Use of pyrolysis molecular beam mass spectrometry (py-MBMS) to characterize forest soil carbon: method and preliminary results

The components of soil organic matter (SOM) and their degradation dynamics in forest soils are difficult to study and thus poorly understood, due to time-consuming sample collection, preparation, and difficulty of analyzing and identifying major components. As a result, changes in soil organic matter chemical composition as a function of age, forest type, or disturbance have not been examined. We applied pyrolysis molecular beam mass spectrometry (py-MBMS), which provides rapid characterization of SOM of whole soil samples. to the Tionesta soil samples described by Hoover, C.M., Magrini, K.A., Evans, R.J., 2002. Soil carbon content and character in an old growth forest in northwestern Pennsylvania: a case study introducing molecular beam mass spectrometry (PY-MBMS). Environmental Pollution 116 (Supp. 1), S269-S278. Our goals in this work were to: (1) develop and demonstrate an advanced, rapid analytical method for characterizing SOM components in whole soils, and (2) provide data-based models to predict soil carbon content and residence time from py-MBMS analysis. Using py-MBMS and pattern recognition techniques we were able to statistically distinguish among four Tionesta sites and show an increase in pyrolysis products of more highly decomposed plant materials at increasing sample depth. For example, all four sites showed increasing amounts of older carbon (phenolic and aromatic species) at deeper depths and higher amounts of more recent carbon (carbohydrates and lignin products) at shallower depths. These results indicate that this type of analysis could be used to rapidly characterize SOM for the purpose of developing a model, which could be used in monitoring the effect of forest management practices on carbon uptake and storage.     

WATER SUPPLY AS A LIMITING FACTOR IN WESTERN ENERGY DEVELOPMENT1

ABSTRACT: This paper discusses the consumptive water needs of the various energy conversion processes including oil shale retorting, coal gasification and liquefaction, electric power generation, and slurry pipelines. Projected energy development water needs in the upper Colorado River and Upper Missouri River basins are compared with projected agricultural needs and water available. The comparative cost and values of water to energy and agricultural development are discussed to emphasize this as well as the political and social factors entering into the picture.     

BACTERIAL RELATIONSHIPS IN STORMWATERS1

ABSTRACT: Data were developed within a three-year period for indicator bacteria and three species of bacterial pathogens following rural storm event hydrographs. The first flush concept was confirmed in all hydrographs. Bacterial density peaking occurred at or before the hydrograph peaks. FC and FS values were higher in more developed areas than the primary rural test site and their numerical ratios followed similar trends. Chlorine demand of storm waters varied between 8 and 16 mg/l and, the ozone requirement was greater than 32 mg/l in the same waters. Aftergrowth of total coliform bacteria occurred following chlorine and ozone doses of 16 mg/l and 32 mg/l respectively. Fecal coliform, fecal streptococci, Salmonella sp., and Pseudomonas sp. all were reduced to near detectable limits by the disinfectants up to 8 days. Staphylococcus sp. demonstrated a propensity to restablish their populations. Multiple regression analysis of the bacterial groups and species in storm waters suggested the fecal streptococci to have been the most useful group in evaluating bacterial storm water quality, with staphylocci have been closely related insofar as their statistical significance was concerned.     

DETERMINATION OF SEDIMENT YIELD BY TRANSFERRING RAINFALL DATA1

ABSTRACT: A methodology for obtaining the optimal design value to allow for sediment storage in a reservoir is presented for the situation where no data on sediment loads in the incoming streams are available. Information concerning the amount of sediment delivered to the reservoir over its life-time is obtained by a sediment yield model which uses data on rainfall amount and duration obtained from a nearby experimental watershed. Bayesian Decision Theory is used to obtain the optimal storage requirements in order to consider the natural variation of rainfall and the sampling error due to the short rainfall record available. The normally difficult calculations involved were made tractable by the use of simplifications and approximations valid in the context of the problem. Results show that sediment storage requirements can be calculated in this manner and that consideration of the uncertainties involved leads to a storage requirement substantially larger than that calculated without such consideration.     

Air pollution in California: Manufacturing vs. services

Relative to manufacturing, service activities are often considered by planners and officials to generate considerably less environmental pollution. This hypothesis is tested by means of an examination of the economic linkages of both manufacturing and service activities and of the resulting direct and indirect emissions of five air pollutants per dollar of output in the California statewide air basin and in four regional basins within the state. Overall acceptance or rejection of the hypothesis depends in part on the particular pollutant and air basin considered but, most importantly, on the judgement as to what activities are to be considered as service activities.This paper is based on research sponsored by the California Air Resources Board under Agreement A7-143-30.     

Product: Guide/1981

Abstract

The impact of weather on air pollution was examined and evaluated for the city of Athens, Greece. We used an objectively defined synoptic classification scheme consisting of six summer and eight winter circulation types. This scheme was established using a combination of both factor and cluster analysis during 1954–1999. Surface and isobaric levels of 850 hPa data were used. Factor analysis combined with cluster analysis was used to derive circulation types based on surface meteorological data for the period 1954–1999 in Athens and on surface pressure grid data. The city was divided into three sectors according to the financial and social activities of the residents. To examine the spatial characteristics of pollutant concentrations over Athens for each synoptic type, the synoptic circulation types were then correlated with both gaseous and particulate pollutant concentrations measured in each sector between 1983 and 1999. Finally, extreme and severe episodic events were studied in terms of their meteorological and synoptic characteristics.     

Interspecific differences in fouling of two congeneric ascidians (Eudistoma olivaceum and E. capsulatum): is surface acidity an effective defense?

Ascidian specimens were collected from the Indian River Lagoon, Florida, USA, in November 1987. Eudistoma olivaceum (Van Name) was fouled by only two species of epifaunal invertebrates and the percent cover of epibionts was negligible. Colonies of E. capsulatum (Van Name) were fouled by up to 17 species of epifaunal invertebrates, epibionts covered an average of 12.5% of the surface area of these colonies. Extracts of E. olivaceum exhibited potent cytotoxic, antimicrobial and antiviral activity in laboratory bioassays, while the activity of extracts of E. capsulatum was insignificant. The toxicity of extracts of each ascidian was negatively related to the percent cover of fouling organisms. Surface acidity of each ascidian was positively related to the percent cover of epibionts: E. olivaceum was nearly neutral (pH=6), while E. capsulatum was highly acidic (pH=1 to 2). Larval settlement and growth of ancestrulae of the cheilostome bryozoan Bugula neritina (Linnaeus) were inhibited at very low concentrations of crude extract of E. olivaceum. Crude extracts of E. capsulatum inhibited settlement and growth of B. neritina only at concentrations of approximately an order of magnitude greater than those of E. olivaceum. Differences in the degree to which these congeneric ascidians are fouled is related to differences in the chemical defenses they possess. Acidity is not an effective inhibitor of settlement by epifaunal invertebrates.     

Southwestern corn borer damage to maize: Influence of plant age at time of larval infestation

A maize (Zea mays L.) hybrid was infested with 30 southwestern corn borer [Diatraea grandiosella (Dyar)] larvae per plant at 4, 5, 6, 7 or 8 weeks after planting in a three-year study conducted at Mississippi State, Mississippi. Visual ratings of leaf feeding damage were highest when plants were infested 5 weeks after planting. Plant height increased linearly with the age of plants at infestation. Height of infested plants was significantly less than uninfested plants only when infestations were made 4 weeks after planting. The relationship between age of plants at infestation and yield was curvilinear. Yields were significantly reduced at all infestation times; however, the least yield reduction occurred when plants were infested 6 weeks after planting. To evaluate resistance to southwestern corn borer damage, infestation at 4 or 5 weeks after planting appeared to be most satisfactory. Yield reductions following infestation at 7 and 8 weeks after planting indicated that, when infestations are late, leaf feeding damage ratings alone may not be satisfactory indicators of plant damage.     

Engaging the community at the Tampakan Copper Project: a community case study in resource development with indigenous people

There is little doubt that one of the most significant challenges facing the mining industry today is how to deal with sociocultural issues, particularly those concerning indigenous groups who are potentially affected by mineral developments. No longer is a project's success dependent on technical and economic considerations alone. Community issues are now an integral component of overall project risk. For the mining industry, therefore, the establishment of positive, strong and transparent relationships with local communities is more than just a moral imperative; it makes good business sense. A case study of WMC's Tampakan Copper Project in the Philippines provides an illustration of how mining companies are developing their capacity to deal with sociocultural concerns.     

Social media and disasters: a functional framework for social media use in disaster planning,response, and research

A comprehensive review of online, official, and scientific literature was carried out in 2012–13 to develop a framework of disaster social media. This framework can be used to facilitate the creation of disaster social media tools, the formulation of disaster social media implementation processes, and the scientific study of disaster social media effects. Disaster social media users in the framework include communities, government, individuals, organisations, and media outlets. Fifteen distinct disaster social media uses were identified, ranging from preparing and receiving disaster preparedness information and warnings and signalling and detecting disasters prior to an event to (re)connecting community members following a disaster. The framework illustrates that a variety of entities may utilise and produce disaster social media content. Consequently, disaster social media use can be conceptualised as occurring at a number of levels, even within the same disaster. Suggestions are provided on how the proposed framework can inform future disaster social media development and research.