Estimating Hydraulic Properties of Volcanic Aquifers Using Constant‐Rate and Variable‐Rate Aquifer Tests1

Abstract: In recent years the ground‐water demand of the population of the island of Maui, Hawaii, has significantly increased. To ensure prudent management of the ground‐water resources, an improved understanding of ground‐water flow systems is needed. At present, large‐scale estimations of aquifer properties are lacking for Maui. Seven analytical methods using constant‐rate and variable‐rate withdrawals for single wells provide an estimate of hydraulic conductivity and transmissivity for 103 wells in central Maui. Methods based on constant‐rate tests, although not widely used on Maui, offer reasonable estimates. Step‐drawdown tests, which are more abundantly used than other tests, provide similar estimates as constant‐rate tests. A numerical model validates the suitability of analytical solutions for step‐drawdown tests and additionally provides an estimate of storage parameters. The results show that hydraulic conductivity is log‐normally distributed and that for dike‐free volcanic rocks it ranges over several orders of magnitude from 1 to 2,500 m/d. The arithmetic mean, geometric mean, and median values of hydraulic conductivity are respectively 520, 280, and 370 m/d for basalt and 80, 50, and 30 m/d for sediment. A geostatistical approach using ordinary kriging yields a prediction of hydraulic conductivity on a larger scale. Overall, the results are in agreement with values published for other Hawaiian islands.     

Degradation of the herbicide imazapyr by Fenton reactions

The degradation of the herbicide imazapyr has been carried out by three advanced oxidation processes involving iron ions as catalysts: Fentons reagent, photo-Fenton and electro-Fenton. We show that all processes are rapid and efficient. The kinetic rate constant was found to be k=5.4×10⁹ M^–1 s^–1. The mineralization of imazapyr is almost complete using the photo-Fenton and electro-Fenton processes.     

Extraction and Characterization of Nanocrystalline Cellulose from Doum (<Emphasis Type="Italic">Chamaerops humilis</Emphasis>) Leaves: A Potential Reinforcing Biomaterial

The aim of this investigation was to extract nanocrystalline cellulose (NCC) from Moroccan Doum fibers (Chamaerops humilis) by chemical treatment to examine their potential for use as reinforcement fibers in bionanocomposite applications. The chemical composition, morphological and structural properties of the Doum fibers was determined at different stages of chemical treatment. Morphological (transmission electron microscopy and scanning electron microscopy), structural characterization (X-ray diffraction, Fourier transformed infrared), thermal characterization (thermogravimetric analysis). The suspension electrostatic stabilization (zeta potential) of NCCs was also carried out. The results of these characterization analysis found that average size of the NCC is 220 nm in length and 11 nm in diameter, with high crystallinity index (93 %), a thermal stability comparable to that of untreated Doum fibers (degradation temperature 340 °C), which is reasonably promising for the use of these nanofibers in reinforced-polymer manufacturing, and a good stability in water suspension that it allows their utilization such as reinforcement of the water-soluble polymers to prepare the bio-nanocomposite.     

Dynamics of heavy-metal transfer between biotic (Cytheria chione and Cerastoderma edule) and abiotic (water and sediment) components in marine environment (Bay of Martil, Moroccan Mediterranean coast)

This study deals with the transfer of heavy metals (Hg, Cd, Pb, Cr, Ni, Ti, Zn, and Cu) between abiotic and biotic components (Cytheria chione and Cerastoderma edule) in the inshore intertidal zones of Tetouan/Martil over 2 yr of investigation (1992-1994). Analysis of the heavy-metal accumulation kinetics in Cytheria chione and Cerastoderma edule shows that their highest contents occur during the spring-summer period when an important proliferation of the plankton biomass occurs. However, the accumulation of Cd is higher during the period between winter and spring. In general, heavy-metal concentrations are higher at Cytheria chione than at Cerastoderma edule. These results, according to previous studies, suggest the presence of significant correlations and dynamic reciprocal transfer of heavy metals among seawater, sediment, and molluscs. They also suggest that the level of contamination of decreasing heavy metals follows the sequence: sediment, organisms, and water. Among the molluscs investigated, the variability of the thallium (Tl) contents is difficult to detect due to the very weak presence of this metal in the analysed tissues.     

One-dimensional numerical modelling of dam-break waves over movable beds: application to experimental and field cases

This paper reports a numerical study on dam-break waves over movable beds. A one-dimensional (1-D) model is built upon the Saint-Venant equations for shallow water waves, the Exner equation of sediment mass conservation and a spatial lag equation for non-equilibrium sediment transport. The set of governing equations is solved using an explicit finite difference scheme. The model is tested in various idealized experimental cases, with fairly good agreement between the numerical predictions and measurements. Discrepancies are observed at the earlier stage of the dam-break wave and around the dam location due to no vertical velocity component being taken into account. Sensitivity tests confirm that the friction coefficient is an important parameter for the evaluation of sediment transport processes operating during a dam-break wave. The influence of the non-equilibrium adaptation length (or the lag distance) is negligible on the wavefront celerity and weak on the free surface and bed profiles, which indicates that one may ignore the spatial lag effect in dam-break wave studies. Finally, the simulation of the Lake Ha!Ha! dyke-break flood event shows that the model can provide relevant results if a convenient formula for computing the sediment transport capacity and an appropriate median grain diameter of riverbed material are selected.     

Organochlorine insecticide residues in Egyptian mothers’ milk

Two hundred ninety‐two mother's milk samples were collected during 1994 from ten Egyptian governorates representing rural, metropolitan, and newly reclaimed desert areas. The samples were analyzed for 14 organochlorine insecticides and metabolites using electron capture gas chromatography and confirmed by gas chromatography/mass spectrometry (GC/MS). The overall samples average showed that the most abundant organochlorine insecticide residues were p,p'‐DDE, α‐endosulfan, β‐HCH and, p,p’‐DDT. Residues in the range of not detectable to less than 14μg/l whole milk were recorded for α‐HCH, heptachlor, heptachlor epoxide, aldrin, dieldrin, endrin endrin aldehyde and p,p'‐DDD. The percentage of samples exceeding the acceptable daily intake for children (ADIs) set by the FAO/WHO ranged from 19% to 44% in all governorates included in the study except the governorate of Minia in which only 2.6% of the samples exceeded the ADI values. The insecticides exceeding ADI values are mostly heptachlor and heptaclor epoxide (ADI = 3.12 μg/1 whole milk).     

Changes in the central and peripheral circulatory system in response to the cold: own studies using impedance plethysmography and Doppler ultrasound

The aim of the study was to determine the cardiovascular response to continuous (4 °C for 60 min) and intermittent (10 min at 4?°C and 10 min at room temperature alternately) exposure to the cold in 30 healthy young men. The subjects were equipped with a set of identical clothing (insulation 2.1 clo) and during the stay in the chamber and outside performed the same activities, i.e., walking on a treadmill at a speed of 0.5?km/h. The tests included assessing the central circulatory system using the Holter system and assessing the peripheral circulatory system using impedance plethysmography and Doppler ultrasound. The analysis of the parameters that describe the central and peripheral circulation poses a difficulty in determining which variant of exposure constitutes a greater load on the circulatory system. It should be noted that even the conditions used in the study may cause adverse effects in the cardiovascular system.     

Vulnerability of tourism to climate change on the Mediterranean coastal area of El Hammam–EL Alamein,Egypt

Environment, Development and Sustainability - The north-western Mediterranean coast of Egypt, including the study area from El Hammam to EL Alamein, is a hub for economic and coastal tourism...     

Short-term, real-time forecasting of hourly ozone, NO2 and NO levels by means of multiple linear regression modelling

Conclusions  The results are at least as good as those obtained with much more sophisticated models. Furthermore, the models can be easily run on a simple PC. This approach may provide a good diagnostic network (as seen in Bilbao) with real-time, short-term prognostic capabilities for a given location. The models have been built for Bilbao and are applicable only in this location. However, using the same methodology, similar results could be obtained in other environments if a good diagnostic network is available. The full paper is published in the Internet journal ‘Gate to EHS (Environmental and Health Science)’, in June 2001, and can be called up and cited by way of the DOI:http://dx.doi.org/10.1065/ehs2001.06.009     

The mutagenic effect of tobacco smoke on male fertility

Despite the association between tobacco use and the harmful effects on general health as well as male fertility parameters, smoking remains globally prevalent. The main content of tobacco smoke is nicotine and its metabolite cotinine. These compounds can pass the blood-testis barrier, which subsequently causes harm of diverse degree to the germ cells. Although controversial, smoking has been shown to cause not only a decrease in sperm motility, sperm concentration, and an increase in abnormal sperm morphology, but also genetic and epigenetic aberrations in spermatozoa. Both animal and human studies have highlighted the occurrence of sperm DNA-strand breaks (fragmentation), genome instability, genetic mutations, and the presence of aneuploids in the germline of animals and men exposed to tobacco smoke. The question to be asked at this point is, if smoking has the potential to cause all these genetic aberrations, what is the extent of damage? Hence, this review aimed to provide evidence that smoking has a mutagenic effect on sperm and how this subsequently affects male fertility. Additionally, the role of tobacco smoke as an aneugen will be explored. We furthermore aim to incorporate the epidemiological aspects of the aforementioned and provide a holistic approach to the topic.