原子吸收光谱分析技术在环境,医学卫生和食品分析方面的应用

回顾了原子吸收光谱分析在我国环境、医学卫生和食品分析方面的应用概况。     

双膜技术在印染废水回用工程的应用

以盛虹集团印染废水回用工程为例,分析了＂SMF＋HAPRO＂双膜技术在印染废水深度处理中的应用。应用情况表明,印染废水经该技术处理后,产水水质优良,满足了生产用水的要求,同时给应用企业带来了经济、环境和社会效益。     

Current Status and Problems in Certification of Sustainable Forest Management in China

Forest certification is a mechanism involving the regulation of trade of forest products in order to protect forest resources and improve forest management. Although China had a late start in adopting this process, the country has made good progress in recent years. As of July 31, 2009, 17 forest management enterprises and more than one million hectares of forests in China have been certified by the Forest Stewardship Council (FSC). Several major factors affect forest certification in China. The first set is institutional in nature. Forest management in China is based on centralized national plans and therefore lacks flexibility. A second factor is public awareness. The importance and value of forest certification are not widely understood and thus consumers do not make informed choices regarding certified forest products. The third major factor is the cost of certification. Together these factors have constrained the development of China’s forest certification efforts. However, the process does have great potential. According to preliminary calculations, if 50% of China’s commercial forests were certified, the economic cost of forest certification would range from US$0.66–86.63 million while the economic benefits for the forestry business sector could exceed US$0.66–86.63 million while the economic benefits for the forestry business sector could exceed US150 million. With continuing progress in forest management practices and the development of international trade in forest products, it becomes important to improve the forest certification process in China. This can be achieved by improving the forest management system, constructing and perfecting market access mechanisms for certificated forest products, and increasing public awareness of environmental protection, forest certification, and their interrelationship.     

Forest Ecosystem Services and Eco-Compensation Mechanisms in China

Forests are a major terrestrial ecosystem providing multiple ecosystem services. However, the importance of forests is frequently underestimated from an economic perspective because of the externalities and public good properties of these services. Forest eco-compensation is a transfer mechanism that serves to internalize the externalities of forest ecosystem services by compensating individuals or companies for the losses or costs resulting from the provision of these services. China’s current forest eco-compensation system is centered mainly on noncommercial forest. The primary measures associated with ecosystem services are (1) a charge on destructive activities, such as indiscriminate logging, and (2) compensation for individual or local activities and investments in forest conservation. The Compensation Fund System for Forest Ecological Benefits was first listed in the Forest Law of the People’s Republic of China in 1998. In 2004, the Central Government Financial Compensation Fund, an important source for the Compensation Fund for Forest Ecological Benefits, was formally established. To improve the forest eco-compensation system, it is crucial to design and establish compensation criteria for noncommercial forests. These criteria should take both theoretical and practical concerns into account, and they should be based on the quantitative valuation of ecosystem services. Although some initial headway has been made on this task, the implementation of an effective forest eco-compensation system in China still has deficiencies and still faces problems. Implementing classification-based and dynamic management for key noncommercial forests and establishing an eco-compensation mechanism with multiple funding sources in the market economy are the key measures needed to conquer these problems and improve the forest eco-compensation system and China’s forestry development in sequence.     

Ligand-assisted degradation of carbon tetrachloride by microscale zero-valent iron

Degradation of carbon tetrachloride (CT) by microscale zero-valent iron (ZVI) was investigated in batch systems with or without organic ligands (ethylenediaminetetraacetic acid (EDTA), citric acid, tartaric acid, malic acid and oxalic acid) at pHs from 3.5 to 7.5. The results demonstrated that at 25°C, the dechlorination of CT by microscale ZVI is slow in the absence of organic ligands, with a pseudo-first-order rate constant of 0.0217 h(-1) at pH 3.5 and being further dropped to 0.0052 h(-1) at pH 7.5. However, addition of organic ligands significantly enhanced the rates and the extents of CT removal, as indicated by the rate constant increases of 39, 31, 32, 28 and 18 times in the presence of EDTA, citric acid, tartaric acid, malic acid and oxalic acid, respectively, at pH 3.5 and 25°C. The effect of EDTA was most significant; the dechlorination of CT at an initial concentration of 20 mg l(-1) increased from 16.3% (no ligands) to 89.1% (with EDTA) at the end of 8h reaction. The enhanced CT degradation in the presence of organic ligands was primarily attributed to the elimination of a surface passivation layer of Fe(III) (hydr)oxides on the microscale ZVI through chelating of organic ligands with Fe(III), which maintained the exposure of active sites on ZVI surface to CT.     

人工神经网络用于铅的化学形态模拟计算

用前馈线性网络法求解水体系中Ｐｂ（２＋）与ＯＨ－之间的反应常数，不同训练算法对求解结果的精度、收敛速度及权值均有影响．结果表明，批处理算法的精度最好，权值不出现负值，但运算时间最长；在线算法的精度虽不如批处理算法，而比数据变换－在线算法好，权值有时会出现负值．运算时间较长；数据变换－在线算法的优点是运算时间短，但相对误差较大，权值出现负值的机会多。采用反馈网络模拟计算铅的各种化学形态的浓度．用物料核算的方法对反馈网络模型进行检验表明，此种模型用于平衡计算是可行的，详细分析了理论模拟和实验曲线的差异的原因，温度的影响最小，在４＜ｐＨ＜９时，ＣＯ有重要的影响．在国代检验时，ｎ值取整所引入的误差的影响亦不可忽视。从本文的结果可以看到，采用前馈网络和反馈网络相结合的方法考察水体中的化学形态是可行的．从而为解决这一类问题提供了一种可能的途径．     

不同源类型农业非点源负荷特征研究——以新田小流域为例

以珠江三角洲北部新田小流域为研究对象,采用源类型法,在流域范围内建立林地、果园、旱地和水田四个全封闭的农业用地单元,并对四个单元出口处的径流量进行同步采样,分析COD、BOD、氨氮、总氮和总磷等污染物的负荷特征.结果表明:(1)流域地表水存在着明显非点源污染现象,不同源类型,地表径流的污染程度不同.(2)不同源类型农业非点源污染负荷强度不同,其中水田、旱地单位面积非点源负荷强度较大,果园、林地各项污染物的负荷强度相对最小.受地表扰动、施肥等人类活动影响,流域内水田、旱地是农业非点源污染发生的关键源区.(3)流域范围内,不同源类型农业非点源负荷总量不同,其中,果园各项污染物非点源负荷总量最大,其次是林地,水田、旱地非点源负荷输出总量较小,流域范围内,源面积成为影响非点源负荷总量的主要因素.(4)相应的非点源污染治理不仅是关键源区,同时应关注大面积流失区.     

有机酸对铬超富集植物李氏禾吸收Cu的影响

许多研究表明有机酸的施加对植物吸收重金属的量具有不同的影响.文章采用盆栽试验研究了EDTA、柠檬酸、草酸和酒石酸对土壤中Cu的活化和李氏禾(Leersia hexandra Swartz)吸收Cu的影响.结果表明,当向土壤中施加质量摩尔浓度为2 mmol·kg-1的EDTA时,土壤中Cu质量分数为220.16 mg·kg-1与空白土壤中500.31 mg·kg-1相比明显减少,说明EDTA可以极显著的降低土壤中的铜质量分数,使其转化成水提取态的Cu浮于土壤表面,并大部分聚集在根部周围,同时向土壤中施加EDTA不但促进了对Cu的活化而且显著提高了李氏禾对Cu的吸收,叶中最高质量分数达到336.54 mg·kg-1是对照中80.34 mg·kg-1的四倍;而柠檬酸、草酸和酒石酸则抑制了Cu的活化,但对李氏禾地上部分的Cu质量分数影响不大.有机酸对Cu的影响相对较弱,除EDTA显著降低了土壤中Cu质量分数外,其他有机酸对Cu的活化和李氏禾吸收Cu的影响与对照均没有明显差异.     

Ethylenediamine-modified activated carbon for aqueous lead adsorption

This study is to develop a carbon-based adsorbent containing multiple functional ligands for effective removal of lead ions from aqueous media. Activated carbon was oxidized by nitric acid, followed by chlorination with thionyl chloride and reaction with ethylenediamine. Modified activated carbon (MAC) was characterized using scanning electron microscopy in conjunction of energy dispersive spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy (FT-IR), and potentiometric titration. Surface characterizations confirmed that carboxyl, amine, and chlorine functional groups were effectively introduced onto the carbon surface by the treatments. The modifications lowered the pH at the point of zero charge (pH_pzc) from 9.6 to 2.55 and resulted in more negatively charged surfaces. Adsorptive experiments showed that aqueous Pb removal by MAC was faster, with a 62% higher capacity than the original activated carbon (60.2 vs. 37.2 mg g⁻¹).     

钢渣掺量对泡沫混凝土砌块性能的影响

泡沫混凝土是一种环保、节能的保温隔热材料,以其优良的保温性能,受到越来越多研究者的关注。对钢渣的特性进行了分析测试,对钢渣不同掺量对泡沫混凝土砌块特性的影响进行了研究,结果表明,采用添加5％～35％钢渣所制备的钢渣泡沫混凝土砌块,其密度等级为JC／T1062—2007中的B10级,掺人5％、15％钢渣的泡沫混凝土抗压强度达到A3．5等级,掺人25％、35％钢渣的泡沫混凝土抗压强度达到A2．5等级。随着钢渣掺量的增大,抗压强度、抗折强度降低,吸水率增大。在同一钢渣掺量的情况下,泡沫混凝土砌块的抗压强度变化率增加显著,而且随着钢渣的加入量升高而增大。钢渣的加入有利于提高泡沫混凝土砌块的后期抗压强度。