From Waste to Reuse: Manufacture of Ecological Composites Based on Biopolyethylene/wood Powder with PE-g-MA and Macaíba Oil

Journal of Polymers and the Environment - This work aimed to investigate the biopolyethylene (BioPE)/wood powder (WP) composites compatibilized with polyethylene-grafted maleic anhydride (PE-g-MA),...     

BTX in urban areas of eastern Spain: a focus on time variations and sources

Environmental Science and Pollution Research - Seasonal and daily cycles of BTX were studied in a non-industrialized city (Alicante) and an urban area near an oil refinery plant (Castellón) in...     

Comparative study on the susceptibility of freshwater species to copper-based pesticides

Copper compounds have been intentionally introduced into water bodies as aquatic plant herbicides, algicides and molluscicides. Copper-based fertilizers and fungicides have been widely used in agriculture as well. Despite the fact that copper is an essential element for all biota, elevated concentrations of this metal have been shown to affect a variety of aquatic organisms. Nonetheless, comparative studies on the susceptibility of different freshwater species to copper compounds have seldom been performed. This study was conducted to compare toxicity of copper-based pesticides (copper oxychloride, cuprous oxide and copper sulfate) to different freshwater target (Raphidocelis subcapitata, a planktonic alga and Biomphalaria glabrata, a snail) and non-target (Daphnia similis, a planktonic crustacean and Danio rerio, a fish) organisms. Test water parameters were as follows: pH = 7.4 +/- 0.1; hardness 44 +/- 1 mg/l as CaCO3; DO 8-9 mg/l at the beginning and > 4 mg/l at the end; temperature, fish and snails 25 +/- 1 degrees C, Daphnia 20 +/- 2 degrees C, algae 24 +/- 1 degrees C. D. similis (immobilization), 48-h EC50s (95% CLs) ranging from 0.013 (0.011-0.016) to 0.043 (0.033-0.057) mg Cu/l, and R. subcapitata (growth inhibition), 96-h IC50s from 0.071 (0.045-0.099) to 0.137 (0.090-0.174) mg Cu/l, were the most susceptible species. B. glabrata (lethality), 48-h LC50s from 0.179 (0.102-0.270) to 0.854 (0.553-1.457) mg Cu/l, and D. rerio (lethality), 48-h LC50s 0.063 (0.045-0.089), 0.192 (0.133-0.272) and 0.714 (0.494-1.016) mg Cu/l, were less susceptible than Daphnia to copper-based pesticides. Findings from the present study therefore suggest that increased levels of copper in water bodies is likely to adversely affect a variety of aquatic species.     

A conceptual framework for analyzing deltas as coupled social–ecological systems: an example from the Amazon River Delta

At the nexus of watersheds, land, coastal areas, oceans, and human settlements, river delta regions pose specific challenges to environmental governance and sustainability. Using the Amazon Estuary-Delta region (AD) as our focus, we reflect on the challenges created by the high degree of functional interdependencies shaping social–ecological dynamics of delta regions. The article introduces the initial design of a conceptual framework to analyze delta regions as coupled social–ecological systems (SES). The first part of the framework is used to define a delta SES according to a problem and/or collective action dilemma. Five components can be used to define a delta SES: social–economic systems, governance systems, ecosystems-resource systems, topographic-hydrological systems, and oceanic-climate systems. These components are used in association with six types of telecoupling conditions: socio-demographic, economic, governance, ecological, material, and climatic-hydrological. The second part of the framework presents a strategy for the analysis of collective action problems in delta regions, from sub-delta/local to delta to basin levels. This framework is intended to support both case studies and comparative analysis. The article provides illustrative applications of the framework to the AD. First, we apply the framework to define and characterize the AD as coupled SES. We then utilize the framework to diagnose an example of collective action problem related to the impacts of urban growth, and urban and industrial pollution on small-scale fishing resources. We argue that the functional interdependencies characteristic of delta regions require new approaches to understand, diagnose, and evaluate the current and future impacts of social–ecological changes and potential solutions to the sustainability dilemmas of delta regions.     

How changes in diet and trade patterns have shaped the N cycle at the national scale: Spain (1961–2009)

During the last five decades (1961–2009), Spain has experienced a considerable expansion in the nutrient cycle of its agricultural sector and, in particular, a threefold increase in anthropogenic reactive nitrogen inputs, from 536 Gg N year^?1 in 1961–1965 to 1673 Gg N year^?1 in 2005–2009. Import of feed (soybean, cereals, and cakes) from America and Europe to supply a growing livestock population constitutes the largest share of this increase, along with intensification of synthetic fertilizer use. While in the early 1960s, Spain was nearly self-sufficient in terms of food and feed supply, the net import of agricultural products presently equals domestic crop production, when expressed in terms of nitrogen content (ca. 650 Gg N year^?1). The most important driver of this shift appears to be the rapid change in domestic consumption patterns, which evolved from a typical Mediterranean diet to an animal-protein-rich diet similar to the North European and American diets. Besides livestock production mostly for national consumption, the Spanish agricultural system has specialized in vegetal products with low N content such as olive oil, wine, vegetables, and citrus fruit, which are for the most part exported. The nitrogen load exported outside the Spanish borders by rivers is very low (6.5 % of the total net N input). As a result of the high import and low export of reactive nitrogen, the Spanish mainland is suffering from considerable pollution by local emissions of reactive nitrogen forms to air and water.     

Chitosan Functionalization with Amino Acids Yields to Higher Copper Ions Adsorption Capacity

Chitosan (Chi) beads were conjugated with three different amino acids [namely, glutamic acid (GLU), methionine (MET), and taurine (TAU)] aiming to increase the divalent copper ions uptake in aqueous media. Scanning Electron Microscopy evidenced the development of a large porous structure after amino acid functionalization, associated with the increase in a number of amino groups in the polymer backbone. X-Ray Photoelectron Spectroscopy and Fourier-Transform Infrared Spectra analyses were also employed to assess the conjugation of these three different amino acids in chitosan backbone. Adsorption experiments were conducted in a batch process, at 298 K, and kinetic data indicated a slightly better fitting for the pseudo-first-order model when compared to pseudo-second order. Intraparticle diffusion model suggested a three-step mechanism for Cu(II) adsorption kinetics, limited by the third step, the intraparticle diffusion. The isotherm data fitting to the traditional Langmuir and Freundlich models indicated a better fit for the former case. The amino acid conjugation resulted in the increase of the maximum adsorption capacity for Cu(II) from 1.30 mmol g^?1 prior to amino acid conjugation to values as high as 2.31 mmol g^?1, 2.40 mmol g^?1 and 2.68 mmol g^?1 for Chi–TAU, Chi–GLU, and Chi–MET, respectively. These results are attributed to the introduction of additional amino groups and new carboxylate and amino acid residues into the chitosan backbone, which might also be explored for amino acid demanding applications.     

Rapid and Low-Cost Method for Evaluation of Nutrient Release from Controlled-Release Fertilizers Using Electrical Conductivity

Methods to determine nutrient release rates of coated fertilizers usually rely on chemical analyses, which often are time-consuming and/or expensive. Our goal was to develop an innovative and rapid low-cost method to evaluate nutrient release from polymer coated MAP or urea using conductometry. The release in water is determined by measuring the electric conductivity (EC) over time, with intervals dependent on release rates. In the case of soluble salt fertilizers, EC can be immediately determined and converted to a concentration using a calibration curve. In the case of urea, an additional step is needed to convert the neutral urea into ammonium. The release rates in water were assessed for a range of commercial and laboratory-coated fertilizers. A validation test demonstrated strong agreement with the release determined using analytical techniques. The EC method hence offers an easy way to quickly evaluate the time course of release of nutrients from controlled-release fertilizers.     

Scaling the quality of teammates' mental models: equifinality and normative comparisons

We tested the impact of teammates' team and task mental model sharedness on team processes and performance using 70 undergraduate teams that completed a series of missions on a PC‐based flight simulator. Moreover, we considered how the quality of mental models might moderate such relationships. Team processes were found to partially mediate the relationship between task mental model sharedness and team performance. Although team mental model sharedness failed to exhibit a significant linear relationship with team processes or performance, it did evidence a multiplicative relationship as moderated by the quality of those models. Team processes and performance were better among teams sharing higher‐quality team mental models than among teams evidencing less sharedness or who had lower‐quality models. Again, team processes partially mediated these relationships. Results are discussed in terms of the equifinality of mental model quality and applications to various team environments. Copyright © 2005 John Wiley & Sons, Ltd.