全文获取类型
收费全文 | 502篇 |
免费 | 11篇 |
国内免费 | 9篇 |
专业分类
安全科学 | 21篇 |
废物处理 | 13篇 |
环保管理 | 138篇 |
综合类 | 50篇 |
基础理论 | 92篇 |
污染及防治 | 130篇 |
评价与监测 | 46篇 |
社会与环境 | 21篇 |
灾害及防治 | 11篇 |
出版年
2021年 | 6篇 |
2020年 | 1篇 |
2019年 | 5篇 |
2018年 | 4篇 |
2017年 | 6篇 |
2016年 | 8篇 |
2015年 | 14篇 |
2014年 | 15篇 |
2013年 | 65篇 |
2012年 | 20篇 |
2011年 | 22篇 |
2010年 | 20篇 |
2009年 | 17篇 |
2008年 | 21篇 |
2007年 | 27篇 |
2006年 | 25篇 |
2005年 | 20篇 |
2004年 | 13篇 |
2003年 | 19篇 |
2002年 | 13篇 |
2001年 | 9篇 |
2000年 | 11篇 |
1999年 | 8篇 |
1998年 | 6篇 |
1997年 | 5篇 |
1996年 | 4篇 |
1995年 | 9篇 |
1994年 | 12篇 |
1993年 | 9篇 |
1992年 | 7篇 |
1991年 | 8篇 |
1990年 | 7篇 |
1989年 | 4篇 |
1988年 | 7篇 |
1987年 | 4篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 9篇 |
1982年 | 8篇 |
1981年 | 8篇 |
1980年 | 11篇 |
1979年 | 8篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1973年 | 2篇 |
1971年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有522条查询结果,搜索用时 375 毫秒
91.
Charles E. Billings Leslie Silverman Richard Dennis Lester H. Levenbaum 《Journal of the Air & Waste Management Association (1995)》2013,63(4):318-330
The trends in and relationships between ambient air concentrations of sulfur dioxide and sulfate aerosols at 48 urban sites and 27 nonurban sites throughout the U.S. between 1963 and 1972 have been analyzed. The substantial decreases in ambient SO2 concentrations measured at urban sites in the eastern and midwestern U.S. are consistent with the corresponding reductions in local SO2 emissions, but these decreases have been accompanied by only modest decreases in ambient sulfate concentrations. Large differences in the amounts of SO2 emitted within individual air quality control regions are associated with much smaller differences in the corresponding ambient sulfate concentrations. Substantial changes in the patterns of SO2 emissions between air quality regions result in essentially no differences between ambient sulfate concentrations in those air quality regions. Comparisons of several air quality regions in the eastern and western U.S. with similar SO2 emission levels and patterns of emissions clearly demonstrates the higher ambient sulfate concentration levels in eastern air quality control regions. Relationships between SO2, sulfates, and vanadium concentrations at eastern nonurban U.S. sites cannot be explained by local emission sources. These various observed results can be best explained by long distance sulfur oxide transport with chemical conversion of SO2 to sulfates occurring over ranges of hundreds of kilometers. This conclusion has been suggested earlier and the present analysis strongly supports previous discussions. An impact of long range transport of sulfates is to emphasize the need for Consistent strategies for reduction of sulfur oxides throughout large geographical regions. Additions of large capacities involving elevated sources in mid-continental or western regions could result in significant increases in sulfate concentrations well downwind of such sources. Some of the types of research activities required to quantitate crucial experimental parameters are discussed. 相似文献
92.
Watts RJ Finn DD Cutler LM Schmidt JT Teel AL 《Journal of contaminant hydrology》2007,91(3-4):312-326
The stabilization of hydrogen peroxide was investigated as a basis for enhancing its downgradient transport and contact with contaminants during catalyzed H(2)O(2) propagations (CHP) in situ chemical oxidation (ISCO). Stabilization of hydrogen peroxide was investigated in slurries containing four characterized subsurface solids using phytate, citrate, and malonate as stabilizing agents after screening ten potential stabilizers. The extent of hydrogen peroxide stabilization and the most effective stabilizer were solid-specific; however, phytate was usually the most effective stabilizer, increasing the hydrogen peroxide half-life to as much as 50 times. The degree of stabilization was nearly as effective at 10 mM concentrations as at 250 mM or 1 M concentrations. The effect of stabilization on relative rates of hydroxyl radical activity varied between the subsurface solids, but citrate and malonate generally had a greater positive effect than phytate. The effect of phytate, citrate, and malonate on the relative rates of superoxide generation was minimal to somewhat negative, depending on the solid. The results of this research demonstrate that the stabilizers phytate, citrate, and malonate can significantly increase the half-life of hydrogen peroxide in the presence of subsurface solids during CHP reactions while maintaining a significant portion of the reactive oxygen species activity. Use of these stabilizers in the field will likely improve the delivery of hydrogen peroxide and downgradient treatment during CHP ISCO. 相似文献
93.
Lemly AD 《Environmental monitoring and assessment》2007,125(1-3):361-375
This paper gives step-by-step instructions for assessing aquatic selenium hazards associated with mining. The procedure was
developed to provide the U.S. Forest Service with a proactive capability for determining the risk of selenium pollution when
it reviews mine permit applications in accordance with the National Environmental Policy Act (NEPA). The procedural framework
is constructed in a decision-tree format in order to guide users through the various steps, provide a logical sequence for
completing individual tasks, and identify key decision points. There are five major components designed to gather information
on operational parameters of the proposed mine as well as key aspects of the physical, chemical, and biological environment
surrounding it — geological assessment, mine operation assessment, hydrological assessment, biological assessment, and hazard
assessment. Validation tests conducted at three mines where selenium pollution has occurred confirmed that the procedure will
accurately predict ecological risks. In each case, it correctly identified and quantified selenium hazard, and indicated the
steps needed to reduce this hazard to an acceptable level. By utilizing the procedure, NEPA workers can be confident in their
ability to understand the risk of aquatic selenium pollution and take appropriate action. Although the procedure was developed
for the Forest Service it should also be useful to other federal land management agencies that conduct NEPA assessments, as
well as regulatory agencies responsible for issuing coal mining permits under the authority of the Surface Mining Control
and Reclamation Act (SMCRA) and associated Section 401 water quality certification under the Clean Water Act. Mining companies
will also benefit from the application of this procedure because priority selenium sources can be identified in relation to
specific mine operating parameters. The procedure will reveal the point(s) at which there is a need to modify operating conditions
to meet environmental quality goals. By recognizing concerns early in the NEPA process, it may be possible for a mining company
to match operational parameters with environmental requirements, thereby increasing the likelihood that the permit application
will be approved. 相似文献
94.
Sather ME Slonecker ET Mathew J Daughtrey H Williams DD 《Environmental monitoring and assessment》2007,124(1-3):211-221
Nitrogen Dioxide (NO2) is a common urban air pollutant that results from the combustion of fossil fuels. It causes serious human health effects,
is a precursor to the formation of ground level ozone, another serious air pollutant, and is one of the six criteria air pollutants
established by the United States (U.S.) Clean Air Act (CAA). Ogawa Passive Sampling Devices (PSDs) for NO2 were collocated and operated at six NO2 Federal Reference Method (FRM) monitor locations in the El Paso, Texas area for the 2004 calendar year. Passive samples were
taken at 2-week, 3-week, and 4-week intervals and compared against the continuously operating FRM monitors. Results showed
that the collective NO2 annual arithmetic mean for all passive monitors was identical to the NO2 mean for all FRM monitors. Of the individual locations, three passive annual NO2 means were identical to their corresponding FRM means, and three passive annual NO2 means differed from their corresponding FRM means by only one part per billion (ppb). Linear correlation analysis between
all readings of the individual NO2 PSDs and FRM values showed an average absolute difference of 1.2 ppb with an r
2 of 0.95. Paired comparison between high and low concentration annual NO2 sites, seasonal considerations, and interlab quality control comparisons all showed excellent results. The ease of deployment,
reliability, and the cost-savings that can be realized with NO2 PSDs could make them an attractive alternative to FRM monitors for screening purposes, and even possibly an equivalent method
for annual NO2 monitoring. More tests of the Ogawa NO2 PSD are recommended for different ecosystem and climate regimes. 相似文献
95.
Wei Gao Dennis P. Swaney Bongghi Hong Robert W. Howarth Yong Liu Huaicheng Guo 《Ambio》2015,44(7):635-646
The environmental degradation of lakes in China has become increasingly serious over the last 30 years and eutrophication resulting from enhanced nutrient inputs is considered a top threat. In this study, a quasi-mass balance method, net anthropogenic N inputs (NANI), was introduced to assess the human influence on N input into three typical Chinese lake basins. The resultant NANI exceeded 10 000 kg N km−2 year−1 for all three basins, and mineral fertilizers were generally the largest sources. However, rapid urbanization and shrinking agricultural production capability may significantly increase N inputs from food and feed imports. Higher percentages of NANI were observed to be exported at urban river outlets, suggesting the acceleration of NANI transfer to rivers by urbanization. Over the last decade, the N inputs have declined in the basins dominated by the fertilizer use but have increased in the basins dominated by the food and feed import. In the foreseeable future, urban areas may arise as new hotspots for nitrogen in China while fertilizer use may decline in importance in areas of high population density.
Electronic supplementary material
The online version of this article (doi:10.1007/s13280-015-0638-8) contains supplementary material, which is available to authorized users. 相似文献96.
Kondolf GM Angermeier PL Cummins K Dunne T Healey M Kimmerer W Moyle PB Murphy D Patten D Railsback S Reed DJ Spies R Twiss R 《Environmental management》2008,42(6):933-945
Despite increasingly large investments, the potential ecological effects of river restoration programs are still small compared
to the degree of human alterations to physical and ecological function. Thus, it is rarely possible to “restore” pre-disturbance
conditions; rather restoration programs (even large, well-funded ones) will nearly always involve multiple small projects,
each of which can make some modest change to selected ecosystem processes and habitats. At present, such projects are typically
selected based on their attributes as individual projects (e.g., consistency with programmatic goals of the funders, scientific
soundness, and acceptance by local communities), and ease of implementation. Projects are rarely prioritized (at least explicitly)
based on how they will cumulatively affect ecosystem function over coming decades. Such projections require an understanding
of the form of the restoration response curve, or at least that we assume some plausible relations and estimate cumulative
effects based thereon. Drawing on our experience with the CALFED Bay-Delta Ecosystem Restoration Program in California, we
consider potential cumulative system-wide benefits of a restoration activity extensively implemented in the region: isolating/filling
abandoned floodplain gravel pits captured by rivers to reduce predation of outmigrating juvenile salmon by exotic warmwater
species inhabiting the pits. We present a simple spreadsheet model to show how different assumptions about gravel pit bathymetry
and predator behavior would affect the cumulative benefits of multiple pit-filling and isolation projects, and how these insights
could help managers prioritize which pits to fill. 相似文献
97.
Chun Wai Lee Dennis G. Tabor Kenneth A. Cowen 《Journal of Material Cycles and Waste Management》2008,10(1):38-45
The performance of four dioxin emission monitors, including two long-term sampling devices, the Dioxin-MonitoringSystem (DMS)
and AMESA (the adsorption method for sampling dioxins and furans), and two semireal-time continuous monitors, the resonance
ionization with multimirror photon accumulation time-of-flight mass spectrometer (RIMMPA-TOFMS) and the jet resonance-enhanced
multiphoton ionization (jet-REMPI) system were tested. A package boiler burning a simulated chlorinated hazardous waste was
used for a total of nine tests. Reference samples were collected during each test and analyzed for polychlorinated dibenzodioxins
and dibenzofurans (PCDDs/Fs) using gas chromatography mass spectrometry. The PCDD/F concentrations of the reference samples
measured by EPA Method 23 ranged from 0.9 to 6.0 ng toxic equivalence (TEQ)/dry standard cubic meter. The relative accuracies
achieved by DMS, AMESA, and jet-REMPI varied from 22.6% to 78.2%, with 100% data completeness. The RIMMPA-TOFMS produced no
quantifiable results due to various difficulties associated with the instrument during the testing. The two long-term samplers
were easy to install and operate and provided a cumulative, averaged emission for the sampling period. The operations of the
two semi-real-time continuous monitors were relatively complex, but one of them provided on-site, real-time data for PCDD/F
emissions from measurement of a TEQ correlative indicator compound. This article summarizes results from the individual Environmental
Technology Verification reports for the four dioxin monitors.
This work was presented, in part, at the Fourth International Conference on Combustion, Incineration/Pyrolysis and Emission
Control (i-CIPEC) 相似文献
98.
Pait AS Whitall DR Dieppa A Newton SE Brune L Caldow C Mason AL Apeti DA Christensen JD 《Environmental monitoring and assessment》2012,184(8):5065-5075
Jobos Bay, located on the southeastern coast of Puerto Rico, contains a variety of habitats including mangroves, seagrass meadows, and coral reefs. The watershed surrounding the bay includes a number of towns, agricultural areas, and the Jobos Bay National Estuarine Research Reserve (NERR). Jobos Bay and the surrounding watershed are part of a Conservation Effects Assessment Project (CEAP), involving the Jobos Bay NERR, the US Department of Agriculture, and the National Oceanic and Atmospheric Administration (NOAA) to assess the benefits of agricultural best management practices (BMPs) on the terrestrial and marine environments. As part of the Jobos Bay CEAP, NOAA collected sediment samples in May 2008 to characterize over 130 organic chemical contaminants. This paper presents the results of the organic contaminant analysis. The organic contaminants detected in the sediments included polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls, and the pesticide DDT. PAHs at one site in the inner bay near a boat yard were significantly elevated; however, all organic contaminant classes measured were below NOAA sediment quality guidelines that would have indicated that impacts were likely. The results of this work provide an important baseline assessment of the marine environment that will assist in understanding the benefits of implementing BMPs on water quality in Jobos Bay. 相似文献
99.
Mark Gabriel Christopher Knightes Ellen Cooter Robin Dennis 《Environmental Modeling and Assessment》2014,19(4):301-314
In this study, we investigated how different meteorology data sets impacts nitrogen fate and transport responses in the Soil and Water Assessment Tool (SWAT) model. We used two meteorology data sets: National Climatic Data Center (observed) and Mesoscale Model 5/Weather Research and Forecasting (simulated). The SWAT model was applied to two 10-digit hydrologic unit code watersheds in the Coastal Plain and Piedmont zones of North Carolina. Nitrogen cycling and loading response to these meteorological data were investigated by exploring 19 SWAT nitrogen outputs relating to landscape delivery, biogeochemical assimilation, and atmospheric deposition. The largest difference in model output using both meteorology data sets was for large loads/fluxes. Landscape delivery outputs (e.g., NO? 3 watershed discharge, groundwater NO? 3 flux, soil NO? 3 percolation) showed the largest difference across all values. Use of the two weather data sources resulted in a nearly twofold difference in NO? 3 watershed discharge and groundwater NO? 3 flux. Differences for many nitrogen outputs were greater than those for sub-basin flow. Nitrogen outputs showed the greatest difference for agricultural land covers and there was no flow-related pattern in output differences across sub-basins or over time (years). In general, nitrogen parameter models that had a greater number of nitrate concentration, flow, and temperature terms (equation variables) in each transport model showed the greatest difference between both meteorology applications. 相似文献
100.
Mark Gabriel Chris Knightes Robin Dennis Ellen Cooter 《Environmental Modeling and Assessment》2014,19(6):451-465
There has been extensive analysis of Clean Air Act Amendment (CAAA) regulation impacts to changes in atmospheric nitrogen deposition; however, few studies have focused on watershed nitrogen transfer particularly regarding long-term predictions. In this study, we investigated impacts of CAAA NOx emissions on the fate and transport of nitrogen for two watersheds in the Neuse River Basin. We applied the Soil and Water Assessment Tool (SWAT) using simulated deposition rates from the Community Multiscale Air Quality (CMAQ) model. Two scenarios were investigated: one that considered CAAA emission controls in CMAQ simulation (with) and a second that did not (without). By 2020, results showed a 70 % drop in nitrogen discharge for the Little River watershed and a 50 % drop for the Nahunta watershed from 1990 levels under the with-CAAA scenario. Denitrification and plant nitrogen uptake played important roles in nitrogen discharge from each watershed. Nitrogen watershed response time to a change in atmospheric nitrogen deposition was 4 years for Nahunta and 2 years for Little River. We attribute these differences in nitrogen response time to contrasts in agricultural land use and diversity of crop types. Soybean, hay, and corn land covers had comparatively longer response times to changes in atmospheric deposition. The studied watersheds demonstrate relatively large nitrogen retention: ≥80 % of all delivered nitrogen. 相似文献