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51.
Urs Baumann Hanspeter Indermaur und Ernst Pletscher 《Umweltwissenschaften und Schadstoff-Forschung》2000,12(2):63-67
Zusammenfassung Zur ?kotoxikologischen Beurteilung von belastetem Wasser werden h?ufig einfache Biotests eingesetzt. Nicht selten werden dabei
toxische Effekte festgestellt. Es stellt sich dann die Frage nach den verantwortlichen Wasserinhalts-stoffen. Durch Festphasenextraktion
(SPE) werden diese angereichert, gewonnen und dünnschichtchromatographisch unter Verwendung der automatisierten Mehrfachentwicklung
aufgetrennt. Von der DC-Platte wird ein Streifen abgetrennt und darauf direkt die biologische Detektion mit Mikroorganismen
(Bacillus subtilis, Leuchtbakterien) durchgeführt. Dadurch k?nnen toxische Banden erkannt werden, Auf dem DC-Plattenrest wird von der toxischen
Bande mit einem DC-scanner ein UV-Spektrum aufgenommen, die entsprechende Bande herausgekratzt, der toxische Stoff eluiert
und infrarotspektroskopisch untersucht. Durch Spektrenvergleich gelingt es meistens, den Stoff zu charakterisieren.
In der vorliegenden Arbeit wird am Beispiel eines Zitzengummieluates das Analysenkonzept vorgestelit. Es zeigte sich, dass
dieser Gummiartikel einen Vulkanisationsbeschleuniger (2-Mercaptobenzothiazol) freisetzt.
Online-Publikation am: 21.12.1999 相似文献
52.
D. Wang S.R. Yates F.F. Ernst 《Atmospheric environment (Oxford, England : 1994)》1997,31(24):4119-4123
Accurate emission measurement of highly volatile chemicals such as methyl bromide (MeBr) is a crucial step in assessing their potential for environmental contamination. Use of flux chambers is a simple method for measuring emission rate under field conditions. To validate the applicability of a dynamic flow-through chamber for measuring MeBr emission, we provide a complete presentation of calibration and testing of the chamber. The calibration was made under a controlled system subject to ambient temperature changes. Two field experiments were conducted to test the chamber for measuring MeBr flux under conditions similar to commercial soil fumigation practices. In both the calibration and the two field experiments, the chamber provided accurate emission estimates. The maximum mass balance error was < 10% which is comparable to the micrometerological method. Because of its simplicity, we believe this dynamic flux chamber can be used reliably in quantifying the emission dynamics of highly volatile chemicals such as MeBr. 相似文献
53.
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55.
The Science of Nature - 相似文献
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57.
Hermann H. Dieter 《Environmental management》1992,16(1):21-31
The limit value of 0.1 μg/liter for “substances used in plant treatment and pest control including their main toxic degradation
products” (PBSM) established in the German Drinking Water Regulations (Trinkwasserverordnung) serves comprehensively to protect
drinking water from unexpected toxicological risks and thus corresponds to theaxiom of concern (Besorgnisgrundsatz) contained in §11,2 of the Federal Communicable Disease Control Act (Bundesseuchengesetz), which is an
essential cornerstone of the Drinking Water Regulations. Furthermore, precautionary values that are specific to the particular
substance and near the valid limit can be found for about 10% of all registered active substances. The goal of the PBSM Recommendations
of the Federal Health Office (BGA) issued in July 1989 is to preserve and restore groundwater and drinking water through measures
to be taken by the causal party, while reducing consumer health risks to the greatest extent possible. The EC commission's
drawbacks on these recommendations and the imminent EC-wide directive for the uniform registration of pesticides being based
solely on Article 43 of the European Treaty would seriously endanger this goal. Therefore, a situation threatens in Europe
similar to that in the United States, where at least 18 active ingredients have been detected in groundwater in concentrations
of up to 1000 times the toxicologically established limits for drinking water.
This article appeared first in the German journal?ffentliches Gesundheitswesen 52(8–9); 372–379, 1990. We thank the editor (Georg Thieme Verlag, D-7000 Stuttgart) for the kind permission to publish this
slightly revised English version inEnvironmental Management. 相似文献
58.
Ben Vanpeperstraete Sébastien Duyck Medani P. Bhandari Janis Brizga Leida Rijnhout Sylvia Lorek A. Peter Castro Chiung Ting Chang Herman Daly Robert J. Didham Gianluca Ferraro Oliver Greenfield Ashok Khosla Ernst Ulrich von Weizsäcker Birgit Lode Simon Miles Henrique Pacini Semida Silveira Leisa Perch Jaap Rijnsburger Mukul Sanwal Sameera Savarala S. Jacob Scherr Kallidaikurichi E. Seetharam A.M.M. Adeeb Donna Shepherd Adrian Smith Lisinka Ulatowska Alice Vincent Werner John 《Natural resources forum》2011,35(4):334-342
59.
Black liquor gasification–combined cycle (BLGCC) is a new technology that has the potential to increase electricity production of a chemical pulping mill. Increased electricity generation in combination with the potential to use biomass (e.g. bark, hog fuel) more efficiently can result in increased power output compared to the conventional Tomlinson-boiler. Because the BLGCC enables an integrated pulp and paper mill to produce excess power, it can offset electricity produced by power plants. This may lead to reduction of the net-CO2 emissions. The impact of BLGCC to offset CO2 emissions from the pulp and paper industry is studied. We focus on two different plant designs and compare the situation in Sweden and the US. The CO2 emissions are studied as function of the share of recycled fibre used to make the paper. The study shows that under specific conditions the production of “CO2-free paper” is possible. First, energy efficiency in pulp and paper mills needs to be improved to allow the export of sufficient power to offset emissions from fossil fuels used in boilers and other equipment. Secondly, the net-CO2 emission per ton of paper depends strongly on the emission reduction credits for electricity export, and hence on the country or grid to which the paper mill is connected. Thirdly, supplemental use of biomass to replace fossil fuel inputs is important to reduce the overall emissions of the pulp and paper industry. 相似文献
60.
Specific Contributions of Politics,Economics, and Toxicology in Setting Socially Consensual Limit Values 总被引:1,自引:0,他引:1
/ Limit values are legal limits for the concentrations of substances in the environment. They must be agreed upon in a consensual procedure between science, economics/technology, and political forces. This is a crucial political precondition for their social acceptance. The arguments put forward to justify their expediency and numerical level are based not only on risk-benefit considerations but also on the aspect of the technical avoidability of direct and indirect exposure. The critical assessment of the direct benefit of specified exposures falls within the responsibility of economics/technology, whereas criteria for their potential adverse effects (direct and indirect) are provided by medicine/biochemistry and/or ecology. Within this concept, the avoidance of nonbeneficial-even if not openly adverse-exposure is the essential aim of environmental hygiene and should be promoted by politics/science. In general, society or segments thereof reject adverse, accept beneficial, and tolerate unavoidable exposure. Conflicts of interest arise when different groups of society simultaneously define a given exposure as being adverse, beneficial, and unavoidable. Therefore, from the viewpoint of society as a whole, an optimal exposure lies as far as reasonably achievable at a level lower than known or plausible adverse effect thresholds (as defined by toxicology or ecology). This optimal level of exposure must be determined using a transparent and, hence, public procedure.KEY WORDS: Legal limit values; Benefit threshold; Social acceptance; Social tolerability; Adverse effect threshold; Avoidable exposure; Tolerance threshold; Environmental hygiene 相似文献