Photoinduzierte hydroxylierungsreaktionen organischer chemikalien in natürlichen Gewässern - Nitrate als potentielle OH-radikalquellen -

Organic chemicals are concentrated in natural waters, where they undergo complex reactions under the influence of solar radiation and catalyzed by substances such as humic acid as well as nitrate and nitrite salts. Nitrates are present in high concentrations in natural waters (5 – 50 mg/l). The photolysis of the nitrate ion leads to the formation of OH-radicals. In this investigation the steady-state concentration of OH-radicals in different aquatic environments is estimated (～ 5 · 10^?16 mol/l). It depends on the amount of nitrate dissolved in the water. Under the conditions of this work the half life for a great number of organic chemicals lies in the range 80 – 400 hours (for the reaction with OH-radicals).     

Radon variations during treatment in thermal spas of Lesvos Island (Greece)

The aim of this paper was to study the variations of radon and daughter nuclei during treatment in the thermal spas of Lesvos Island (Greece). For this purpose, in the thermal spas of Lesvos we have measured the radon concentrations of thermal waters, as well as indoor radon, daughter and coarse particle (>500 nm) concentration. Various instruments and procedures were employed for measurements. Radon concentrations of thermal waters were found to lie in the range 10 and 304 Bq l(-1). Concentration peaks both for radon, radon daughter and coarse particle, were found to appear during filling of baths in the treatment process. The doses delivered to the bathers during treatment were in the range of 0.00670 mSv per year to 0.1279 mSv per year, while the doses delivered to personnel were below 20 mSv per year.     

Frontal impact dummy kinematics in oblique frontal collisions: evaluation against post mortem human subject test data

OBJECTIVE: Today, a predominant percentage of vehicles involved in car crashes are exposed to oblique or frontal offset collisions. The aim of this study is to evaluate the 50th percentile male Hybrid III, THOR 99, and THOR Alpha dummies by comparing them with the corresponding kinematics of post mortem human subjects (PMHS) in this type of collision. METHODS: The PMHS data include results from oblique frontal collision tests. They include sled tests with near-side and far-side belt geometries at 15 degrees , 30 degrees , and 45 degrees angles. The test subjects were restrained with a three-point lap-shoulder belt and the Delta V was 30 km/h. RESULTS: The results from the Hybrid III and THOR 99 tests showed that, in most of the test, the head trajectories were an average of approximately 0.1 m shorter than those from equivalent PMHS. The Hybrid III and THOR 99 far-side belt geometry tests showed that the belt remained in place longer on the shoulder of the Hybrid III than on the THOR 99 and the THOR Alpha. This was probably due to a stiffer lumbar spine in the Hybrid III and to a large groove in the steel of the superior surface of the Hybrid III shoulder structure. The THOR 99 escaped from the shoulder belt about 40-50 ms earlier than the THOR Alpha. The results from the THOR Alpha tests show that the head trajectory accorded fairly well with the PMHS data, as long as the shoulder belt did not slip off the shoulder. Although the THOR Alpha shoulder escaped the shoulder belt in the 45 degrees far-side belt geometry, the PMHS did not. This may be due to the THOR Alpha shoulder design, with approximately 0.05 m smaller superior and medial shoulder range-of-motion, in combination with a relatively soft lumbar spine. CONCLUSIONS: The THOR Alpha provides head trajectories similar to those of the PMHS under these loading conditions, provided the shoulder belt remains in position on the shoulder. When the shoulder belt slipped off the dummy shoulder, the head kinematics was altered. The shoulder range-of-motion may be a contributing factor to the overall kinematics of an occupant in oblique frontal impact situations where the occupant moves in a trajectory at an angle from that of the longitudinal direction of the car.     

PHYSICAL AND CONCEPTUAL SIMULATION OF EFFLUENTS FROM DREDGED MATERIAL CONFINEMENT FACILITIES1

ABSTRACT: Environmental protection dictates that effluents of desired quality should be dischargd from dredged material confinement facilities. In general, this can be accomplished by supplementing the solid-liquid separation obtained by simple sedimentation with appropriate filter systems which provide additional clarification. A methodology to estimate the sedimentation required in a disposal area was developed on the basis of classical sedimentation theories and compared favorably with field data. A procedure was then advanced and documented whereby effluents from dredged material confinement facilities can be successfully modeled for laboratory filtration tests. For these purposes inorganic suspended solids can be simulted reasonably well by adjusting the concentration of commercially available clays, and fresh or saline water environments can be simulated satisfactorily by tap water or sodium chloride solutions, respectively.     

Hazardous medical waste generation rates of different categories of health-care facilities

Goal of this work was to calculate the hazardous medical waste unit generation rates (HMWUGR), in kg bed(-1)d(-1), using data from 132 health-care facilities in Greece. The calculations were based on the weights of the hazardous medical wastes that were regularly transferred to the sole medical waste incinerator in Athens over a 22-month period during years 2009 and 2010. The 132 health-care facilities were grouped into public and private ones, and, also, into seven sub-categories, namely: birth, cancer treatment, general, military, pediatric, psychiatric and university hospitals. Results showed that there is a large variability in the HMWUGR, even among hospitals of the same category. Average total HMWUGR varied from 0.012 kg bed(-1)d(-1), for the public psychiatric hospitals, to up to 0.72 kg bed(-1)d(-1), for the public university hospitals. Within the private hospitals, average HMWUGR ranged from 0.0012 kg bed(-1)d(-1), for the psychiatric clinics, to up to 0.49 kg bed(-1)d(-1), for the birth clinics. Based on non-parametric statistics, HMWUGR were statistically similar for the birth and general hospitals, in both the public and private sector. The private birth and general hospitals generated statistically more wastes compared to the corresponding public hospitals. The infectious/toxic and toxic medical wastes appear to be 10% and 50% of the total hazardous medical wastes generated by the public cancer treatment and university hospitals, respectively.     

Critical ranges of pollution indices: a tool for predicting soil metal pollution under long-term wastewater reuse

A greenhouse experiment was conducted in pots, for two years (2015–2016), in Amaliada, Greece, using a randomized block design, including six treatments with mixtures composed of Zn, Mn, Cd, Co, Cu, Cr, Ni, and Pb, each metal taking part in the mixture at concentrations of 0, 10, 20, 30 40, and 50 mg/kg soil in four replicates each. Beta vulgaris (beet) was used as a test plant. The aim of the experiment was to calibrate the following pollution indices: “pollution load index,” “elemental pollution index,” “heavy metal load,” and “total concentration factor,” in order to determine the level of soil pollution under variable levels (low to very high) of metal mixtures. The irrigation of the plants was conducted with treated municipal wastewater based on field capacity and percent wilting point. The above pollution indices were classified into four soil pollution classes, i.e., “optimum,” “low,” “high” and “very high” on the basis of percent dry matter plant losses.