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571.
572.
A series of H-SAPO-34 zeolites were synthesized by a hydrothermal method in fluoride media. The as-synthesized H-SAPO-34 zeolites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), N2 physisorption, temperature-programmed desorption of NH3 (NH3-TPD) and nuclear magnetic resonance (NMR) measurements. The results showed that a certain concentration of F− anions promoted the nucleation and crystallization of H-SAPO-34. The H-SAPO-34 synthesized in the fluoride media showed high crystallinity, uniform particle size distribution, large specific surface area and pore volume, and enhanced acidity. Therefore, Cu/SAPO-34 based on the fluoride-assisted zeolite showed a broadened temperature window for the selective catalytic reduction of NO by NH3 (NH3-SCR) reaction due to the enhanced acidity of the zeolite and the improved dispersion of copper species. 相似文献
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577.
气瓶水压试验合格标准实验研究 总被引:4,自引:1,他引:3
水压试验是气瓶检验的主要项目,将容积残余变形率超过10% 作为气瓶报废的标准沿用至今。笔者通过实验,分析了气瓶水压试验现行评定标准存在的问题,并对采用容积弹性变形作为评定指标进行了探讨,以期为制订更合理的水压试验标准提供有益的启示。 相似文献
578.
Arsenic (As) is a pervasive and ubiquitous environmental toxin that has created catastrophic human health problems world-wide.
Chlamydomonas reinhardtii is a unicellular green alga, which exists ubiquitously in freshwater aquatic systems. Arsenic metabolism
processes of this alga through arsenate reduction and sequent store and efflux were investigated. When supplied with 10 mol/L arsenate,
arsenic speciation analysis showed that arsenite concentration increased from 5.7 to 15.7 mg/kg dry weight during a 7-day period,
accounting for 18%–24% of the total As in alga. When treated with different levels of arsenate (10, 20, 30, 40, 50 mol/L) for 7 days,
the arsenite concentration increased with increasing external arsenate concentrations, the proportion of arsenite was up to 23%–28%
of the total As in alga. In efflux experiments, both arsenate and arsenite could be found in the efflux solutions. Additionally, the efflux
of arsenate was more than that of arsenite. Furthermore, two arsenate reductase genes of C. reinhardtii (CrACR2s) were cloned and
expressed in Escherichia coli strain WC3110 (ΔarsC) for the first time. The abilities of both CrACR2s genes to complement the arsenatesensitive
strain were examined. CrACR2.1 restored arsenate resistance at 0.8 mmol/L. However, CrACR2.2 showed much less ability
to complement. The gene products were demonstrated to reduce arsenate to arsenite in vivo. In agreement with the complementation
results, CrACR2.1 showed higher reduction ability than CrACR2.2, when treated with 0.4 mmol/L arsenate for 16 hr incubation. 相似文献
579.
随着中国养殖业的迅速发展,禽畜粪便的排放数量逐年增加。据统计,禽畜粪尿排放量每头牛为55kg/d~65 kg/d,每头猪为3.5 kg/d~11.0 kg/d,每只鸡为0.10 kg/d~0.15 kg/d,每只羊为2.66 kg/d。大量的禽畜粪便不经处理而排入环境,将会对地表水、地下水、土壤和空气造成严重的污染,并危及禽畜本身及人体健康。因此,实现禽畜粪便的减量化、无害化及资源化,防止和消除养殖场粪便的污染及其利用问题的研究,对于生态环境的保护、实施可持续发展战略都具有十分重要的意义。本试验利用日本JST赠送的生态厕所反应装置为试验设备,分别以木屑和木屑与秸秆混合物为微生物载体,对牛粪便进行减量化处理技术研究。旨在为研究中国农业的玉米作物秸秆是否可以替代木屑作为反应过程中的调理剂,达到对禽畜养殖业粪便良好的减量化处理效果,减轻对环境的污染,同时也为中国大量的农作物秸秆寻找另一条资源化利用途径。 相似文献
580.
Yao Chen Jinhui Li Huabo Duan Zhishi Wang 《Frontiers of Environmental Science & Engineering in China》2011,5(2):167-174
Mechanical waste-processing methods, which combine crushing and separation processes for the recovery of valuable materials,
have been widely applied in waste printed wiring board (PWB) treatment. However, both the high impact toughness and the tensile
and flexural strengths of whole PWB with a laminated structure result in great energy consumption and severe abrasion of the
cutters during multi-level crushing. In addition, the high temperatures occurring in continual crushing probably cause the
decomposition of the polymer matrix. A thermal-crack method using residual steam as the heating medium has been developed
to pre-treat waste PWBs. This treatment reduces the mechanical strength in order to improve the recovery rate of valuable
materials in subsequent mechanical recycling. The changes of the PWBs’ macro-mechanical properties were studied to evaluate
thermal expansion impacts associated with changes in temperature, and the dynamic dislocation micro-structures were observed
to identify the fracture mechanism. The results showed that thermal cracking with steam at the temperature of 500 K can effectively
attenuate the mechanical properties of waste PWBs, by reducing the impact, tensile and flexural strengths respectively, by
59.2%, 49.3% and 51.4%, compared to untreated PWB. Thermal expansion can also facilitate the separation of copper from glass
fiber by reducing peel resistance by 95.4% at 500 K. It was revealed that the flexural fracture was a transverse cracking
caused by concentrated stress when the heating temperature was less than 500 K, and shifted to a vertical cracking after exceeding
500 K. 相似文献