Comparison of Air Pollutant Emissions from Vaporizing and Air Atomizing Waste Oil Heaters

Information presented in this paper is directed to individuals concerned with emissions from combustion of waste crankcase oil for space heating. Studies were performed to characterize gaseous and particulate emissions and vaporizing pot solid residues resulting from the combustion of waste crankcase oil. Two types of waste oil burners were tested. One was a vaporizing oil burner rated at 35.2 kW (120,000 Btu/h heat input), and the other was an air atomizing oil burner rated at 73.3 kW (250,000 Btu/h heat input). Except for NO_X and SO_X, gaseous emissions were similar to those from conventional distillate oil combustion. NO_X and SO_X emissions were higher due to higher fuel nitrogen and sulfur concentrations. Waste oil from automotive use showed higher inorganic levels than crankcase oil used for truck engine lubrication. Both burner types discharged high levels of metallic species, but the air atomizing unit had much higher stack emission levels than did the vaporizing pot system. Also, particulate loading levels were an order of magnitude higher for the air atomizing burner than for the vaporizing pot burner when firing the waste oils. However, the vaporizing pot burner generated a waste residue containing the majority of its elemental emissions. Elements which exceeded threshold limit values for one or both heaters were cadmium, chromium, cobalt, copper, iron, lead, nickel, phosphorus, and zinc. However, the nickel and much of chromium appeared to be a sampling artifact caused by the stainless steel sampling system.     

Dry FGD at United Power Association’s Stanton Station

The United Power Association’s dry FGD system at Stanton, North Dakota was the first utility-operated lime spray dryer to be put into service in the United States. At 60 MW in size, it utilizes a single spray dryer vessel with three rotary atomizers and a ten-compartment fabric filter. It is currently operating at better than expected efficiency and Is meeting state and federal air quality requirements. Start-up and operation have shown that certain areas of design and operating conditions are critical to reliable operation. Flue gas, slurry, and water distribution and mixing must be carefully controlled if reliable, long term operation is to be achieved. Likewise, water chemistry Is Important in the reagent preparation equipment. Start-up of the system was accomplished In a step-wise fashion to bring the baghouse on line first, followed by the spray dryer. The spray dryer was operated at gradually lower outlet temperatures until design conditions were met. Measures taken since start-up to ensure reliable operation, and operation over an eighteen month period are discussed. Both particulate and SO₂ emission performance are evaluated.     

Evaluation of RAM Model for Cleveland,Ohio, Part II

Coal combustion is the primary contributor to atmospheric pollution in China, especially so In big cities. Particulate matter and sulfur dioxide are the two main pollutants worthy of attention. Concentration of suspended particles is usually higher in northern cities than in southern cities and higher in winter than in summer. In the case of sulfur dioxide, concentrations are high in the heating season (wintertime) in northern cities, but also in some of the cities in the southwest part of China. Rainfall with pH less than 5.6 occurs mostly to the south of the Yangtze River, especially so in the cities of Chongqing and Gueiyang, and their neighboring areas, and also In the southwest part of China. No acid rain, however, has been found in Beijing and Tianjin. Although the formation of acid rain can thus be thought of as dependent on the presence of enough sulfur dioxide, other factors such as airborne particles and ammonia also play an important role. The difference is, therefore, explained and theorem postulated with supporting data. Ways of abating atmospheric pollution are, in essence, related to improved coal burning; some simple methods are suggested for nationwide control options.     

Reducing Interference Effects in the Chemiluminescent Measurement of Nitric Oxides from Combustion Systems

Experiments were carried out to determine the relative chemiluminescence quenching efficiencies as a function of third body concentration for each of the common combustion products, H₂O, CO₂, CO, H₂, O₂ and Ar. These results are compared with those of other investigators. The effect of reaction chamber pressure on analyzer response and the development of an analyzer design which incorporates an adjustable sample capillary inlet capable of maintaining a constant molar flow rate of sample gas to the reaction chamber are discussed. The effect of carbon monoxide interference on chemiluminescent NO_x measurement has been isolated and found to be significant. A means of correcting NO, measurements for these CO interference effects is described. Quantification of NO and NO₂ absorption in liquid water in NO_x sampling systems has been made. Recommendations for sample system designs to handle the presence of water in the sample gas are made.     

1985 Update,Operating History and Current Status of Fabric Filters in the Utility Industry

Stringent particulate emissions limits and increasing awareness of stack opacity is leading the utility industry to use high efficiency particulate control systems. In response to this trend, the Electric Power Research Institute (EPRI) is conducting several research programs aimed at improving the operation, maintenance and performance of particulate control systems. One of these programs, RP-1401, “Reliability Assessment of Particulate Control Systems,” is developing operation, maintenance and design data bases for both electrostatic precipitators and fabric filters. This paper discusses some of the intermediate findings of the work done on fabric filters.     

Development of Federal Air Standards to Reduce Sulfur Dioxide Emissions from New Industrial Boilers

Federal new source performance standards to control air emissions of sulfur dioxide from new industrial boilers were proposed by EPA on June 19, 1986. These standards would require boiler owners to reduce SO₂ emissions by 90 percent and meet an emission limit of 1.2 lb/MM Btu of heat input for coal-fired boilers and 0.8 lb/MM Btu for oil-fired boilers. In developing these standards, several regulatory options were considered, from standards that could be met by firing low sulfur fuels to standards that would necessitate flue gas treatment. The environmental, economic, and cost impacts of each option were analyzed. National impacts were estimated by a computer model that projects the population of new boilers over the 5-year period following proposal, predicts the compliance strategy that will be used to comply with the particular option (always assuming that the lowest cost method of compliance will be selected), and estimates the resulting emission reductions and costs. Impacts on specific industries and on model boilers were also analyzed. This paper focuses on these analyses and their results. The Agency's conclusions from these analyses, which led to the decision to establish percent reduction standards, are provided, and the proposed SO₂ standards are summarized. The proposed standards also include an emission limit for particulate matter from oil-fired boilers (0.1 lb/MM Btu). However, this article focuses only on the SO₂ standards.     

Rotary Kiln Incineration III. An Indepth Study—Kiln Exit/Afterburner/Stack Train and Kiln Exit Pattern Factor Measurements During Liquid CCl4 Processing

Temperature and stable species concentration data are presented from various locations within a full-scale rotary kiln incinerator firing natural gas/carbon tetrachloride/air. The data are being collected as part of a cooperative program involving university, industry and government participation. The overall goal of the program is to develop a more sophisticated understanding of and a predictive capability for rotary kiln and afterburner performance as influenced by basic design and operational parameters. Non-uniformities in stable species and temperature exist for this particular kiln, at the kiln exit, under certain operating conditions. Flow perturbations from within the kiln were found to persist into the afterburner, but not into the stack. High destruction and removal efficiencies (DRE’s) were achieved under the operating conditions of these tests through adequate secondary combustion processing.     

Rotary Kiln Incineration IV. An Indepth Study— Kiln Exit,Transition and Afterburner Sampling During Liquid CCl4 Processing

Detailed temperature and stable species concentration data are presented from the kiln exit, transition section and afterburner of a full-scale incinerator facility firing natural gas/carbon tetrachloride/air. The data are collected as part of a cooperative program involving university, industry and government participation. The overall goal of the program is to develop an understanding and predictive capability for rotary kiln and afterburner performance as influenced by basic design and operational parameters. The data demonstrate that nonuniformities in stable species and temperature exist, under certain operating conditions, at the kiln exit in the vertical direction only. Measurements from the transition section indicate that non-uniformities may exist within this region under certain operating conditions. Flow perturbations from within the kiln can persist into the afterburner, although the degree of nonuniformity is substantially reduced compared to either the kiln or transition sections. High destruction and removal efficiencies were achieved under all operating conditions of these tests through a combination of kiln and secondary combustion processing.     

Rotary Kiln Incineration II. Laboratory-Scale Desorption and Kiln-Simulator Studies—Solids

With landfill costs increasing and regulations on landfilling becoming more stringent, alternatives to conventional hazardous waste treatment strategies are becoming more desirable. Incineration Is presently a permanent, proven solution for the disposal of most organic contaminants, but also a costly one, especially in the case of solids which require some auxiliary fuel. The goal of this research is to develop an understanding of the phenomena associated with the evolution of contaminants from solids In the primary combustor of an Incineration system. A four-fold approach is being used. First, a bench-scale particle characterization reactor was developed to study the transport phenomena on a particle basis, where the controlling processes are mainly intraparticle. Second, a bed-characterization reactor was built to examine the controlling transport phenomena within a bed of particles, where the processes are primarily interparticle. The results of these studies can be applied to any primary combustor. A pilot-scale rotary kiln was developed to study the evolution of contaminants from solids within a realistic temperature and rotation environment. Finally, in situ measurements are being obtained from a full-scale rotary-kiln.

This paper describes results obtained in a study using a commercial sorbent contaminated with toluene. The data are from the particle-characterization reactor and the rotary-kiln simulator. The results show that the method of contamination and charge size do not have a large effect on desorption, while temperature and contaminant concentration are important parameters In the evolution of contaminants in a rotary kiln.