全文获取类型
收费全文 | 1304篇 |
免费 | 32篇 |
国内免费 | 18篇 |
专业分类
安全科学 | 54篇 |
废物处理 | 68篇 |
环保管理 | 130篇 |
综合类 | 279篇 |
基础理论 | 225篇 |
环境理论 | 1篇 |
污染及防治 | 352篇 |
评价与监测 | 144篇 |
社会与环境 | 81篇 |
灾害及防治 | 20篇 |
出版年
2023年 | 10篇 |
2022年 | 16篇 |
2021年 | 30篇 |
2020年 | 17篇 |
2019年 | 17篇 |
2018年 | 40篇 |
2017年 | 49篇 |
2016年 | 44篇 |
2015年 | 32篇 |
2014年 | 58篇 |
2013年 | 93篇 |
2012年 | 44篇 |
2011年 | 81篇 |
2010年 | 54篇 |
2009年 | 64篇 |
2008年 | 74篇 |
2007年 | 70篇 |
2006年 | 52篇 |
2005年 | 53篇 |
2004年 | 60篇 |
2003年 | 69篇 |
2002年 | 49篇 |
2001年 | 53篇 |
2000年 | 30篇 |
1999年 | 25篇 |
1998年 | 16篇 |
1997年 | 12篇 |
1996年 | 5篇 |
1995年 | 12篇 |
1994年 | 10篇 |
1993年 | 14篇 |
1992年 | 16篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 6篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1986年 | 5篇 |
1985年 | 8篇 |
1984年 | 4篇 |
1983年 | 8篇 |
1982年 | 8篇 |
1981年 | 4篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1976年 | 2篇 |
1970年 | 2篇 |
1962年 | 5篇 |
1961年 | 2篇 |
1938年 | 1篇 |
排序方式: 共有1354条查询结果,搜索用时 62 毫秒
111.
The photochemical transformation of natural estrogenic steroid 17beta-estradiol (E2) and the synthetic oral contraceptive 17alpha-ethinylestradiol (EE2) has been studied in dilute non buffered aqueous solution (pH 5.5-6.0) upon monochromatic (254 nm) and polychromatic (lambda>290 nm) irradiation. Upon irradiation at 254 nm, the quantum yields of E2 and EE2 photolysis were similar and evaluated to be 0.067+/-0.007 and 0.062+/-0.007, respectively. Upon polychromatic excitation, and by using phenol as chemical actinometer, the photolysis efficiencies have been determined to be 0.07+/-0.01 and 0.08+/-0.01 for E2 and EE2, respectively. For both estrogens, photodegradation by-products were identified with GC/MS and LC/MS. In a first step, a model compound--5,6,7,8-tetrahydro-2-naphthol (THN)--, which represents the photoactive phenolic group, was used to obtain basic photoproduct structural informations. Numerous primary and secondary products were observed, corresponding to hydroxylated phenolic- or quinone-type compounds. 相似文献
112.
Modelling of stable isotope fractionation by methane oxidation and diffusion in landfill cover soils 总被引:2,自引:0,他引:2
Mahieu K De Visscher A Vanrolleghem PA Van Cleemput O 《Waste management (New York, N.Y.)》2008,28(9):1535-1542
A technique to measure biological methane oxidation in landfill cover soils that is gaining increased interest is the measurement of stable isotope fractionation in the methane. Usually to quantify methane oxidation, only fractionation by oxidation is taken into account. Recently it was shown that neglecting the isotope fractionation by diffusion results in underestimation of the methane oxidation. In this study a simulation model was developed that describes gas transport and methane oxidation in landfill cover soils. The model distinguishes between (12)CH(4), (13)CH(4), and (12)CH(3)D explicitly, and includes isotope fractionation by diffusion and oxidation. To evaluate the model, the simulations were compared with column experiments from previous studies. The predicted concentration profiles and isotopic profiles match the measured ones very well, with a root mean square deviation (RMSD) of 1.7vol% in the concentration and a RMSD of 0.8 per thousand in the delta(13)C value, with delta(13)C the relative (13)C abundance as compared to an international standard. Overall, the comparison shows that a model-based isotope approach for the determination of methane oxidation efficiencies is feasible and superior to existing isotope methods. 相似文献
113.
Toluene removal biofilter modeling: Optimization and case study 总被引:1,自引:0,他引:1
Based on the model proposed by De Visscher and Van Cleemput for methane oxidation in landfill cover soils, a simulation model for biofiltration of toluene-contaminated air has been developed for biofilters with substrate inhibition. A convenient way to optimize biofilter performance was developed assuming Haldane kinetics. It was calculated that for a typical oilsands operation emitting 200 ton of toluene annually, 90% of the toluene can be removed by a 740 m3 biofilter, if the waste gas sent to the biofilter has a toluene concentration of 2.25 g m−3. The optimal initial concentration increases with increasing target efficiency. 相似文献
114.
Daniela Romano Domenico Gaudioso Riccardo De Lauretis 《Environmental monitoring and assessment》1999,56(1):51-74
The impact of air traffic on the global atmosphere is characterised by a high degree of uncertainty, concerning both the physico-chemical phenomena involved and the extent of the forcing due to anthropogenic emissions. The different effects of these emissions (e.g. on climate change, stratospheric ozone depletion, acidification, tropospheric ozone formation) are dealt with by different international bodies and conventions (e.g. IPCC, EMEP. . .) which are trying to define a standard methodology allowing countries to evaluate their contributions to global aircraft emissions and to report these figures in a standardised way. The paper compares different methodologies proposed by the joint EMEP/CORINAIR 'Atmospheric Emission Inventory Guidebook' for estimating aircraft emissions. Adjustments to these methodologies have been proposed, in order to integrate some additional data such as the total amount of flight hours per aircraft type or fuel consumption per trip. In case detailed information is not available, we recommend the use of a VERY SIMPLE methodology which may yield acceptable results, provided that every country makes adequate assumptions on the average aircraft type. 相似文献
115.
Stefano Loppi Stergios Arg. Pirintsos Vincenzo De Dominicis 《Environmental monitoring and assessment》1999,58(2):121-131
Total concentrations of Al, Ba, Cd, Co, Cr, Cu, Fe, Mn, Mo, Pb, Sr, Ti, V and Zn in the epiphytic lichen Parmelia sulcata and superficial soils from 60 remote sampling sites in Tuscany (central Italy) were determined to evaluate the contribution of soil to the elemental composition of the lichen. The results showed that in the Mediterranean environment, the trace element content of unwashed lichen samples is greatly affected by soil contamination. However, despite the strong correlations between the concentrations of lithogene elements such as Al, Fe and Ti in P. sulcata, lichen levels of these elements were not at all linearly correlated with their concentrations in the soil, suggesting that dust contamination is highly variable and probably dependent on local site characteristics. All methods evaluated to minimize soil contamination indicated Cu, Pb and Zn as elements of atmospheric origin. However, while levels of Pb were similar to those reported for background areas, moderate pollution by Cu and Zn, probably from fertilizers used in agriculture, was revealed. For elements such as Cd and Mo, identified as atmophile, some uncertainty exists due to the fact that they are essential for lichen metabolism and accumulate intracellularly in lichens; they may therefore occur in soluble form in the lichen thallus. 相似文献
116.
E. Gornung C. Cordisco A. Rossi De S. Innocentiis D. Crosetti L. Sola 《Marine Biology》2001,139(1):55-60
This study continues a comparative cytogenetic analysis of the fish family Mugilidae, reporting the karyotype characterization of the leaping mullet, Liza saliens, by C-banding, Ag- and fluorochrome-staining, and completing the fluorescence in situ hybridization (FISH)-mapping of the 18S and 5S rRNA genes (rDNA) to the chromosomes of the six Mediterranean mullets, namely L. saliens, L. ramada, L. aurata, Mugil cephalus, Chelon labrosus and Oedalechilus labeo. In all species, except M. cephalus, the 5S rDNA sites were localized on a medium-sized acrocentric chromosome pair, which was considered homeologous in all of them. In L. saliens, an additional 5S rDNA site was detected in a location close to the one shown by major ribosomal genes in M. cephalus, i.e. the subtelomeric region of chromosome pair 1. The 5S rDNA site in M. cephalus is located on the smallest chromosome pair of the complement, which, on the other hand, though on a different position, bears 18S rDNA in all the species of Liza and Chelon examined. The heterochromatin composition and the major and minor ribosomal gene locations suggest that the karyotype of L. saliens (subgenus Protomugil) can be considered intermediate between the karyotype of the more primitive M. cephalus and those of the other Liza (subgenus Liza) species and of the representatives of the more derived genera Chelon and Oedalechilus. 相似文献
117.
对承德市热电厂CG35/3.82-MX型循环流化术锅炉的脱硫除尘系统进行了改造,解决了原水膜除尘器效率低,烟法排放严重超标的问题,取得了良好的环境效益,社会效益和经济效益。 相似文献
118.
119.
Michel De Lara Eladio Oca?a Ricardo Oliveros-Ramos Jorge Tam 《Environmental Modeling and Assessment》2012,17(6):565-575
The World Summit on Sustainable Development (Johannesburg, 2002) encouraged the application of the ecosystem approach by 2010. However, at the same summit, the signatory States undertook to restore and exploit their stocks at maximum sustainable yield (MSY), a concept and practice without ecosystemic dimension, since MSY is computed species by species, on the basis of a monospecific model. Acknowledging this gap, we propose a definition of “ecosystem viable yields” (EVY) as yields compatible (a) with biological safety levels (over which biomasses can be maintained for all times) and (b) with an ecosystem dynamics. The difference from MSY is that this notion is not based on equilibrium but on viability theory, which offers advantages for robustness. For a generic class of multispecies models with harvesting, we provide explicit expressions for the EVY. We apply our approach to the anchovy–hake couple in the Peruvian upwelling ecosystem. 相似文献
120.
Collivignarelli C Tharnpoophasiam P Vaccari M De Felice V Di Bella V Mingkwan R 《Environmental monitoring and assessment》2008,147(1-3):191-198
University of Brescia and Mahidol University of Bangkok developed a project in Phang Nga province (Thailand), the most damaged by 2004 tsunami. In particular, the study, performed between April and May 2006, dealt with the surface and ground water monitoring in Ban Nam Khem village and the experimental evaluation of possible drinking treatment alternatives. The monitoring highlighted that saline content in the tsunami affected area is decreasing but still very high (conductivity presented values up to 2,600 and 6,230 microS/cm in ground and surface water, respectively); hence, advanced and complicated processes such as reverse osmosis should be adopted to treat such water for drinking purposes. Waiting for ground water salinity to assume acceptable values, activities for the reduction of its organic and microbiological contamination will be started. However, it has to be underlined that the diffusion of drinking water to a greater part of population can be obtained only through the realization of new centralised treatment plants and the improvement of existing ones (serving at the moment about 20% of inhabitants). 相似文献