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51.
In an acid mining lake (pH 2.6) enclosure experiments wereperformed with the addition of different concentrations oforganic carbon, nitrogen and phosphorus. SSCP-communityfingerprints, based on 16S rRNA gene amplicons, were performed tomonitor changes in the structure of the total bacterialcommunity and the sulfate reducing bacteria (SRB) in themesocosms. Total bacterial cell counts, as assessed byepifluorescence microscopy, were increased in the mesocosmsamended with organic carbon. The addition of carbon alsoincreased the number of abundant bacterial taxa substantiallyalong depth. Sulfate reducing bacteria (SRB) could be detected inall enclosures and all parts of the water column. These SRBbelonged to genus Desulfobacter as indicated bycoroborating molecular data.  相似文献   
52.
Multi-year hourly measurements of PM2.5 elemental carbon (EC) and organic carbon (OC) from a site in the South Bronx, New York were used to examine diurnal, day of week and seasonal patterns. The hourly carbon measurements also provided temporally resolved information on sporadic EC spikes observed predominantly in winter. Furthermore, hourly EC and OC data were used to provide information on secondary organic aerosol formation. Average monthly EC concentrations ranged from 0.5 to 1.4 μg m?3 with peak hourly values of several μg m?3 typically observed from November to March. Mean EC concentrations were lower on weekends (approximately 27% lower on Saturday and 38% lower on Sunday) than on weekdays (Monday to Friday). The weekday/weekend difference was more pronounced during summer months and less noticeable during winter. Throughout the year EC exhibited a similar diurnal pattern to NOx showing a pronounced peak during the morning commute period (7–10 AM EST). These patterns suggest that EC was impacted by local mobile emissions and in addition by emissions from space heating sources during winter months. Although EC was highly correlated with black carbon (BC) there was a pronounced seasonal BC/EC gradient with summer BC concentrations approximately a factor of 2 higher than EC. Average monthly OC concentrations ranged from 1.0 to 4.1 μg m?3 with maximum hourly concentrations of 7–11 μg m?3 predominantly in summer or winter months. OC concentrations generally correlated with PM2.5 total mass and aerosol sulfate and with NOx during winter months. OC showed no particular day of week pattern. The OC diurnal pattern was typically different than EC except in winter when OC tracked EC and NOx indicating local primary emissions contributed significantly to OC during winter at the urban location. On average secondary organic aerosol was estimated to account for 40–50% of OC during winter and up to 63–73% during summer months.  相似文献   
53.
The pesticides in flooded applications model (PFAM) is a regulatory model for government agencies and others interested in estimating water concentrations of pesticides used in flooded agriculture applications such as rice paddies and cranberries bogs. PFAM was designed around the specific parameters that are typically available for a pesticide risk assessment, thereby simplifying the model and allowing the user to concentrate on only the most relevant model inputs. The model considers the fate properties of pesticides and allows for the specifications of typical flooded agriculture management practices such as scheduled water releases and refills. It also allows for natural water-level fluctuations resulting from precipitation and evapotranspiration. Model quality assurance requirements for regulatory models aimed at protecting the public are that the models err on the high side of measured data and at the same time should not cause undue burden to stakeholders by being overly conservative. For the studies herein, PFAM did tend to err on the high side of the data yet provided more realistic estimates than the currently used methods, which thereby reduced stakeholder burden. As is also important for a regulatory model, PFAM is nonproprietary and freely available.  相似文献   
54.
The collection of fog water is a simple and sustainable technology to obtain fresh water for afforestation, gardening, and as a drinking water source for human and animal consumption. In regions where fresh water is sparse and fog frequently occurs, it is feasible to set up a passive mesh system for fog water collection. The mesh is directly exposed to the atmosphere, and the foggy air is pushed through the mesh by the wind. Fog droplets are deposited on the mesh, combine to form larger droplets, and run down passing into a storage tank. Fog water collection rates vary dramatically from site to site but yearly averages from 3 to 10 l m−2 of mesh per day are typical of operational projects. The scope of this article is to review fog collection projects worldwide, to analyze factors of success, and to evaluate the prospects of this technology.  相似文献   
55.
Europium(III) was coprecipitated with the clay mineral hectorite, a magnesian smectite, following a multi-step synthesis procedure. Different Eu(III) species associated with the proceeding synthetic hectorite were characterized by selectively exciting the 5D0-->7F0 transition at low temperature (T < 20 K). Fluorescence decay times indicated that Eu(III) ions may be incorporated in the octahedral layer of the brucite precursor as well as in the octahedral sheet of the clay mineral. The excitation spectra indicated that the substitution of the divalent Mg by the trivalent Eu induced local structural deformation. This investigation implements the molecular-level understanding of the f element structural incorporation into the octahedral layer of sheet silicates by coprecipitation with clay minerals from salt solutions at 100 degrees C.  相似文献   
56.
Over 400tons of Pb enters Swiss soils annually at some 2000 military shooting ranges (MSRs). We measured elements in the leaves of 10 plant species and associated rhizospheric soil on the stop butt of a disused MSR. The geometric mean concentrations of Pb, Sb, Cu, Ni in rhizospheric soils were 10,171mg/kg, 5067mg/kg, 4125mg/kg and 917mg/kg. Some species contained Pb, Cu and Ni, above concentrations (30mg/kg, 25mg/kg and 50mg/kg) shown to be toxic to livestock. Most contaminants in leaves resulted from surface deposition. However, at soil Pb concentrations >60,000mg/kg, Equisetum arvense and Tussilago farfara took up >1000mg/kg Pb into the leaves. These plants are not hyperaccumulators, having <100mg/kg Pb in leaves at lower soil concentrations. Removal of soil with more than 30,000 Pb, from which one could smelt this metal to offset remediation costs, followed by revegetation, would minimise dust and hence leaf-borne contaminants.  相似文献   
57.
Via a historical reconstruction, this paper primarily demonstrates how the societal debate on genetically modified organisms (GMOs) gradually extended in terms of actors involved and concerns reflected. It is argued that the implementation of recombinant DNA technology out of the laboratory and into civil society entailed a “complex of concerns.” In this complex, distinctions between environmental, agricultural, socio-economic, and ethical issues proved to be blurred. This fueled the confusion between the wider debate on genetic modification and the risk assessment of transgenic crops in the European Union. In this paper, the lasting skeptical and/or ambivalent attitude of Europeans towards agro-food biotechnology is interpreted as signaling an ongoing social request – and even a quest – for an evaluation of biotechnology with Sense and Sensibility. In this (re)quest, a broader-than-scientific dimension is sought for that allows addressing the GMO debate in a more “sensible” way, whilst making “sense” of the different stances taken in it. Here, the restyling of the European regulatory frame on transgenic agro-food products and of science communication models are discussed and taken to be indicative of the (re)quest to move from a merely scientific evaluation and risk-based policy towards a socially more robust evaluation that takes the “non-scientific” concerns at stake in the GMO debate seriously.  相似文献   
58.
Summary Position preferences of well-fed and food-deprived juvenile roach were investigated in schools of 2 and 4 fish in the laboratory. Food-deprived fish appeared significantly more often in the front position than their well-fed conspecifics. For fish at the same hunger level, individuals at the front of the school had the highest feeding rate. These results represent the first evidence for a relationship between the nutritional state of individual fish and their positions in a school and suggest a functional advantage of the preference. Offprint requests to: J. Krause at the present address  相似文献   
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