基于遥感和像元二分模型的新疆植被覆盖度格局动态监测

利用MODIS归一化植被指数(NDVI)资料反演了2006—2015年新疆植被覆盖状况,获取不同时期的植被覆盖度图,并进一步分析了植被覆盖度变化的原因。结果表明:新疆植被覆盖度呈现北部高于南部、西部高于东部的分布特征,其中西部和西北部的山地森林、草地以及天山北坡绿洲农作物、草地区域植被覆盖情况最好。过去10年间,新疆植被覆盖度总体呈上升趋势,2015年植被覆盖度达到最高,为16.68%。生态恢复工程、降水和气温等是影响植被覆盖度变化的主要因素。     

往复流河道沉积物重金属的污染特征和风险评估

在往复流现象明显的蕰藻浜中下游河道选择16个采样点,分析研究沉积物性状以及Cr、Cu、Zn、Cd、Ni、Pb、Mn的含量以及分布情况。结果表明:蕰藻浜总体污染程度为中等,其中陈行桥、江杨北路桥以及淞港码头污染较严重。Cr、Cd、Pb、Ni、Cu、Zn和Mn的含量分别为24.0~357.0、0.06~0.69、20.0~85.4、18.2~132、14.2~136、84.6~685、472~1 086 mg/kg。通过分析发现,Pb、Ni、Cu、Zn和Cr总量都具有显著的相关性,很有可能来自同一外源污染,而中游河段的Mn主要来自于沉积物母质。河道两岸以往的工业与生活排污以及往复水流使得重金属污染物在沉积物中聚集是造成重金属污染的潜在原因。运用地累积指数法、潜在生态危害指数法、污染负荷指数3种风险评价法对沉积物重金属进行风险评估,总体来说,3种评价方法都表明Cu的污染程度较严重,Mn的污染较轻。其中地累积指数法结果显示,各重金属的污染顺序为CuZn≥CdPb≥CrNiMn,然而由于Cd本身生物毒性较高,对沉积物生态环境危害贡献率可达到60%;污染负荷指数评价结果发现蕰藻浜下游河段部分断面沉积物达到了极强污染程度,应当受到重视。     

耕地保护外部性及其经济补偿研究进展

耕地保护外部性及其经济补偿问题日益成为经济发展现实中的生态治理研究的重要领域,但既有的研究尚缺乏系统性和理论基础。本文综合运用文献资料法、对比分析法,较为系统的梳理了国内外关于耕地价值核算、耕地保护外部性及其经济补偿研究的代表性观点,在此基础上分析了当前的研究不足与未来的研究取向。研究发现:①国内对耕地价值核算的研究多沿袭国外的理论框架,且对于耕地非市场价值的划分缺少一个明晰的分类体系;②耕地资源外部效益的估算方法应区别对待,且缺少不同方法与途径的比较研究;③耕地外部性的经济补偿标准在时空分配方面的研究有待强化;④缺乏对耕地保护的补偿模式与执行效率的研究。进而提出:应充分借鉴国外经验并结合中国国情,实现耕地价值核算理论框架的整合,并基于利益相关者的分析框架进一步加强耕地保护外部性经济补偿体系、补偿标准及其运行机制方面的研究,推进CVM等价值评价方法等在资源开采矿区生态补偿及资源综合成本核算方面的应用研究。     

典型湖库富营养化的模糊综合评价研究

随着氮磷等营养盐类的不断排入湖库中,导致了水体的富营养化,使得水体透明度下降,产生异味,对人们的身体健康造成威胁。通过采用合适的水体富营养化评价模型,可以对水体的污染现状进行评价,得出正确的结论,以便采用适当的处理方式及时处理富营养化状况,减少对水环境和人体健康的危害。采用模糊综合评价法,将评价指标进行层次分析,并根据指标的相互关系,确定了各指标的权重,建立了模糊综合评价的数学模型。最终根据建立的评价指标体系、确定的评价标准和实测的湖库（巢湖、洱海和微山湖等）水质资料,得到了我国典型湖库的富营养化评价结论。评价结果与实际状况相吻合,说明该模型适合广泛应用     

中国排污权有偿使用与交易实证的比较研究

建立排污权有偿使用与交易制度对于解决过高的环境治理成本问题具有重要作用.总结了中国排污权有偿使用与交易试点地区的实践经验,梳理并分析了不同时期、不同地区的交易模式、组织过程和主要方法,以期推动中国排污权交易工作的顺利开展和有序推进,进而推动符合国情的排污权交易政策体系的构建.结果表明,总体而言各试点地区的排污权有偿使用和交易在探索中不断发展,取得了积极成效:促进了环境管理的精细化,为地方经济的发展提供了空间,促进了环境质量改善.最后还指出,中国的排污权有偿使用和交易工作中仍存在政策制度建设支撑不足、交易市场活跃度不高、后期监管不力等问题,今后应依法依规,始终坚持由易到难、积极稳妥、重点突破的原则,由点到面、有序推进试点工作.     

制革废水中好氧反硝化菌的筛选及其特性

从制革废水中分离得到1株好氧反硝化菌ZY1,并对ZY1的反硝化能力进行了研究。通过16S rDNA序列分析,确定ZY1为地衣芽孢杆菌(Bacillus licheniformis)。在初始NO2--N质量浓度为80 mg/L、DO为5.7 mg/L、废水温度为30℃、废水pH为8.0、废水中Cr3+质量浓度为110 mg/L、反应时间为24 h的条件下,ZY1菌对NO2--N的降解率大于98%。     

Use of a reactive transport model to describe reductive dechlorination (RD) as a remediation design tool: application at a CAH-contaminated site

In this paper, a numerical model is presented that is capable of describing the complex set of biochemical processes that occur in chlorinated aliphatic hydrocarbon (CAH)-contaminated groundwater when an exogenous electron donor is added. The reactive pattern is based on the degradation pathways of both chlorinated ethanes and ethenes, and it includes electron donor production (H₂ and acetate) from the fermentation of an organic substrate as well as rate-limiting processes related to electron acceptor competition. Coupling of the kinetic model to a convection–dispersion module is described. The calibration phase was carried out using data obtained at a real CAH-contaminated site in the north of Italy. Model simulations of different application scenarios are presented to draw general conclusions on the effectiveness of reductive dechlorination (RD) as a possible cleanup strategy. Early outcomes indicate that cleanup targets can only be achieved if source longevity is reduced. Therefore, metabolic RD is expected to produce beneficial effects because it is known to induce bioenhanced degradation and transformation of CAHs.     

一体化生物膜技术处理滨海农村污水

对厌氧-3级好氧/缺氧生物膜工艺进行技术改进,并对改进后的"一体化生物膜技术"处理低碳氮比农村生活污水进行了实际应用。新工艺增设了回流泵(回流比2∶1),且厌氧段悬浮填料装填率由原来的15%提高到30%,3级好氧/缺氧段YDT型弹性立体填料装填率依次由原来的50%、40%、25%提高到70%、60%和40%。装置连续稳定运行12个月,平均进水量为18 m3/d,HRT为3.7 d,监测结果表明:对COD、BOD、NH3-N、TN、TP和SS平均去除率分别为75.6%、85.9%、86.7%、63.9%、69.3%和85.5%;出水COD、BOD、NH3-N、TN、TP和SS的平均浓度分别在34.9、8.9、3.4、9.9、0.9和6.9 mg/L以下。改进后出水BOD和TN的去除能力有较大提高,除TP外其他各项指标均达到了设计要求。     

Adsorption of sulfamethoxazole on functionalized carbon nanotubes as affected by cations and anions

The environmental risks of antibiotics have attracted lots of research attention, but their environmental behavior is not clear yet. Functionalized carbon nanotubes (CNTs) were used as model adsorbents and sulfamethoxazole (SMX) was used as a model antibiotic to investigate the effect of both cations (Ca²⁺, Cs⁺) and anions (phosphate) on antibiotics adsorption. Various mechanisms (such as electrostatic interaction, hydrophobic interaction, π-π and hydrogen bonds) play roles in SMX adsorption. Cations and anions could “wedge into” these mechanisms and thus alter SMX adsorption. This study emphasized that both increased and decreased SMX adsorption could be observed with the addition of cations/anions, depending on environmental conditions (such as pH in this current study). The net effect is the balance between the increased and decreased effects. The contribution of different mechanisms to the overall antibiotic adsorption on solid particles should be identified to accurately predict the apparent effect by cations and anions.     

Effect of aging on catalytic properties in mechanochemical degradation of pentachlorophenol by birnessite

Mechanochemistry, a technique concerning with milling contaminated samples for prolonged times, induces massive degradation of pollutants by grinding them in ball mills with different soil components or additives. In the present study, laboratory experiments were conducted to evaluate the effect of aging on the mechanochemical efficiency of the Mn-oxide birnessite in degrading pentachlorophenol (PCP). A comparative study on an aged birnessite (KBiA), used after 3 years from synthesis, and a fresh birnessite (KBiF), employed immediately after synthesis, was carried out. The differences between the two birnessites, evidenced by spectroscopic and diffractometric techniques, are mainly relative to reduction of the Mn(IV) centered at the MnO₆ octahedra layers from the birnessite structure, which represent the most reactive sites for PCP degradation. The long term air drying at room temperature, by favouring reduction of Mn(IV) to Mn(III), produces an inorganic substrate that offers paucity of the less reactive sites for PCP degradation, thus reducing the oxidative potential of the KBiA. Accordingly, the more reactive fresh birnessite was employed in the experiment with a polluted soil. Adding a small amount of KBiF to soil only induces a light increase in PCP removal, probably due to the mechanically induced PCP adsorption and transformation onto clay minerals present in the soil. Besides, adding a higher dose of birnessite causes a stronger degradation of PCP.