The value of information on the response function of crops to soil salinity

The expected profitability to farmers from acquiring additional information on the biological response function of crop yield to soil salinity is investigated. First, a switching regression approach to estimate piecewise linear response function with critical threshold level is presented. Then, an optimization irrigation model is developed, aimed at determining the optimal use of irrigation water for soil leaching. Finally, a loss function is defined, the expected value of sample information is calculated and the optimal number of additional needed observations is determined. At each stage, an empirical analysis, using data from potato field experiments in Israel, is presented.     

The effect of different educational interventions on schoolchildren's knowledge of earthquake protective behaviour in Israel

Knowledge of appropriate behaviour during an earthquake is crucial for prevention of injury and loss of life. The Israeli Home Front Command conducts a yearly earthquake education programme in all Israeli schools, using three types of educational interventions: lectures, drills and a combination of the two. The aim of this study was to evaluate the effectiveness of these interventions in providing students with knowledge. We distributed a questionnaire to 2,648 children from the 5th and 6th grades in 120 schools nationwide. Knowledge scores for both 5th and 6th grades were increased, regardless of type of intervention, compared to the non-exposure group. A combined intervention of lectures and drills resulted in the highest knowledge scores. Our findings suggest that for the age group studied a combination of lectures and drills will likely prepare students best for how to behave in the event of an earthquake.     

Modeling concentration-dependent sorption-desorption hysteresis of atrazine in a loam soil

Nonequilibrium sorption plays an active role in the transport of organic contaminants in soil. We applied a two-stage, one-rate model (2S1R) and a new, nonlinear variant (2S1RN) of this model to examine the effects of wastewater irrigation on the sorption kinetics of atrazine (2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine) in soil. The models were applied to previously published sorption-desorption data sets, which showed pronounced deviations between sorption curves and desorption curves (sorption-desorption hysteresis). Moreover, the slopes of the desorption curves decreased with decreasing concentration. Different treatments had been used, and two experimental time steps (2 and 14 d) were used. Treatments considered were lipid removal, fulvic and humic acid removal, and untreated soil. The 2S1R model was unable to reproduce the observed type of hysteresis, but the 2S1RN model, which assumes that the sorption-desorption process follows a power function relationship, was able to reproduce the observed type of hysteresis. Visually, applying the new model improved the model fits in all test cases. Statistically, as tested by an extra sum of squares analysis, the new model performed significantly better in 50% of all test cases. According to an example simulation, the choice of the sorption model has a considerable impact on the prediction of atrazine transport in soil.     

A model for the analysis of seasonal aspects of water quality control

A multiseasonal mathematical programming model for the analysis of water quality control within a river basin is presented. Phenomena of interseasonal variation in flow intensity and the river's pollutant assimilative capacity are introduced into the model by defining several seasons and their characterizations by seasonal parameters. An application of the model to a typical case situation is reported. The results suggest that seasonal adjustments in the treatment levels of wastewater treatment plants involve a considerable saving potential in comparison with a situation in which treatment levels are rigidly determined for the entire year.     

Interactions of sodium azide with triazine herbicides: effect on sorption to soils

Sodium azide (NaN(3)) is one of the biocides commonly used to inhibit microbial growth during sorption experiments. However, a few reports have suggested that NaN(3) can react with the analyte of interest. In this study, the interactions of NaN(3) with triazine herbicides were investigated and the effect of atrazine transformation on its sorption to soil was evaluated. The concentration of atrazine in the presence of NaN(3) decreased significantly over period of time. After 14 days, only 38% of the initial atrazine concentration (10 mg l(-1)) was detected in a solution containing 1,000 mg l(-1) NaN(3) at pH 5.5. The magnitude and the rate of atrazine transformation increased with increase in NaN(3) load and with decrease in pH. In contrast to atrazine behavior, the concentrations of prometon and ametryn did not change during the experiment. GC/MS analysis indicated that the chlorine atom of atrazine is replaced by the azide group yielding 2-azido-4-(ethylamino)-6-(isopropylamino)-s-triazine. Atrazine transformation by NaN(3) significantly affected sorption of herbicide to soil. The presence of NaN(3) affects indirectly the sorption of atrazine due to competitive effect of its derivative. Our results demonstrated that the application of NaN(3) as a biocide in sorption-desorption experiments must be carefully evaluated. This issue is vital for sorption experiments conducted over long periods of time or/and with concentration of NaN(3) higher than 100 mg l(-1).