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651.
This article is intended to provide background information on leachate management in closed landfill sites based on a comparison
of two landfill sites and the identification of leachate characteristics depending on the final cover and the season. Site
S is older and has no final cover, while site J is younger and has final capping. The results of leachate analysis from the
two landfills show that the biological oxygen demand to chemical oxygen demand ratio decreases below 0.1 to the range 0.05–0.07
for site S, whereas the ratio at site J was in the range 0.08–0.55. The inorganic nitrogen concentration was in the range
169.9–386.1 mg/l with an average of 265.2 mg/l at site S. Ammonia nitrogen accounted for 98.9% of the total nitrogen. The
absence of a final cover on closed landfill sites may contribute to the stabilization of such landfills due to flushing. The
nitrogen content at landfill S dropped in the summer, whereas it decreased in the fall at site J. A higher fluctuation in
the pollutant levels of organic matters and nitrogen at the younger landfill site was observed, compared to the older site,
even though the younger site had final capping. Therefore, intensive leachate management should be arranged at the early stages
after closing for proper treatment. Specifically, nitrogen management of leachate is a critical factor in treatment operations. 相似文献
652.
Jeong-Hun Kim Yong-Chil Seo Deepak Pudasainee Sang-Hyeob Lee Sung-Jin Cho Ha-Na Jang Ju-Myon Park Geum-Ju Song Kyu-Shik Park 《Journal of Material Cycles and Waste Management》2009,11(3):183-190
The development of regulations patterned after the United States’ requirement for maximum achievable control technology (MACT)
to control hazardous air pollutants from major industrial sources in Korea is in progress. Current management practices and
installed air pollution control devices were surveyed; emission tests and continuous emission data collected from facilities
under operation were assessed considering other MACT requirements such as reporting, report keeping requirements. Emission
sampling and air pollutant analysis were carried out at representative hazardous waste incinerators installed with wet-type
and dry-type air pollution control devices. Korean and United States Environmental Protection Agency methods were used for
sampling and analysis. The major heavy metals emitted were Zn, Ni, Pb, and Cr. The heavy metal removal efficiency of existing
air pollution control devices was greater than 99%. The average mercury removal efficiency was more than 30%. Toluene; m,p-xylene; o-xylene; benzene; dichloromethane; styrene; ethylbenzene; 1,3-dichlorobenzene; and 1,2,4-trimethylbenzene were the major volatile
organic compounds emitted. The emissions from field tests were compared, reviewed, and analyzed with respect to MACT regulations
to check applicability. Finally, draft guidelines were suggested for effective hazardous air pollutant management in Korea. 相似文献
653.
Ji-Hoon Jeong Byung-Taek Oh Jai-Young Lee 《Journal of Material Cycles and Waste Management》2009,11(3):208-213
Most sludge has historically been disposed of in landfills and by ocean dumping but, because of its heavy metal content, this
will be totally banned in Korea starting in 2012, based on the London Dumping Convention. Therefore, treatment and disposal
methods that are environmentally friendlily are urgently required. The recycling of sewage sludge is a good treatment method
for solving sludge problems in an environmentally friendly way. In this study, physical and environmental tests were conducted
to evaluate the feasibility of using the by-products of thermal hydrolysis of sewage sludge as barrier layer materials in
the final cover systems for landfills. In addition, testing methods for freezing-thawing (KS F 2332) and wetting-drying (KS
F 2330) cycles were conducted to assess the effects of cold and hot soil climates starting from pavement. These tests yielded
positive results for alternative materials for the barrier layer in a final cover system for a landfill. 相似文献
654.
Sujeeva Setunge Natalie Nguyen Brendan Lee Alexander Louise Dutton 《Water, Air, & Soil Pollution: Focus》2009,9(5-6):381-391
Concrete is usually the preferred material for construction of structures in contact with water during their service life. Early age exposure to water is beneficial for curing of concrete structures. However, the pollution of water from freshly cast concrete in contact with water has not been investigated in detail. A significant increase in the alkalinity has recently been observed in a stream in contact with freshly installed concrete culverts. High alkalinity has caused distress to fresh water fish in the stream. A preliminary laboratory study was commenced to explore the effect of leaching of alkali into water from freshly placed concrete. Freshly cast concrete specimens were exposed to fresh water, covering a range of conditions observed in the field such as volume of concrete/volume of water, age of exposure and cement content. Analysis of the results indicated that early age contact with fresh concrete can lead to an increase in the pH levels of water up to 11, similar to the levels of pH observed in pore water inside freshly cast concrete. It was noted that until an age of 4 days from casting of concrete, the age of exposure does not significantly affect the changes in the peak pH levels of water. Continuous monitoring of water in contact with concrete also indicated that the pH levels diminish with time, which is attributed to the possible reaction of calcium hydroxide with atmospheric carbon. The paper will present the experimental study, the results, analysis and outcomes as well as planning of a more comprehensive study to observe possible ways of reducing the leaching of alkali from freshly placed concrete. 相似文献
655.
Seong Kon Lee Gento Mogi Jong Wook Kim 《Journal of Loss Prevention in the Process Industries》2009,22(6):915-920
To provide national energy security in the 21st century, establishing a long-term strategic energy technology development is essential through selection and specialization. We established a strategic energy technology roadmap (ETRM) taking economic spin-offs, commercial potential, inner capacity, and technical spin-off into account. In this research, we suggest an integrated multi-criteria decision making (MCDM) approach, which is composed of more than two criteria as the assessment of the optimal alternatives and solutions in the real world with the fuzzy theory and analytic hierarchy process (AHP), to prioritize the weights of energy technologies of ETRM as we allocate R&D budget using a fuzzy analytic hierarchy process. Building technology is the most preferred technology in the sector of energy technologies against high oil prices. And the coal technology and transportation technology follows and take the 2nd and 3rd place with the fuzzy AHP approach. 相似文献
656.
Yuxin Wu Roelof Versteeg Lee Slater Douglas LaBrecque 《Journal of contaminant hydrology》2009,106(3-4):131-143
Calcium carbonate is a secondary mineral precipitate influencing zero valent iron (ZVI) barrier reactivity and hydraulic performance. We conducted column experiments to investigate electrical signatures resulting from concurrent CaCO3 and iron oxides precipitation under simulated field geochemical conditions. We identified CaCO3 as a major mineral phase throughout the columns, with magnetite present primarily close to the influent based on XRD analysis. Electrical measurements revealed decreases in conductivity and polarization of both columns, suggesting that electrically insulating CaCO3 dominates the electrical response despite the presence of electrically conductive iron oxides. SEM/EDX imaging suggests that the electrical signal reflects the geometrical arrangement of the mineral phases. CaCO3 forms insulating films on ZVI/magnetite surfaces, restricting charge transfer between the pore electrolyte and ZVI particles, as well as across interconnected ZVI particles. As surface reactivity also depends on the ability of the surface to engage in redox reactions via charge transfer, electrical measurements may provide a minimally invasive technology for monitoring reactivity loss due to CaCO3 precipitation. Comparison between laboratory and field data shows consistent changes in electrical signatures due to iron corrosion and secondary mineral precipitation. 相似文献
657.
The application of a mulch biofilm barrier for surfactant enhanced polycyclic aromatic hydrocarbon bioremediation 总被引:1,自引:0,他引:1
Lab scale mulch biofilm barriers were constructed and tested to evaluate their performance for preventing the migration of aqueous and surfactant solubilized PAHs. The spatial distribution of viable PAH degrader populations and resultant biofilm formation were also monitored to evaluate the performance of the biobarrier and the prolonged surfactant effect on the PAH degrading microorganism consortia in the biobarrier. Sorption and biodegradation of PAHs resulted in stable operation of the system for dissolved phenanthrene and pyrene during 150 days of experimentation. The nonionic surfactant could increase the solubility of phenanthrene and pyrene significantly. However, the biobarrier itself couldn't totally prevent the migration of micellar solubilized phenanthrene and pyrene. The presence of surfactant and the resultant highly increased phenanthrene or pyrene concentration didn't appear to cause toxic effects on the attached biofilm in the biobarrier. However, the presence of surfactant did change the structural composition of the biofilm. 相似文献
658.
659.
Y.M. Han S.C. Lee J.J. Cao K.F. Ho Z.S. An 《Atmospheric environment (Oxford, England : 1994)》2009,43(38):6066-6073
A previous study on PM2.5 carbonaceous aerosols measured with the thermal optical reflectance (TOR) method in fourteen Chinese cities is extended by subdividing total EC into char-EC and soot-EC. Average char-EC concentrations show great differences between the fourteen cities and between winter and summer periods, with concentrations of 8.67 and 2.41 μg m?3 in winter and summer, respectively. Meanwhile spatial and seasonal soot-EC variations are small, with average concentrations of 1.26 and 1.21 μg m?3 in winter and summer, respectively. Spatial and temporal distributions of char-EC, similar to EC, are mainly influenced by local fuel consumption, as well as the East Asian monsoon and some meteorological factors such as the mixing height and wet precipitation. The small spatial and seasonal variation of soot-EC is consistent with its regional-to-global dispersion, which may suggest that soot carbon is not local carbon, but regional carbon. Char-EC/soot-EC ratios show summer minimum and winter maximum in all cities, which is in good agreement with the difference in source contributions between the two periods. As OC/EC ratio is affected by the formation of the secondary organic aerosol (SOA), char-EC/soot-EC ratio is a more effective indicator for source identification of carbonaceous aerosol than previously used OC/EC ratio. 相似文献
660.
K.F. Ho Steven Sai Hang Ho S.C. Lee Y. Cheng Judith C. Chow John G. Watson P.K.K. Louie Linwei Tian 《Atmospheric environment (Oxford, England : 1994)》2009,43(40):6343-6351
Real-world vehicle emission factors for seventeen gas and particulate polycyclic aromatic hydrocarbons (PAHs) were quantified in the Shing Mun Tunnel, Hong Kong during summer and winter 2003. Naphthalene, acenaphthylene, and acenaphthene were the most abundant gas PAHs while fluoranthene and pyrene were the most abundant in the particle phase. Most (98%) of the gas PAHs consisted of two- and three-aromatic rings whereas most of the particle-phase PAHs were in four- (~60%) and five-ring (~17%) for fresh exhaust emissions. Average emission factors for the gas- and particle PAHs were 950–2564 μg veh?1 km?1 and 22–354 μg veh?1 km?1, respectively. Good correlations were found between diesel markers (fluoranthene and pyrene; 0.85) and gasoline markers (benzo[ghi]perylene and indeno[1,2,3-cd]pyrene; 0.96). Higher PAH emission factors were associated with a higher fraction of diesel-fueled vehicles (DV) passing through the tunnel. Separate emission factors were determined from diesel and non-diesel exhaust by the regression intercept method. The average PAH emission factor (i.e., sum of gas and particle phases) from DV (3085 ± 1058 μg veh?1 km?1) was ~5 times higher than that from non-diesel-fueled vehicles (NDV, 566 ± 428 μg veh?1 km?1). Ratios of DV to NDV emission factors were high for diesel markers (>24); and low for gasoline markers (<0.4). 相似文献