options for simple chemical-for-chemical substitution to alternative materials and designs, many of the solutions are already available. The remainder could undoubtedly be developed given the incentives to do so. However, a strong and clear policy approach, backed by legislative phase-outs within specified (and challenging) timeframes, will be necessary to break our current dependency on organobromine chemistry. This paper presents the justification for such an approach, reviews those initiatives already underway to replace brominated flame retardants and identifies pathways to the use of more sustainable products in the service of society. 相似文献
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Johan Tidblad Vladimir Kucera Farid Samie Surendra N. Das Chalothorn Bhamornsut Leong Chow Peng King Lung So Zhao Dawei Le Thi Hong Lien Hans Schollenberger Chozi V. Lungu David Simbi 《Water, Air, & Soil Pollution: Focus》2007,7(1-3):241-247
Many national exposure programmes have been performed in tropical and subtropical climates during the last 50 years. However,
ambitious programmes involving more than a few countries are scarce. In this paper a recently formed network of test sites
is described involving 12 test sites in Asia (India, Vietnam, Thailand, Malaysia and China including Hong Kong) and four test
sites in Africa (South Africa, Zambia and Zimbabwe). This effort is part of the 2001–2004 Swedish International Development
Agency (SIDA) funded Programme on Regional Air Pollution in Developing Countries (RAPIDC). Corrosion attack after one (2002–2003)
year of exposure (carbon steel, zinc, copper, limestone and paint coated steel) are presented together with environmental
data (SO2, NO2, HNO3, O3, particles, amount and pH of precipitation, temperature and relative humidity) for all the test sites. The obtained corrosion
values are substantially higher than expected for limestone, higher than expected for carbon steel and lower than expected
for zinc compared to values calculated using the best available dose–response functions. 相似文献
464.
Carmen A. Lebrón Timothy McHale Robroy Young Dale Williams Matthew G. Bogaart David W. Major Michaye L. McMaster Ian Tasker Naji Akladiss 《补救:环境净化治理成本、技术与工艺杂志》2007,17(2):5-17
An Interstate Technology and Regulatory Council (ITRC) forum was recently held that focused on six case studies in which bioremediation of dense nonaqueous‐phase liquids (DNAPLs) was performed; the objective was to demonstrate that there is credible evidence for bioremediation as a viable environmental remediation technology. The first two case studies from the forum have been previously published; this third case study involves a pilot‐scale demonstration that investigated the effects of biological activity on enhancing dissolution of an emplaced tetrachloroethene (PCE) DNAPL source. It used a controlled‐release test cell with PCE as the primary DNAPL in a porous media groundwater system. Both laboratory tests and a field‐scale pilot test demonstrated that bioaugmentation can stimulate complete dechlorination to a nontoxic end product and that the mass flux from a source zone increases when biological dehalorespiration activity is enhanced through nutrient (electron donor) addition and bioaugmentation. All project goals were met. Important achievements include demonstrating the ability to degrade a PCE DNAPL source to ethene and obtaining significant information on the impacts to the microbial populations and corresponding isotope enrichments during biodegradation of a source area. © 2007 Wiley Periodicals, Inc. 相似文献
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Mondher Chehata David Jasinski Michael C. Monteith William B. Samuels 《Journal of the American Water Resources Association》2007,43(3):813-828
Abstract: Data interpretation and visualization software tools with geostatistical capabilities were adapted, customized, and tested to assist the Chesapeake Bay Program in improving its water‐quality modeling protocols. Tools were required to interpolate, map, and visualize three‐dimensional (3D) water‐quality data, with the capability to determine estimation errors. Components of the software, originally developed for ground‐water modeling, were customized for application in estuaries. Additional software components were developed for retrieval, and for pre‐ and post‐ processing of data. The Chesapeake Bay Program uses the 3D mapped data for input to the Bay water‐quality model that projects the future health of the Bay and its tidal tributary system. In determining water‐quality attainment criteria, 3D kriging estimation errors are needed as a statistical measure of uncertainty. Furthermore, given the high cost of installing and operating new monitoring stations, geostatistical techniques can assist the Chesapeake Bay Program in the identification of suitable data collection locations. Following the evaluation, selection, and development of the software components phase, 3D ordinary kriging techniques with directional semi‐variograms to account for anisotropy were successfully demonstrated for mapping 3D fixed station water‐quality data, such as dissolved oxygen and salinity. Additionally, an improved delineation tool was implemented to simulate the upper and lower pycnocline boundary surfaces allowing the segregation of the interpolated 3D data into three separate zones for a better characterization of the pycnocline layer. 相似文献
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Illinois has been operating an ambient water quality network of almost 600 stations for several years. In 1977 changes in program emphasis toward intensive monitoring, the need for improved procedures and quality control in monitoring operations, and the desire to create a single data base of all Illinois State monitoring data, resulted in a redesign of the ambient monitoring program.A unique cooperative program between the Illinois Environmental Protection Agency and the US Geological Survey provides for their monitoring a portion of the network. The Survey provides flow data at most network stations as well as extensive manpower training, equipment, data processing, and program quality control. Informal agreements with other agencies have permitted a great reduction in the monitoring effort required by the Illinois Environmental Protection Agency. 相似文献
470.
A nonstationary time-series model is used to examine the changes occurring at sampling stations on the Chicago Sanitary and Ship Canal. Using data from upstream sampling sites, downstream levels of dissolved oxygen, total dissolved solids, nitrates and nitrites, and ammonia are accurately predicted. The method is simple, insensitive to extreme values, and responsive to changes in the system. 相似文献