In this study, different pretreatment strategies of sugarcane bagasse prior to citric acid modification were investigated in terms of Pb2+ adsorption capacity. Pretreatment strategies included the use of NaOH, HCl, and C2H5OH in various concentrations. In order to fundamentally understand how these pretreatment methods affect the modification of sugarcane bagasse by citric acid as well as the Pb2+ adsorption capacity of sugarcane bagasse, three main components of sugarcane bagasse namely cellulose, hemicellulose, and lignin were isolated and esterified by citric acid under the same conditions. ATR-FTIR, XPS, SEM, and an analysis of the number of carboxylic acid groups were used to investigate the physicochemical and chemical properties of the materials. These three components were proved to participate in adsorption and induce the esterification with citric acid. Hence, pretreatment with ethanol and 0.01 M NaOH which could retain cellulose, hemicellulose, and lignin in sugarcane bagasse achieved a high Pb2+ adsorption capacity, i.e., 122.4 and 97 mg/g after the esterification with citric acid. In contrast, pretreatment with 0.5 M NaOH and 0.1 M HCl removed lignin and hemicellulose, leading to the lowest value of approximately 45 mg/g for citric acid esterified-pretreated sugarcane bagasse. XPS analysis and number of carboxylic group measurement confirmed the esterification between bagasse and citric acid. To understand the adsorption mechanism of adsorbent, two kinetic models including pseudo-first-order model and pseudo-second-order model were applied. The experimental data were well described by the pseudo-second-order model. The adsorption isotherm data were fitted Langmuir and Freundlich.
E-waste management in Vietnam poses real challenges such as the lack of specific e-waste legislation, the strong involvement of “craft villages” and the missing of monitoring data. Many issues (e.g., pollution level, generated waste, health of workers and resident living at recycling sites) lead to the limited access to these craft villages. Thus, there is no comprehensive picture on e-waste management in Vietnam available today. This research focuses on the current situation of e-waste management. Sources of e-waste, collection and treatment in Vietnam are investigated by utilizing most available sources of information (published journals, unpublished works from projects and reports from institutes, ministry) together with the interviewed data from experts, collectors, workers and especially, biggest traders in the field. Based on this information, the processes applied in Vietnam, both in the formal and informal sector, have been analyzed systematically in terms of inputs, outputs, potential emissions and related risks for workers. From these aspects, a comparison in terms of legal frameworks, collection and treatment at both formal and informal sector between Vietnam and other countries in Asian region was undertaken. Thus, major challenges of e-waste management and relatively comprehensive image of e-waste management and treatment in Vietnam have been identified. 相似文献