Major ion chemistry and control of weathering of Bhimtal Lake, Humaun Himalaya, India

ＭａｊｏｒｉｏｎｃｈｅｍｉｓｔｒｙａｎｄｃｏｎｔｒｏｌｏｆｗｅａｔｈｅｒｉｎｇｏｆＢｈｉｍｔａｌＬａｋｅ，ＨｕｍａｕｎＨｉｍａｌａｙａ，Ｉｎｄｉａ￥ＭａｎｐｒｅｅｔＳｉｎｇｈ；Ｂ．Ｋ．Ｄａｓ（ＣｅｎｔｒｅｏｆＡｄｖａｎｃｅｄＳｔｕｄｙｉｎＧｅｏｌｏｇ...     

Effect of pH and temperature on the kinetics of odor oxidation using chlorine dioxide

Increasing public concerns over odors and air regulations in nonattainment zones necessitate the remediation of a wide range of volatile organic compounds (VOCs) generated in the poultry-rendering industry. Currently, wet scrubbers using oxidizing chemicals such as chlorine dioxide (ClO2) are utilized to treat VOCs. However, little information is available on the kinetics of ClO2 reaction with rendering air pollutants, limiting wet scrubber design and optimization. Kinetic analysis indicated that ClO2 does not react with hexanal and 2-methylbutanal regardless of pH and temperature and implied that aldehyde removal occurs primarily via mass transfer. Contrary to the aldehydes, ethanethiol or ethyl mercaptan (a model compound for methanethiol or methyl mercaptan) and dimethyl disulfide (DMDS) rapidly reacted with ClO2. The overall reaction was found to be second and third order for ethanethiol and DMDS, respectively. Moreover, an increase in pH from 3.6 to 5.1 exponentially increased the reaction rate of ethanethiol (e.g., k2 = 25-4200 L/mol/sec from pH 3.6 to 5.1) and significantly increased the reaction rate of DMDS if increased to pH 9 (k3 = 1.4 x 10(6) L2/mol2/sec). Thus, a small increase in pH could significantly improve wet scrubber operations for removal of odor-causing compounds. However, an increase in pH did not improve aldehyde removal. The results explain why aldehyde removal efficiencies are much lower than methanethiol and DMDS in wet scrubbers using ClO2.     

Wet scrubber analysis of volatile organic compound removal in the rendering industry

The promulgation of odor control rules, increasing public concerns, and U.S. Environmental Protection Agency (EPA) air regulations in nonattainment zones necessitates the remediation of a wide range of volatile organic compounds (VOCs) generated by the rendering industry. Currently, wet scrubbers with oxidizing chemicals are used to treat VOCs; however, little information is available on scrubber efficiency for many of the VOCs generated within the rendering process. Portable gas chromatography/mass spectrometry (GC/MS) units were used to rapidly identify key VOCs on-site in process streams at two poultry byproduct rendering plants. On-site analysis was found to be important, given the significant reduction in peak areas if samples were held for 24 hr before analysis. Major compounds consistently identified in the emissions from the plant included dimethyl disulfide, methanethiol, octane, hexanal, 2-methylbutanal, and 3-methylbutanal. The two branched aldehydes, 2-methylbutanal and 3-methylbutanal, were by far the most consistent, appearing in every sample and typically the largest fraction of the VOC mixture. A chlorinated hydrocarbon, methanesulfonyl chloride, was identified in the outlet of a high-intensity wet scrubber, and several VOCs and chlorinated compounds were identified in the scrubbing solution, but not on a consistent basis. Total VOC concentrations in noncondensable gas streams ranged from 4 to 91 ppmv. At the two plants, the odor-causing compound methanethiol ranged from 25 to 33% and 9.6% of the total VOCs (v/v). In one plant, wet scrubber analysis using chlorine dioxide (ClO2) as the oxidizing agent indicated that close to 100% of the methanethiol was removed from the gas phase, but removal efficiencies ranged from 20 to 80% for the aldehydes and hydrocarbons and from 23 to 64% for total VOCs. In the second plant, conversion efficiencies were much lower in a packed-bed wet scrubber, with a measurable removal of only dimethyl sulfide (20-100%).     

Automobile recycling in the United States: Energy impacts and waste generation

Changes in the trends in the material composition of domestic and imported automobiles and the increasing cost of landfilling the non-recyclable portion of automobiles (automobile shredder residue or ASR) pose questions about the future of automobile recycling in the United States. In response to these challenges, new and innovative approaches to automobile recycling are being developed. This paper presents the findings of a recent study to examine the impacts of these changes on the life cycle energy consumption of automobiles and on the quantity of waste that must be disposed of. Given the recycle status quo, trends in material composition and the viability of recycling the non-metallic components of the typical automobile are of secondary importance when compared to the energy consumed during the life of the automobile. The energy savings resulting from small changes in the fuel efficiency of a vehicle overshadow potential energy losses associated with the adoption of new and possibly non-recyclable materials. Under status quo conditions, the life cycle energy consumed by the typical automobile is projected to decrease from 599 million Btus in 1992 to 565 million Btus in 2000. Energy consumed during the manufacture of the typical car will increase from about 120 to 140 million Btus between 1992 and 2000, while energy used during vehicle operation will decrease from 520 to 480 million Btus. This study projects that energy saved at the recycle step will increase from 41 million Btus in 1992 to 55 million Btus in 2000. This study also investigated the energy impacts of several potential changes to the recycle status quo, including the adoption of technologies to retrieve the heat value of ASR by incineration and the recycle of some or all thermoplastics in the typical automobile. The study estimates that under optimistic conditions —i.e., the recycling of all thermoplastics and the incineration with heat recovery of all remaining ASR —about 8 million Btus could be saved per automobile —i.e., an increase from about 55 to 63 million Btus. In the more realistic scenario —i.e., the recycling of easy-to-remove thermoplastic components (bumper covers and dash-boards) —the potential energy savings are about 1 million Btus per vehicle. It is estimated that the annual quantity of ASR in the United States could be reduced from about 5 billion pounds to as little as 1 billion pounds of ash if all ASR is incinerated. Alternatively, ASR quantity could be reduced to about 4 billion pounds if all thermoplastics in automobiles are recycled. However, in the case of recycling only thermoplastic bumper covers and dashboards, the quantity of ASR would be reduced by only 0.2 billion pounds. A significant reduction or increase in the size of the ASR waste stream will not in itself have a large impact on the solid waste stream in the United States.     

Using conditional inference forests to identify the factors affecting crash severity on arterial corridors

Introduction

The study aims at identifying traffic/highway design/driver-vehicle information significantly related with fatal/severe crashes on urban arterials for different crash types. Since the data used in this study are observational (i.e., collected outside the purview of a designed experiment), an information discovery approach is adopted for this study.

Method

Random Forests, which are ensembles of individual trees grown by CART (Classification and Regression Tree) algorithm, are applied in numerous applications for this purpose. Specifically, conditional inference forests have been implemented. In each tree of the conditional inference forest, splits are based on how good the association is. Chi-square test statistics are used to measure the association. Apart from identifying the variables that improve classification accuracy, the methodology also clearly identifies the variables that are neutral to accuracy, and also those that decrease it.

Results

The methodology is quite insightful in identifying the variables of interest in the database (e.g., alcohol/ drug use and higher posted speed limits contribute to severe crashes). Failure to use safety equipment by all passengers and presence of driver/passenger in the vulnerable age group (more than 55 years or less than 3 years) increased the severity of injuries given a crash had occurred. A new variable, ‘element’ has been used in this study, which assigns crashes to segments, intersections, or access points based on the information from site location, traffic control, and presence of signals.

Impact

The authors were able to identify roadway locations where severe crashes tend to occur. For example, segments and access points were found to be riskier for single vehicle crashes. Higher skid resistance and k-factor also contributed toward increased severity of injuries in crashes.     

Logistic regression model for prediction of roof fall risks in bord and pillar workings in coal mines: An approach

The roof fall hazards are the major problems in underground coal mines, which are generally unpredictable due to the associated uncertainties arising out of the complexity of geological conditions and variability in mining parameters. During the six year period, 1996–2001, 253 Indian coal miners lost their lives and 401 are seriously injured in 490 different roof fall accidents. In India, 32.7% of the total fatal injuries in coal sectors are due to roof fall in bord and pillar method of workings. This paper attempts to predict the severities of roof fall accidents based on some major contributing parameters using the binary logistic regression model. In total, 128 roof fall accidents for the last few years from five underground coal mines in India having bord and pillar method of working are analyzed for this study. The results revealed that wider gallery width is more prone to major and serious accidents than narrower gallery width. Thin seams are more amenable to major accidents in comparison to thick seams. Unsupported or partially supported roofs have higher risk for contributing major as well as serious accidents. Deep workings are more prone to major accidents as compared to shallow depth workings.     

Comparison between availability of heavy metals in dry and wetland tailing of an abandoned copper tailing pond

Wetland sediments are generally considered as a sink for metals and, in the anoxic zone, may contain very high concentrations of heavy metals in reduced state. A comprehensive study was carried out to compare the differences of total, environmentally available (Env-Av), HOAC, EDTA and DTPA available heavy metal fraction in tailing of the marshy area of a copper tailing pond and the dry tailing. The average concentrations of all the seven metals in the wetland tailing were found higher than dry tailing. Regarding pH, organic carbon, availailable N, P and K also found higher in marshy wetland tailing compare to the dry tailing. This information is needed in order to understand wetland system and to assure that wetlands do not themselves eventually become sources of metal contamination to surrounding areas. But as levels of pollutants increases, the ability of a wetland system to incorporate waste can be impaired and the wetland can become a source of toxicity.     

Effect of pendimethalin and quizalofop on N<Subscript>2</Subscript>-fixing bacteria in relation to availability of nitrogen in a <Emphasis Type="Italic">Typic Haplustept</Emphasis> soil of West Bengal,India

An experiment was conducted under laboratory conditions to investigate the effect of two systemic herbicides viz., pendimethalin and quizalofop, at their recommended field rates (1.0 kg and 50 g active ingredient ha^− 1, respectively) on the growth and activities of non-symbiotic N₂-fixing bacteria in relation to mineralization and availability of nitrogen in a Typic Haplustept soil. Both the herbicides, either singly or in a combination, stimulated the growth and activities of N₂-fixing bacteria resulting in higher mineralization and availability of nitrogen in soil. The single application of quizalofop increased the proliferation of aerobic non-symbiotic N₂-fixing bacteria to the highest extent while that of pendimethalin exerted maximum stimulation to their N₂-fixing capacity in soil. Both the herbicides, either alone or in a combination, did not have any significant difference in the stimulation of total nitrogen content and availability of exchangeable NH₄ ⁺ while the solubility of NO₃ ⁻ was highly manifested when the herbicides were applied separately in soil.