土霉素残留对猪粪堆肥过程中理化性质的影响

为探讨土霉素残留对猪粪堆肥过程的影响,以猪粪和锯末为原料,设置土霉素初始残留质量浓度分别为0、10、50、100、150 mg/kg的5个处理,进行为期30 d的好氧堆肥,研究土霉素对堆肥过程中温度、含水率、水溶性NH4+-N、水溶性NO3- -N、水溶性有机碳(DOC)的变化影响.结果表明:(1)土霉素残留加速了温度的下降,不利于温度的上升.(2)土霉素初始残留质量浓度为100、150 mg/kg不利于堆肥过程中水分的散失,并且会造成堆肥结束后堆体的高含水率.(3)土霉素抑制了堆肥过程中微生物对有机氮的分解及硝化细菌的硝化作用,其中150mg/kg处理的土霉素抑制作用最显著.(4)堆肥结束后,0、10、50、100、150 mg/kg处理的DOC分别为3 815.65、3 461.88、3 429.28、3 231.18、2 782.09mg/kg.0 mg/kg处理的DOC高于其他4个处理,且与150 mg/kg处理之间差异显著,表明土霉素抑制了堆肥过程中微生物对有机碳的利用,其中150 mg/kg处理的土霉素抑制作用最显著.     

支撑气膜法脱除/回收垃圾渗滤液中氨氮简

利用由微孔疏水性聚丙烯中空纤维制成的工业级膜组件对垃圾渗滤液中氨氮进行支撑气膜法脱除研究,考察了泡沫分离-石灰絮凝等预处理技术对垃圾渗滤液表面张力及COD值的处理效果,在此基础上研究了物料因素和操作因素对膜传质性能的影响,并对该工艺的长期操作稳定性进行了研究。实验结果表明该预处理技术不仅可显著提高垃圾渗滤液的表面张力,还可大大降低其色度和COD值。当进料流量为100 L/h、进料氨氮浓度为1 000~3 000 mg/L、硫酸吸收液流量为200 L/h、硫酸浓度为6%~10%、温度为20~30℃时,支撑气膜过程（两级膜组件串联）可有效脱除垃圾渗滤液中99%以上的氨氮,同时得到含10%~15%硫酸铵的水溶液作为副产品。工业级支撑气膜组件在连续运行的2个月内保持了良好的传质稳定性。     

生化法处理乳链菌肽发酵废水研究

根据乳链菌肽发酵废水氮源丰富、碳源缺乏,不利于酵母菌生长和废水处理,利用色拉油加工废水做碳源,研究了初始pH、接种量、初始C/N比、溶解氧、水力停留时间对生化法处理乳链菌肽发酵废水的影响。结果表明,最佳条件为：初始pH 4.5、溶氧浓度2～3 mg/L、接种量12%、C/N 20∶1～30∶1、水力停留时间56 h,进水COD浓度27 100 mg/L。处理后的乳链菌肽发酵废水COD去除率达91.3%、出水pH 6.0～8.0。     

几种型式微孔曝气器清水充氧性能对比实验研究

对不同厂家生产的不同型式和材质的微孔曝气器在不同测试条件下进行清水曝气实验,结果表明,同一产品在相同水深条件下,随着标准通气量增大,充氧能力增大,理论动力效率减小,氧利用率减小;曝气密度越大,曝气器充氧性能越好;曝气器材质和生产工艺严重影响其充氧性能.     

基于炉渣图像处理的生活垃圾焚烧效果快速评测方法

以生活垃圾可燃组分焚烧炉渣为研究对象,基于图像处理技术设计了一种简单快捷的炉渣质量快速评价比色方法 .为验证该方法的可行性,以4种生活垃圾可燃组分（纸类、橡塑、织物、混合组分）制备焚烧炉渣并获取图像信息同时测定热灼减率.结果表明,不同条件下炉渣颜色与热灼减率差异显著,且除橡塑组分外,其余组分炉渣颜色与热灼减率存在显著相关性.选取混合组分炉渣热灼减率与颜色信息分析划分了6个颜色质量等级并生成色卡.该方法将炉渣外貌特征与焚烧炉焚烧效果建立关联,可为垃圾焚烧现场快速评价提供参考.     

Systematic assessment of dredged sludge dewaterability improvement with different organic polymers based on analytic hierarchy process

Organic polymeric flocculants are commonly used in improving dredged sludge dewaterability, but less attention has been paid to residual water quality. In this paper, the effects of cationic etherified starch (CS) and poly-dimethyl diallyl ammonium chloride (PDDA) on dredged sludge dewatering efficiency and residual water quality of Baiyangdian lake were comprehensively investigated and evaluated by analytic hierarchy process (AHP). The results indicated that PDDA had stronger electrical effect and flocculation performance compared with CS, resulting in more efficient dewatering performance. PDDA can reduce the pollutants of discharged residual water, while CS significantly promoted the increase of NH₄⁺-N and NO₃^–-N in the residual water. The increase of NH₄⁺-N in the residual water of CS was due to the release of dredged sludge, while the increase of NO₃^–-N was introduced by CS leaching. AHP showed that PDDA performed better in flocculation treatment of dredged sludge than other organic polymers. This work provides a method for optimization of flocculation treatment for dredged sludge dewaterability.     

One-step preparation of polyimide-inlaid amine-rich porous organic block copolymer for efficient removal of chlorophenols from aqueous solution

A novel polyimide-inlaid amine-rich porous organic block copolymer (PI-b-ARPOP) was prepared via one-step polymerization by using different molar ratios of melamine (MA)/terephthalaldehyde (TA)/pyromellitic dianhydride (PMDA), at molar ratios of 4/3/1, 4/2/2 and 4/1/3. The copolymer contained both aminal groups belonging to ARPOP and imide groups belonging to PI, and the bonding styles of the monomers and growth orientations of the polymeric chains were diversiform, forming an excellent porous structure. Notably, MA/TA/PMDA (4/2/2) had a surface area and pore volume of 487.27?m²/g and 1.169?cm³/g, respectively. The adsorption performance of the materials towards 2,4-dichlorophenol (2,4-DCP) in ultra-pure water was systematically studied. The pH value of 7 was optimal in aqueous solution. Na⁺ and Cl^? ions did not negatively affect the adsorption process, while humic acid (HA) slightly decreased the capacity. The equilibrium time was 40 sec, and the maximum adsorption capacity reached 282.49?mg/g at 298?K. The removal process was endothermic and spontaneous, and the copolymer could maintain its porous structure and consistent performance after regeneration by treatment with alkali. Moreover, to further assess the practical applicability of the material, the adsorption performance towards 2,4-DCP in river water was also investigated. This paper demonstrated that the PI-b-ARPOP can be an efficient and practical adsorbent to remove chlorophenols from aqueous solution.     

Disinfection byproduct precursor removal by enhanced coagulation and their distribution in chemical fractions

Raw water from the Songhua River was treated by four types of coagulants, ferric chloride(FeCl3), aluminum sulfate(Al2(SO4)3),polyaluminum chloride(PACl) and composite polyaluminum(HPAC), in order to remove dissolved organic matter(DOM). Considering the disinfection byproduct(DBP) precursor treatability, DOM was divided into five chemical fractions based on resin adsorption.Trihalomethane formation potential(THMFP) and haloacetic acid formation potential(HAAFP) were measured for each fraction. The results showed that hydrophobic acids(HoA), hydrophilic matter(HiM) and hydrophobic neutral(HoN) were the dominant fractions.Although both HoN and HoA were the main THM precursors, the contribution for THMFP changed after coagulation. Additionally,HoA and HiM were the main HAA precursors, while the contribution of HoN to HAAFP significantly increased after coagulation.HoM was more easily removed than HiM, no matter which coagulant was used, especially under enhanced coagulation conditions.DOC removal was highest for enhanced coagulation using FeCl3 while DBPFP was lowest using PACl. This could indicate that not all DOC fractions contained the precursors of DBPs. Reduction of THMFP and HAAFP by PACl under enhanced coagulation could reach51% and 59% respectively.     

推荐管理措施情景下黄淮海地区旱地土壤固碳潜力模拟研究——以河南省获嘉县为例

农田土壤固碳不仅可以减缓气候变化,而且能够提高土壤质量。推荐管理措施,如少、免耕和秸秆还田等,具有促进农田土壤有机碳（SOC）增加的巨大潜力。旱地占中国农田面积的70%以上,在固定大气CO2方面可以发挥重要作用。本研究基于黄淮海地区的一个旱地土壤肥力长期监测点数据并运用Century模型模拟了监测期间（1998～2007）土壤有机碳动态变化。在此基础上,设计了1种基础管理措施情景和4种推荐管理措施情景并模拟了它们未来20年的固碳潜力。模拟结果表明,监测期间监测点土壤有机碳密度增加2.72 Mg.hm-2,年均增加0.27 Mg.hm-2。土壤有机碳的增加主要是因为氮肥施用量的增加。模型验证结果表明,Century模型很好地模拟了监测点土壤有机碳的动态变化。各推荐管理措施均具有较大的固碳潜力,其中50%秸秆还田是比少、免耕更有效的固碳措施,而少耕＋50%秸秆还田的固碳潜力最大。因此,在黄淮海地区旱地推广实施推荐管理措施是促进农田土壤固碳的有效策略,有助于减缓大气CO2浓度升高和保障国家粮食安全。     

Band gap tuning of g-C3N4 via decoration with AgCl to expedite the photocatalytic degradation and mineralization of oxalic acid

A series of functional organic-metal AgCl-decorated graphitic carbon nitride(AgCl-CNx)composites were synthesized and applied for the degradation of oxalic acid(OA)under visible light.The highest photocatalytic activity was achieved with AgCl decoration ratio of1.0(denoted as AgCl-CN_(1.0)).The pseudo-first-order constant for OA degradation was 0.0722min-1 with the mineralization efficiency of 90.80%after 60 min reaction in the photocatalytic process with AgCl-CN_(1.0).A variety of characterization techniques including BrunauerEmmett-Teller,X-ray diffraction,scanning electron microscope,transmission electron microscopy,X-ray photoelectron spectroscopy,Fourier transform infrared spectra,ultraviolet-visible diffuse reflectance spectra,photoluminescence,and Mott-Schottky were utilized to elucidate the physicochemical,microstructure,and optical properties contributing to the improvement of the photocatalytic performance.The results showed that AgClCN_(1.0)had an oblate flaky erythrocyte-like structure with a moderate band gap energy of～3.00 eV.In addition,the effects of the key parameters(i.e.,AgCl-CN_(1.0) dosage,initial OA concentration,solution pH,and presence of natural organic matter)on OA degradation were systematically investigated.Radical scavenger experiments indicated that photogenerated holes,electrons,superoxide anion radicals,and hydroxyl radicals were the dominant reactive species.Moreover,AgCl-CN_(1.0) exhibited excellent stability and reusability for OA degradation without detectable Ag~+release in the solution over multiple reaction cycles.The efficient OA mineralization could be mainly ascribed to the moderate specific surface area,increased numbers of active sites,and effective interfacial charge transfer of AgCl-CN_(1.0).Overall,the AgCl-CN_(1.0) composite was demonstrated to be a highly efficient,stable,and recoverable photocatalyst.