A Survey of Graduate Education in Hazardous Waste Management

A brief, informal survey questionnaire was sent to 69 universities in the U.S. Forty-two schools responded. Of the 42 respondents, 30 offered one or more courses in hazardous waste management. The average number of courses offered was 1.76 at an average frequency of once per year. Approximately 400 students take the hazardous waste management courses each year. Only four schools provided explicit laboratory training in hazardous waste analysis/treatment. Sixty-nine percent of the respondents have a research program in hazardous waste management. Typical course outlines are presented. Equipment needs for a hazardous waste laboratory are suggested.     

Influence of mercury and selenium chemistries on the progression of cardiomyopathy in pygmy sperm whales, Kogia breviceps

More than half of pygmy sperm whales (Kogia breviceps) that strand exhibit signs of cardiomyopathy (CMP). Many factors may contribute to the development of idiopathic CMP in K. breviceps, including genetics, infectious agents, contaminants, biotoxins, and dietary intake (e.g. selenium, mercury, and pro-oxidants). This study assessed trace elements in K. breviceps at various stages of CMP progression using fresh frozen liver and heart samples collected from individuals that stranded along US Atlantic and Gulf coasts between 1993 and 2007. Standard addition calibration and collision cell inductively coupled plasma mass spectrometry (ICP-MS) were employed for total Se analysis and pyrolysis atomic absorption (AA) was utilized for total Hg analysis to examine if the Se/Hg detoxification pathway inhibits the bioavailability of Se. Double spike speciated isotope dilution gas chromatography ICP-MS was utilized to measure methyl Hg and inorganic Hg. Immunoblot detection and colorimetric assays were used to assess protein oxidation status. Data collected on trace elements, selenoproteins, and oxidative status were evaluated in the context of animal life history and other complementary histological information to gain insight into the biochemical pathways contributing to the development of CMP in K. breviceps. Cardiomyopathy was only observed in adult pygmy sperm whales, predominantly in male animals. Both Hg:Se molar ratios and overall protein oxidation were greater in males than females and increased with progression of CMP.     

Effects of temperature on bacterial transport and destruction in bioretention media: field and laboratory evaluations

Microbial activities are significantly influenced by temperature. This study investigated the effects of temperature on the capture and destruction of bacteria from urban stormwater runoff in bioretention media using 2-year field evaluations coupled with controlled laboratory column studies. Field data from two bioretention cells show that the concentration of indicator bacteria (fecal coliforms and Escherichia coli) was reduced during most storm events, and that the probability of meeting specific water quality criteria in the discharge was increased. Indicator bacteria concentration in the input flow typically increased with higher daily temperature. Although bacterial removal efficiency was independent of temperature in the field and laboratory, column tests showed that bacterial decay coefficients in conventional bioretention media (CBM) increase exponentially with elevated temperature. Increases in levels of protozoa and heterotrophic bacteria associated with increasing temperature appear to contribute to faster die-off of trapped E. coli in CBM via predation and competition.     

A Case History of the Science and Management Collaboration in Understanding Hypoxia Events in Long Bay, South Carolina, USA

Communication of knowledge between the scientific and management communities is a difficult process complicated by the distinctive nature of professional career goals of scientists and decision-makers. This article provides a case history highlighting a collaboration between the science and management communities that resulted from a response to a 2004 hypoxia, or low dissolved oxygen, event in Long Bay, off Myrtle Beach, South Carolina. A working group of scientists and decision-makers was established at the time of the event and has continued to interact to develop a firm understanding of the drivers responsible for hypoxia formation in Long Bay. Several factors were found to be important to ensure that these collaborative efforts were productive: (1) genuine interest in collaboratively working across disciplines to examine a problem; (2) commitment by agency leadership, decision-makers, and researchers to create successful communication mechanisms; (3) respect for each others’ perspectives and an understanding how science and management are performed and that they are not mutually exclusive; (4) networking among researchers and decision-makers to ensure appropriate team members are involved in the process; (5) use of decision-maker input in the formulation of research and monitoring projects; and (6) commitment of resources for facilitation to ensure that researchers and decision-makers are communicating effectively.     

Sediment Source Assessment in a Lowland Watershed Using Nitrogen Stable Isotopes1

Fox, James F., Charles M. Davis, and Darren K. Martin, 2010. Sediment Source Assessment in a Lowland Watershed Using Nitrogen Stable Isotopes. Journal of the American Water Resources Association (JAWRA) 46(6):1192–1204. DOI: 10.1111/j.1752-1688.2010.00485.x Abstract: Sediment sources and transported sediments were sampled in a lowland watershed with pronounced fine sediment storage in the streambed. Sediments were analyzed for carbon and nitrogen content and stable nitrogen isotopic composition. Analysis of the data shows that temporarily stored streambed sediments dominate the sediment load during moderate- and low-flow hydrologic events. Modeling of sediment transport and nitrogen elemental and isotopic mass balance was performed for the watershed for a 12-month time period using a continuous, conceptual-based model. The model results show that during moderate- and low-flow hydrologic events, the streambed is slowly downcutting. During very high-flow hydrologic events, deposition is pronounced in the streambed and sediment is replenished to the bed. Nitrogen model results show that elemental and isotopic nitrogen of streambed sediments vary substantially over the simulation period. In this manner, the streambed in a lowland watershed functions as a temporary storage zone that, in turn, can impact the nitrogen elemental and isotopic signature of sediments. The variation could significantly impact estimates of sediment provenance using nitrogen tracer-based methods. Future work should consider both hydrologic and biogeochemical control on the nitrogen isotopic signature of sediments in small lowland watersheds and streams where a significant portion of deposited fines are temporarily stored.     

Context change and travel mode choice: Combining the habit discontinuity and self-activation hypotheses

The habit discontinuity hypothesis states that when a context change disrupts individuals’ habits, a window opens in which behavior is more likely to be deliberately considered. The self-activation hypothesis states that when values incorporated in the self-concept are activated, these are more likely to guide behavior. Combining these two hypotheses, it was predicted that context change enhances the likelihood that important values are considered and guide behavior. This prediction was tested in the domain of travel mode choices among university employees who had recently moved versus had not recently moved residence. As was anticipated, participants who had recently moved and were environmentally concerned used the car less frequently for commuting to work. This was found not only when compared to those who were low on environmental concern (which would be a trivial finding), but also to those who were environmentally concerned but had not recently moved. The effects were controlled for a range of background variables. The results support the notion that context change can activate important values that guide the process of negotiating sustainable behaviors.     

Open windrow composting of polymers: an investigation into the operational issues of composting polyethylene (PE)

This paper investigates the operational issues surrounding the open windrow composting of degradable polyethylene sacks. Areas for consideration were the impact of degradable polyethylene sacks on the composting process, the quality of the finished compost product, and how the use of sacks influenced the on-site processing. These factors were investigated through determining the amount of polymer residue and chemical contaminants in the finished compost product and the daily monitoring of windrow temperature profiles. Site and practical handling considerations of accepting an organic waste contained within PE sacks are also discussed. Statistical analysis of the windrow temperature profiles has led to the development of a model that can help to predict the expected trends in the temperature profiles of open compost windrows where the organic waste is kerbside collected using a degradable PE sack.     

MODIFICATION OF NEILL'S EQUATION FOR STORM‐TIDE DESIGN FLOW ANALYSIS1

ABSTRACT: Design of bridges spanning tidal estuaries or bays requires an estimate of peak tidal flow. One common approach to estimating these flows (Neill's method) uses a first‐order approximation of uniform water surface rise in the water body. For larger water bodies, the assumptions of this method are decreasingly valid. This study develops a simple modification that accounts for the spatial variability in the response of tidal waterways to storm surge flows. The peak tidal flow predicted by Neill's equation is compared to the peak flow determined by numerical simulation of estuaries with simple geometries, ranging from 1 to 25 km in length, using the U.S. Army Corps of Engineers one‐dimensional unsteady flow model, UNET. Results indicate that, under certain conditions, it may be appropriate to apply a correction factor to the peak discharge and peak velocity predicted by Neill's method. An algorithm, developed by nonlinear regression, is presented for computing correction factors based on estuary length, shape, mean depth, and storm‐tide characteristics. The results should permit the design of more reliable, cost‐effective structures by providing more realistic estimates of the potential for bridge scour in tidal waterways, especially when a full solution of the unsteady flow equations is impractical.