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51.
Mechanochemistry of ibuprofen pharmaceutical 总被引:1,自引:0,他引:1
In this paper mechanochemistry has been studied in view of possible application to detoxification of expired pharmaceuticals. The experiments have been carried out with a commercial medication containing ibuprofen ((RS)-2-(4-(2-methylpropyl)phenyl)propanoic acid) which has been submitted to prolonged milling up to 40 h. When Al(OH)3 is used as co-reagent, the first degradation step induced by the mechanochemical treatment is an acid-base reaction with the ibuprofen carboxylic acid group. The subsequent degradation follows a complex pathway leading to 1-(4-isobutylphenyl)ethanone, 1-isobutyl-4-vinylbenzene and 2-(4-(3-methylbutan-2-yl)phenyl)propan-1-ol after 10 h milling and, in addition, 1-(4-acetylphenyl)-2-methylpropan-1-one, 1-(4-(1-hydroxy-2-methylpropyl)phenyl)ethanone and 1-(4-(2-hydroxy-2-methylpropyl)phenyl)ethanone after 40 h milling. The degradation reaction path and products have been identified by means of FT-IR spectroscopy, thin layer chromatography, NMR spectroscopy, mass spectroscopy and elemental analysis. The observed ibuprofen decarboxylation makes the drug simultaneously lose both its pharmaceutical activity and toxicity. 相似文献
52.
Domenico Mignacca Ken Stubbs 《Journal of the Air & Waste Management Association (1995)》2013,63(10):1250-1254
ABSTRACT This study investigated the effect of equilibration temperature on PM10 concentrations from the tapered element oscillating microbalance (TEOM) method by operating collocated TEOM monitors at different equilibration temperatures in an airshed (the Lower Fraser Valley, British Columbia). This airshed contained an abundance of par-ticulate semivolatile material (PSVM). For the period when three collocated TEOM monitors were operated, the PM10 from the monitor at an equilibration temperature of 30 ° C was 2.5 μ g/m3 (22%) and 1.7 (17%) μ g/m3 higher, on average, than the PM10 from monitors at 50 and 40 ° C, respectively, and the differences were proportional to the ambient PM10 loading. Greater volatilization of PSVM in the TEOM monitors at higher equilibration temperatures may have been a cause of the differences. 相似文献
53.
Ingelido AM Ballard T Dellatte E di Domenico A Ferri F Fulgenzi AR Herrmann T Iacovella N Miniero R Päpke O Porpora MG De Felip E 《Chemosphere》2007,67(9):S301-S306
The levels of selected polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) were measured in human milk samples from the areas of Venice and Rome, primarily in order to characterize the current levels of infant exposure to PCBs and PBDEs due to breast feeding in Italy. Sixteen non-dioxin-like PCBs, including the traditional indicator congeners, and 11 PBDEs, comprising the relevant PBDE-47, PBDE-99, and PBDE-153, were determined. Congeners were selected for analysis according to their relative abundance in human tissues, toxicological relevance, and diffusion in the environment. Dietary habits of the milk donors were recorded by questionnaires; mothers of the Venice area were classified into three groups according to their consumption of local fish, molluscs, and other fishery products. Sigma(16)(PCBs) and Sigma(11)(PBDEs) (ng g(-1) fat) for the areas of Venice and Rome were respectively, 250-390 and 240, and 1.6-2.8 and 4.1. An increase of fish and fishery product consumption could not be associated with an increase of PCB and PBDE levels in milk. 相似文献
54.
Particle-phase Polycyclic Aromatic Hydrocarbon Emissions from Non-catalysed, In-use Four-stroke Scooters 总被引:2,自引:0,他引:2
Spezzano P Picini P Cataldi D Messale F Manni C Santino D 《Environmental monitoring and assessment》2007,127(1-3):105-117
Metals and radionuclide levels in marine birds of the Aleutians are of interest because they are part of subsistence diets
of the Aleut people, and can also serve as indicators of marine pollution. We examined geographic and species-specific variations
in concentrations of radionuclides in birds and their eggs from Amchitka, the site of underground nuclear tests from 1965
to 1971, and Kiska Islands (a reference site) in the Aleutians, and the levels of lead, mercury and cadmium in eggs. In 2004
we collected common eiders (Somateria mollissima), tufted puffins (Fratercula cirrhata), pigeon guillemot (Cepphus columba) and glaucous-winged gulls (Larus glaucescens) from Amchitka and Kiska, and eggs from eiders and gulls from the two island. We also collected one runt bald eagle (Haliaeetus leucocephalus) chick from both Amchitka and Kiska Islands. For most species, the levels of radionuclide isotopes were below the minimum
detectable activity levels (MDA). Out of 74 cesium-137 analyses, only one composite (gulls) was above the MDA, and out of
14 composites tested for plutonium (Pu-239, 240), only one exceeded the MDA (a guillemots). Three composites out of 14 tested
had detectable uranium-238. In all cases, the levels were low and close to the MDAs, and were below those reported for other
seabirds. There were significant interspecific differences in metal levels in eggs: gulls had significantly higher levels
of cadmium and mercury than the eiders, and eiders had higher levels of lead than gulls. There were few significant differences
as a function of island, but eiders had significantly higher levels of cadmium in eggs from Kiska, and gulls had significantly
higher levels of mercury on Kiska. The levels of cadmium and mercury in eggs of eiders and gulls from this study were above
the median for cadmium and mercury from studies in the literature. The levels of mercury in eggs are within the range known
to affect avian predators, but seabirds seem less vulnerable to mercury than other birds. However, the levels of mercury are
within the action levels for humans, suggesting some cause for concern if subsistence Aleuts eat a large quantity of eggs. 相似文献
55.
Gupta Medhavi Ho Dang Santoro Domenico Torfs Elena Doucet Julie Vanrolleghem Peter A. Nakhla George 《Environmental science and pollution research international》2018,25(17):16743-16753
Environmental Science and Pollution Research - Cellulose, mostly in the form of toilet paper, forms a major component of the particulates in raw municipal wastewater, which could lead to... 相似文献
56.
Mauro Mele Diego Servida Domenico Lupis 《Environmental monitoring and assessment》2013,185(7):5891-5907
Sulphide-bearing mine dumps are potential sources of pollution when acid mine drainage (AMD) occurs. Because the generation of AMD depends on the volume and composition of waste materials, their characterisation is crucial for the evaluation of geochemical hazards and for the design of remediation strategies to minimise their environmental impact. In this paper, a cost-effective strategy for the characterisation of an inactive mine dump in the Rio Marina mining district (Elba Island, Italy) using earth resistivity imaging (ERI) is presented. As no information regarding the nature of waste rocks is found in reports for the mine, five ERI profiles were acquired at the top of the waste pile. The results show that waste rocks are heterogeneous with a maximum thickness of 30 m. Due to the large amounts of dispersed sulphide minerals, the waste rocks are characterised by an electrically conductive geophysical signature in comparison to the surrounding resistive metamorphic bedrock. A geostatistical approach was adopted to estimate the elevation of the edges of the mine dump, and the net volume of the waste rocks was computed through a raster analysis of the elevations of the upper and lower boundaries of the mine dump. High-conductivity anomalies were detected within the core of the mine dump. The integration of the hydrogeological, geochemical and geological framework of the Rio Marina mining district suggests that these anomalies could be a geophysical signature of subsurface regions where AMD is currently generated or stored, thus representing sources of environmental pollution. 相似文献
57.
Although Mar Piccolo of Taranto (Ionian Sea, Italy) is one of the most important Mytilus galloprovincialis farming areas, data concerning the natural bacterial microbiota of these mussels and their surrounding environment are still scant. This study was carried out seasonally, throughout a year, to determine culturable heterotrophic bacteria both in the water and mussels samples collected at three sampling sites in the Northern Ionian Sea: S. Vito, Lido Gandoli and Lido Silvana. Culturable heterotrophic bacteria abundance was determined by spread plate on Marine Agar. Heterotrophic bacteria were identified by several morphological, culture and biochemical methods. Bacterial concentrations were higher in the mussel samples compared to the corresponding seawater throughout the year. Among Gram negative heterotrophic bacteria, Aeromonas prevailed both in the water (18%) and mussel samples (40%). Other genera such as Moraxella, Pseudomonas, Alcaligenes, Acinetobacter, Flavobacterium, Chromobacterium, Photobacterium and Flexibacter were present with different percentages of isolation. Bacilli were predominant among Gram positive bacteria. Some genera (Lucibacterium and Vibrio) were present only in mussel samples. The results obtained contribute to improve the knowledge on both the bacterial abundance and diversity in mussels and the surrounding seawater in the Northern Ionian Sea. 相似文献
58.
Concetto Giorgianni Mariagiuseppina Tanzariello Domenico De Pasquale Renato Brecciaroli Giovanna Spatari 《International journal of occupational safety and ergonomics》2019,25(4):583-586
Background. Organic solvents cause diseases of the vestibular system. However, little is known regarding the correlation between vestibular damage and exposure to organic solvents below threshold limit values. The best measure by which to evaluate vestibular disorders is static and dynamic posturography. Objective. The aim of this study was to evaluate equilibrium disorders via static and dynamic posturography in workers without clear symptoms and exposed to low doses of mixed solvents. Methods. 200 subjects were selected. Using an Otometrics device (Madsen, Denmark), all subjects endured static and dynamic posturography testing with both eyes-open and eyes-closed conditions. Results were compared with a control group of unexposed individuals. Result. Based on the obtained data, the following results can be drawn: (a) subjects exposed to mixtures of solvents show highly significant differences regarding all static and dynamic posturography parameters in comparison to the control group; (b) posturography testing has proven to be a valid means by which to detect subliminal equilibrium disorders in subjects exposed to solvents. Conclusion. We can confirm that refinery workers exposed to mixtures of solvents can present subliminal equilibrium disorders. Early diagnosis of the latter is made possible by static and dynamic posturography. 相似文献
59.
The feasibility of electrokinetic remediation of copper-contaminated soil was evaluated following eight days of electroreclamation. The results indicate that electrokinetic reclamation of Cu is totally ineffective in soil composed primarily of clay minerals and organic matter. The strong absorption of copper by this kind of soil, in our view mainly a result of retention by the clay component, makes it resistant to mobilization by the electrogenerated acidic front as well as by citrates (the competitors of natural chelating agents, i.e., humates). Such conditions, while adverse for the electroremediation process, may cause this kind of soil to act as a natural barrier to the leaching of copper ions. 相似文献
60.
Porpora MG Ingelido AM di Domenico A Ferro A Crobu M Pallante D Cardelli M Cosmi EV De Felip E 《Chemosphere》2006,63(8):1361-1367
Endometriosis has been hypothesised to be linked to persistent and toxic organochlorinated chemicals. Dioxins and dioxin-like compounds have in particular been associated with the disease, mainly on the basis of experimental studies. Data in women are conflicting. A case-control study on 80 Italian nulliparous women of reproductive age was carried out to assess whether there is a correlation between the presence of endometriosis and blood levels of polychlorobiphenyls (PCBs), a family of ubiquitary environmental pollutants which comprises congeners with dioxin-like activity. Higher levels of PCBs were found in women with endometriosis. A mean cumulative value of 410 ng g(-1), lipid base, was found in cases versus the value of 250 ng g(-1) observed in the control group (odds ratio for upper tertile 4.0, CI 95% 1.3-13; p = 0.0003). PCB increase involved both dioxin-like (PCBs 105, 118, 156, and 167) and non-dioxin-like congeners (PCBs 101, 138, 153, 170, 180). 相似文献