Potentiometric studies of mixed complexes of cobalt(II) and copper(II) with l‐Asparagine and adenine

A potentiometric titration technique has been used to determine the stability constants for the various complexes of Co(II) and Cu(II) with L‐asparagine and from DNA base, e.g. adenine. Stability constants of ternary systems have been evaluated by the method suggested by Irwing‐Rossotti. In addition, the conditional constants were calculated as a function of pH. The maximum values of the conditional formation constants were found to be in accordance with the mixed‐ligand complex formation constants in a determined pH region. Furthermore, the molar fractions of different species from mixed complexes were calculated by means of formation constants. The values of stability constants of mixed‐ligand complexes at 25°C are as follows: log K= 5.25 for Co(II)‐L‐asparagine‐adenine; log K= 9.30 for Cu(II)‐L‐asparagine‐adenine. The ionic strength was kept constant at I = 0.20 with NaClO₄.     

Impacts of repeated timber skidding on the chemical properties of topsoil, herbaceous cover and forest floor in an eastern beech (Fagus orientalis Lipsky) stand

In this study, long-term timber skidding effects on herbaceous understory forest floor and soil were investigated on a skid road in a stand of the eastern beech (Fagus orientalis Lipsky). For this purpose, herbaceous understory forest floor and soil samples were collected from the skid road and from an undisturbed area used as a control plot. The mass (kg ha(-1)) of herbaceous and forest floor samples was determined, and soil characteristics were examined at two depths (0-5 cm and 5-10 cm). We quantified sand, silt and clay content, as well as bulk density compaction, pH, and organic carbon content in soil samples. The quantities of N, K, P, Na, Ca, Mg, Fe, Mn, Zn and Cu were determined in all herbaceous cover forest floor and soil samples. The quantities of Na, Fe, Zn, Cu and Mn in herbaceous understory samples from the skid road were considerably higher than those in the undisturbed area, while the quantity of Mg was considerably lower. These differences could have been caused by decreased herbaceous cover in addition to variations in the properties of the forest floor and soil after skidding. A lower amount of forest floor on the skid road was the result of skidding and harvesting activities. Mg and Zn contents in forest floor samples were found to be considerably lower for the skid road than for the undisturbed area. No significant differences were found in soil chemical properties (quantities of N, P, K, Na, Ca, Mg, Fe, Zn, Cu and Mn) at the 0-5 cm soil depth. Important differences exist between soil quantities of Mg at a 5-10 cm depth on the skid road and in undisturbed areas. Both 0-5 cm and 5-10 cm soil depths, the average penetrometer resistance values for the skid road was higher than for the undisturbed area. This result shows that the compaction caused by skidding is maintained to depth of 10 cm. Skid road soil showed higher bulk density values than undisturbed areas because of compaction.     

Solidification/stabilization of landfill leachate concentrate using different aggregate materials

The application of reverse osmosis for the treatment of landfill leachate is becoming widespread in Turkey as well as in Europe. A major drawback of this process is the production of concentrate, which could be as much as 30% of the feed stream, and high concentrations of salts and contaminants. The reverse osmosis concentrate is disposed of by using several methods including re-infiltration, drying, incineration and solidification/stabilization. In this study, solidification/stabilization (S/S) technology was studied for the treatment of reverse osmosis concentrate produced from landfill leachate. In order to benefit from its capability to absorb heavy metals, ammonia and some other pollutants, zeolite and different aggregate materials were used in solidification experiments. Main pollutants in the leachate concentrate, TOC, DOC, TDS and ammonia were successfully solidified and approximately 1% of TOC, DOC, TDS and ammonia remained in the eluate water. The results indicated that the landfill disposal limits could be attained by solidification/stabilization process.     

Effect of diurnal changes in VOC source strengths on performances of receptor models

Introduction

The effect of diurnal changes in strengths of volatile organic compound (VOC) sources on the performances of positive matrix factorization (PMF) and principal component analysis (PCA) was investigated using ambient measurement results that were taken during daytime and nighttime hours between March 24 and May 14, 2011, within Davutpasa Campus of Yildiz Technical University (Istanbul, Turkey).

Methods

Forty-five VOC species, ranging from C₅ to C₁₁ in volatility, were measured in the samples, 40 of which are included in the analyses. Ambient samples were grouped as daytime, nighttime, and all day datasets, and both PMF and PCA were applied to each dataset. A total of six source groups were extracted from each dataset: solvent use, general industrial paint use, gasoline and diesel vehicle exhausts, and biogenic as well as evaporative emissions. Estimated source contributions showed great diurnal variations.

Results

The results suggested that extraction of possible sources by PCA depends greatly on the number of samples and the strength of the sources, while PMF produced stable results regardless of number of samples and source strengths.

Conclusion

Although PMF was unable to resolve gasoline vehicle and evaporative emissions, it was found to be successful in explaining diurnal fluctuations in source strengths, while the performance of PCA depends on the strength of emission source.     

Inhibition effects of some pesticides and heavy metals on carbonic anhydrase enzyme activity purified from horse mackerel (Trachurus trachurus) gill tissues

Environmental Science and Pollution Research - The gill tissue is the main site of metabolic enzymes or compensation, with the kidney tissue playing a supporting role. At the gill tissue, carbonic...     

Determination of heavy metal concentrations in street dusts in Istanbul E-5 highway

Components and quantity of street dust are environmental pollution indicators especially in big cities. Street dust is generally composed of car exhaust gas originated particles and wind-transported particles. Heavy metals, which are found in street dust, such as Pb, Cu, Mn, Zn, Cd and Ni are significant for environmental pollution. According to the kind of vehicle in traffic, quantity and type of heavy metals vary in street dust. The use of leaded gasoline gives a boost to the importance of lead level especially in street dust even at the start of 21st century. These metals possess bioaccumulation property, and the possibility of the amount of these metals reaching a critical value and threatening human health increases the importance of this issue. In this study, street dusts have been collected from E-5 Highway from Topkapi to Avcilar regions that spans about 18 km in Istanbul, Turkey, and Pb, Cu, Mn, Zn, Cd and Ni concentrations have been detected in street dust. Twenty-two street dust samples were taken from a total of 22 different points at previously decided 14 main areas. Analyses were conducted using Leeds Public Analyst method. According to the results of this study, Pb, Cu and Zn concentrations in E-5 Highway between Topkapi and Avcilar region in Istanbul were higher than maximum concentration levels of these heavy metals in normal soil. This situation indicates that there is heavy metal pollution in the inspected area in E-5 Highway in Istanbul.     

Decolorization of remazol yellow RR gran by white rot fungus Phanerochaete chrysosporium

In this study, the removal of color, chemical oxygen demand (COD) and aromatic group from one of the azo dyes, Remazol Yellow RR Gran, had been carried out by using one of the white rot fungi, Phanerochaete chrysosporium. Experimental studies were performed in growth media containing different amounts of dye and glucose. Color measurements were done at 436nm wavelength using spectrophotometer while aromatic group measurements were done at 280 nm wavelength using UV/Visible spectrophotometer. As a result of this study the values of the removable color concentration were determined as 10 mgl(-1) and lower. The optimum medium glucose concentration was determined to be 2 gl(-1) during color removal processes, aromatic group measurements were done in samples in the UV region at 280 nm wavelength. As a result of the measurements, it was shown that certain amount of aromatic group remained in the model wastewater at the end of the process.     

Addressing the operational problems in a composting and recycling plant

The Istanbul composting and recycling plant, constructed in 2001, is one of the few composting plants in Turkey. During test operations of the plant, it was reported that the weight of the oversize materials (OM) above a 80-mm sieve was about 40% of the total incoming waste. They mainly consist of plastic bags that were full of garbage, which resulted in operational problems in the plant. In this paper, the composition of OM was determined and evaluated, particularly to find the economic losses in the plant. It was determined that approximately 58% of the OM transferred to the landfill area due to operational failures and interruptions could be used at the plant with improved operational conditions. Otherwise, the plant would realize an annual economic loss of about 640,800 US$. Compost quality in the plant has been satisfactory, but source separated collection, at least the separation of the wet from the dry fraction, is needed to increase the amount of compost and recovered materials.     

The impact of pretreatment and inoculum to substrate ratio on methane potential of organic wastes from various origins

Biochemical methane potentials (BMP) of two different substrates from macroalgae (MA) and market place wastes (MPW) were investigated using anaerobic granulated sludge from food industry with different ratios of substrate to inoculum (S/X). The substrates were used as MA only, MPW only, MA–MPW mixture, pretreated MA, and pretreated MA–MPW mixture. Research involved investigation of the effects of parameters such as temperature (35, 45, and 55 °C), substrate to inoculum ratio (S/X = 0.5, 2.0, 4.0, and 6.0 as g VS_substrate/g VS_inoculum), and the type of pretreatment (by microwave, thermal, and ultrasonic) on BMP. BMP assays were performed for all substrates. The highest cumulative biogas production (and BMP) were obtained for MA only at an S/X ratio of 4.0 g VS/g VS as 357 L_biogas/kg VS (197 L CH₄/kg VS) and 33 L_biogas/kg VS (17 L CH₄/kg VS), respectively, at 35 and 55 °C. For pretreated substrates, the highest cumulative biogas production and BMP were observed as 287 L_biogas/kg VS and 146 L CH₄/kg VS using pretreated macroalgae at 35 °C. Results suggested that MA only and MA–MPW mixtures are suitable substrates for biogas production. It is also concluded that any type of pretreatment has adverse effects on biogas and methane productions.     

Impacts of seawater intrusion on soil salinity and alkalinity in Bafra Plain, Turkey

This study was carried out to investigate possible seawater intrusion into groundwater along the coastal lines of the Bafra Plain and salinity–alkalinity problems over land areas irrigated with water exposed to seawater intrusion were evaluated. For this purpose, 32 groundwater wells were selected over the plain, water samples were taken from these wells between October 2007 and September 2008, and chemical analyses were performed over these samples. Soil samples were taken from the fields irrigated with this water at 32 different locations at the end of the irrigation season in September 2008 from 0–30, 30–60, 60–90, and 90–120 cm soil depths and textures. EC, pH, Na, Ca, Mg, and K analyses were performed over these samples. Excessive seawater intrusion was observed in some parts of the plain and impacts of seawater intrusion decreased with the distance from the coastal line. It was determined that groundwater quality was significantly affected from seawater intrusion. Salinity and especially alkalinity problems were observed in land areas irrigated with this water and alkalinity increased with the rate of intrusion.