全文获取类型
收费全文 | 554篇 |
免费 | 47篇 |
国内免费 | 269篇 |
专业分类
安全科学 | 46篇 |
废物处理 | 43篇 |
环保管理 | 47篇 |
综合类 | 342篇 |
基础理论 | 117篇 |
污染及防治 | 192篇 |
评价与监测 | 32篇 |
社会与环境 | 23篇 |
灾害及防治 | 28篇 |
出版年
2023年 | 22篇 |
2022年 | 28篇 |
2021年 | 33篇 |
2020年 | 35篇 |
2019年 | 24篇 |
2018年 | 32篇 |
2017年 | 32篇 |
2016年 | 37篇 |
2015年 | 52篇 |
2014年 | 48篇 |
2013年 | 68篇 |
2012年 | 63篇 |
2011年 | 48篇 |
2010年 | 44篇 |
2009年 | 39篇 |
2008年 | 35篇 |
2007年 | 44篇 |
2006年 | 18篇 |
2005年 | 19篇 |
2004年 | 12篇 |
2003年 | 15篇 |
2002年 | 22篇 |
2001年 | 11篇 |
2000年 | 10篇 |
1999年 | 19篇 |
1998年 | 8篇 |
1997年 | 6篇 |
1996年 | 8篇 |
1995年 | 11篇 |
1994年 | 6篇 |
1993年 | 8篇 |
1992年 | 7篇 |
1991年 | 1篇 |
1984年 | 1篇 |
1982年 | 2篇 |
1981年 | 2篇 |
排序方式: 共有870条查询结果,搜索用时 250 毫秒
181.
水中不同铅浓度(5—500μg/l)急性致毒使白鲢血液中δ-氨基乙酞丙酸脱水酶(ALA-D)活性随铅浓度的增加而呈线性关系下降.温度越高,铅对酶活性的抑制越明显。0.1ppm汞、镉、铜,0.008ppm滴滴涕和0.84ppm对硫磷急性致毒,除对硫磷外对草鱼血ALA-D活性皆没有显著性影响.锌、镉、铜分别与铅混合,降低铅对ALA-D酶的抑制作用,致毒四天,可恢复甚至刺激鱼血ALA-D酶活性.被重金属(包括铅)污染的S湖中白鲢血ALA-D酶表现出明显的抑制作用,但鲤鱼血ALA-D酶却测不出抑制作用 相似文献
182.
本研究采用两种提纯方法并以Mg-Al、Fe-Al(1)、Fe-Al(2)聚合羟基物为改性剂对膨润土进行提纯和改性。通过对膨润土改性过程中的悬浮液浓度、柱撑温度、老化温度、老化时间等影响因素的考察,系统研究了不同制备条件对改性膨润土去除Cu~(2+)、Cd~(2+)、Pb~(2+)的效果,并通过XRD分析了提纯和改性方法对膨润土结构的影响。实验结果表明,利用六偏磷酸钠提纯后制得的Mg-Al改性膨润土对Cu~(2+)、Cd~(2+)、Pb~(2+)的去除效果较原土分别提高了24.94%、40.37%和6.80%,其主要影响因素分别为:老化时间和柱撑温度。 相似文献
183.
Fan Feng Cheng-Shan Duan Xi Tang Xi Chen Xuan Lu Xi-Lin Chai Qaisar Mahmoo Chong-Jian Tang Li-Yuan Chai 《环境科学学报(英文版)》2020,32(5):117-127
Biological nitrogen removal process could be affected due to the presence of heavy metals owing to their toxicity and accumulation in the sludge.In this study,the impact of Cu~(2+)shock on a long-term nitritation operation was investigated in an air-lift reactor with selfrecirculation.Both the dynamics of microbial community and inhibition kinetics under Cu~(2+) stress were ascertained.The results showed that Cu~(2+) exerted severe inhibition on nitritation performance of an air-lift reactor(ALR) at 25 mg/L.The corresponding NH_4~+-N removal efficiency decreased to below 50%,which was mainly due to the variation of microbial community structure,especially the inhibition of nitrifiers like Nitrosomonas(the relative abundance decreased from 30% to 1% after Cu~(2+)inhibition).Kinetic parameters were obtained and compared after fitting the Haldane model.The long-term Cu~(2+) stress on the ALR aggravated the ammonium affinity and the resistance to substrate self-inhibition of the nitritation sludge,but reduced the resistance to Cu~(2+) inhibition.Furthermore,Cu~(2+)acted as uncompetitive inhibitor on nitritation process.Our results provide new insights into the nitritation characteristics under long-term Cu~(2+) stress. 相似文献
184.
Richao Wang Zibing Yuan Junyu Zheng Cheng Li Zhijiong Huang Wenshi Li Yan Xie Yiran Wang Kaiyang Yu Lejun Duan 《环境科学学报(英文版)》2020,32(10):138-150
Speciated characterization of Volatile Organic Compounds (VOCs), including oxygenated VOCs (OVOCs), from construction machinery and river ships in China is currently lacking. In this regard, we conducted field measurement on speciated VOC (including OVOC) emissions from six construction machinery and five river ships in the Pearl River Delta (PRD) region to identify VOC emission characteristics. We noticed that OVOC emissions from construction machinery and ships accounted for more than 50% of the total VOC emissions, followed by alkenes, aromatics and alkanes. Formaldehyde and acetaldehyde were the most emission species, accounting for 61.8%-83.2% of OVOCs. For construction machinery, the fuel-based emission factors of roller, grader and pile driver were 3.12, 3.12 and 7.36 g/kg, respectively. With the rigorous restraint by the national emission standards, VOC emissions of construction machinery had decreased considerably, especially during stage Ⅲ. Ozone formation potential was also significantly reduced due to the significant decrease in emissions of OVOCs and alkenes with higher reactivity. For river ships, the fuel-based emission factors of cargo ships and speedboat were 1.46 and 0.44 g/kg, respectively. VOC emissions from construction machinery and river ships in Guangdong Province in 2017 were 8851.0 and 4361.0 ton, respectively. This study filled the knowledge gaps of reactive gas emissions from different kinds of non-road mobile sources over the PRD, and more importantly, highlighted the necessity in adding OVOC measurement to give a complete and accurate depiction of reactive gas emissions from non-road mobile sources. 相似文献
185.
Shouliang Huo Chunzi M Beidou Xi Yali Zhang Fengchang Wu Hongliang Liu 《环境科学学报(英文版)》2018,30(5):54-66
Nutrient criteria provide a scientific foundation for the comprehensive evaluation, prevention,control and management of water eutrophication. In this review, the literature was examined to systematically evaluate the benefits, drawbacks, and applications of statistical analysis,paleolimnological reconstruction, stressor-response model, and model inference approaches for nutrient criteria determination. The developments and challenges in the determination of nutrient criteria in lakes and reservoirs are presented. Reference lakes can reflect the original states of lakes, but reference sites are often unavailable. Using the paleolimnological reconstruction method, it is often difficult to reconstruct the historical nutrient conditions of shallow lakes in which the sediments are easily disturbed. The model inference approach requires sufficient data to identify the appropriate equations and characterize a waterbody or group of waterbodies, thereby increasing the difficulty of establishing nutrient criteria. The stressor-response model is a potential development direction for nutrient criteria determination, and the mechanisms of stressor-response models should be studied further. Based on studies of the relationships among water ecological criteria, eutrophication, nutrient criteria and plankton, methods for determining nutrient criteria should be closely integrated with water management requirements. 相似文献
186.
187.
Zhengzheng Zhang Hong Li Hongyan Liu Runxiang Ni Jinjuan Li Liqun Deng Defeng Lu Xueli Cheng Pengli Duan Wenjun Li 《环境科学学报(英文版)》2016,28(9):71-81
Atmospheric aerosol particle samples were collected using an Ambient Eight Stage(Non-Viable) Cascade Impactor Sampler in a typical urban area of Beijing from 27 th Sep.to 5th Oct.,2009.The surface chemistry of these aerosol particles was analyzed using Static Time of Flight-Secondary Ion Mass Spectrometry(Static TOF-SIMS).The factors influencing surface compositions were evaluated in conjunction with the air pollution levels,meteorological factors,and air mass transport for the sampling period.The results show that a variety of organic ion groups and inorganic ions/ion groups were accumulated on the surfaces of aerosol particles in urban areas of Beijing;and hydrophobic organic compounds with short-or middle-chain alkyl as well as hydrophilic secondary inorganic compounds were observed.All these compounds have the potential to affect the atmospheric behavior of urban aerosol particles.PM1.1–2.1and PM3.3–4.7had similar elements on their surfaces,but some molecules and ionic groups demonstrated differences in Time of Flight-Secondary Ion Mass Spectrometry spectra.This suggests that the quantities of elements varied between PM1.1–2.1and PM3.3–4.7.In particular,more intense research efforts into fluoride pollution are required,because the fluorides on aerosol surfaces have the potential to harm human health.The levels of air pollution had the most significant influence on the surface compositions of aerosol particles in our study.Hence,heavier air pollution was associated with more complex surface compositions on aerosol particles.In addition,wind,rainfall,and air masses from the south also greatly influenced the surface compositions of these urban aerosol particles. 相似文献
188.
189.
Polybrominated diphenyl ethers in background surface soils from the Yangtze River Delta (YRD), China: occurrence,sources, and inventory 总被引:1,自引:0,他引:1
Yan-Ping Duan Xiang-Zhou Meng Chao Yang Zhao-Yu Pan Ling Chen Ran Yu Feng-Ting Li 《Environmental science and pollution research international》2010,17(4):948-956
Purposes
Very few data for polybrominated diphenyl ethers (PBDEs) were available in the Yangtze River Delta (YRD), one of the most developed and urbanized region in China. In this study, Chongming Island, located at the estuary of the Yangtze River, was selected as background area to investigate the occurrence, sources, and inventory of PBDEs. 相似文献190.
Jin Ma Li-bo Pan Qin Wang Chun-ye Lin Xiao-li Duan Hong Hou 《Environmental geochemistry and health》2018,40(1):295-301
A total of 60 children (31 males and 29 females) between the ages of 3 and 12 years were randomly selected from Lanzhou City in Gansu Province, northwest China. Hand (soil/dust) SD samples from these children were collected using hand wipes. We determined the approximate amounts of hand SD and the concentrations of three tracer soil elements (Ce, Y, and V) in these samples. The approximate amounts of hand SD ranged from 42.28 to 173.76 mg, with a median value of 85.42 mg. In addition, the mean amounts of hand SD estimated using the concentrations of Ce, Y, and V in the samples were 4.63, 3.43, and 3.42 mg, respectively. The amount of hand SD varied greatly among the age groups: primary school children had more hand SD than kindergarten children, males had more hand SD than females, and children from rural areas had more hand SD than those from urban areas. The rates of daily ingestion of hand SD for kindergarten and primary school children were estimated to be 7.73 and 6.61 mg/day, respectively. 相似文献