Trihalomethanes formation in water treatment plants and distribution lines: a monitoring and modeling scheme

Monitoring and modeling of the concentrations of trihalomethanes (THMs) within four water treatment plants (WTPs) and distribution lines in Fayoum City, Egypt, were studied. Sampling sites for raw and treated waters were determined by global positioning system and the Arc geographic information system software was used for mapping. THMs were monitored using 25 sampling points located at the plant exit and through the distribution lines up to the plant extremity. Results indicated that the THMs concentration varied significantly but it was very rarely higher than the allowed maximum contaminant level of 100 μg L^?1. However, at the dead zones in the distribution lines, the THMs increased by about 160% compared to in-plant level. Furthermore, the level of THMs in hot months was about 1.3 times higher than in cold ones. The influence of some independent variables such as temperature, pH, ammonia concentration, total organic carbon and color were investigated by Pearson model to find their correlation with the rate of THMs formation in WTPs. The resulted R values ranged from 0.81 to 0.98. Successful application of the model to a selected region on the distribution lines has resulted in a correlation coefficient of 0.98.     

Analysis of Total Work Inability in Poland in 2000 and 2001 According to Age,Disease Diagnosis and Occupation

This study was to determine the main health-related reasons, age and occupation of those who took ear retirement due to total work inability. This was done through an analysis of the data from Poland’s Soci Insurance Institution (ZUS) from 2000 and 2001. An analysis of these data showed an increase in the numb of certificates confirming total inability to work in people over 40 years old. Over 50% of certificates wo, were issued to workers in 2 age-groups: 45–49 and 50–54.

Diseases of the circulatory system, musculoskeletal system and connective tissue as well as mental and behavioural disorders are the main causes of early inability to work. Approximately 70% of people who obtained certificates confirming total inability to work had blue- and blue-and-white-collar jobs.     

Occupational Exposure to Natural UV Radiation and Premature Skin Ageing

The skin is the part of the human body most vulnerable to ultraviolet (UV) radiation. The spectrum of the negative effects of UV radiation on the skin ranges from acute erythema to carcinogenesis. Between these extreme conditions, there are other common skin lesions, e.g.,photoageing. The aim of this study was to assess the skin for signs of photoageing in a group of 52 men occupationally exposed to natural UV radiation. There were 2 types of examinations: an examination of skin condition (moisture, elasticity, sebum, porosity, smoothness, discolourations and wrinkles) with a device for diagnosing the skin, and a dermatological examination. The results of both examinations revealed a higher percentage of skin characteristics typical for photoageing in outdoor workers compared to the general population.     

Vulnerability assessment and adaptation to the impacts of sea level rise on the Kingdom of Bahrain

This paper assesses quantitatively the impact of sea level rise (SLR) at the global and regional scale as a result of climate change (CC) on the coastal areas of the Kingdom of Bahrain’s islands (36 Islands). The standard Intergovernmental Panel on Climate Change (IPCC) guidelines was modified as appropriate for the situation of the study area. Geographic Information Systems (GIS) coupled with Remote Sensing (RS) were used as the main techniques of collecting, analyzing, modeling simulating and disseminating information to build SLR scenarios in a geographically referenced context. Also, these tools were used to assess vulnerability and risk of the coastal area of the islands with the expectation that coastal planner and government authorities will profit from integrating these knowledge into a broad based environmental decision making. Three SLR scenarios: low, moderate and high were developed to examine the impacts from SLR on all islands. The low SLR scenario (Optimistic) assumes a 0.5-m rise above current sea level, the moderate scenario (Intermediate) assumes a one meter rise, and the high scenario (Pessimistic) assumes a 1.5 m rise in sea level. Two more SLR scenarios were assumed to perform risk analysis, a 2 and 5 meter rise above current sea level. The simulation of SLR are quite straightforward, emphasizing on the uses of both of the data that are incorporated from the satellite images and the created Digital Elevation Model (DEM) to estimate SLR scenarios that are adapted in the study. These data were used to predict consequences of the possibility of the rise in sea level at different scenarios which may alter the landuse and patterns of human communities. Results indicate that low-lying coastal areas of Bahrain islands are at risk from the effects of any SLR resulting from CC. These islands are vulnerable under different SLR Scenarios. More than 17% of the country total area may be inundated under 1.5 m SLR in 2100. The total area that might be lost under different sea level scenarios will vary from more than 77 km² if SLR reaches 0.5 m, to about 100 km² under 1.0 m SLR and may reach 124 km² under 1.5 m SLR scenario. The total inundated areas due to risk scenarios will reach 133 km², if the SLR rises to 2.0 m, and it is estimated to be more than (22%) of the main island total area. Under the second scenario, if the SLR reaches 5.0 m, the main islands will lose approximately half of its area (47%) equal to 280 km². Hawar islands group will lose about (30%) of its total area under 2.0 m SLR, which is about 15.5 km².A SLR adaptation policy framework (APF) and adaptation policy initiatives (APIs) are suggested for planners to build upon for reducing the likely effects of SLR in the Kingdom of Bahrain. The framework is composed of four steps namely, acquisition of information, planning and design, implementation and monitoring and evaluation. A general policy framework for a national response to SLR is suggested. Additionally, a range of policy adaptation options/initiatives to sustain coastal developments under the likely effects of SLR are recommended.     

Immune responses,DNA damage and ultrastructural alterations of gills in the marine mussel Lithophaga lithophaga exposed to CuO nanoparticles

Environmental Science and Pollution Research - Nanoparticle (NP) pollution is a worldwide problem. Copper oxide nanoparticles (CuO NPs) are one of the most used NPs in a variety of applications,...     

The detoxifying effect of Polygonum equisetiforme extracts against dichlorvos (DDVP)-induced oxidative stress and neurotoxicity in the commercial clam Ruditapes decussatus

Environmental Science and Pollution Research - Effects of Polygonum equisetiforme extracts against dichlorvos were investigated in the commercial clam Ruditapes decussatus. The toxicity of this...     

Performance characteristics of sequential separation and quantification of lead-210 and polonium-210 by ion exchange chromatography and nuclear spectrometric measurements

A selective separation and quantitative determination procedure for 210Pb and 210Po in various environmental matrices from different sources such as IAEA-326 soil, phosphate rocks (PR), and phosphogypsum (PG) was developed. The tested samples were digested sequentially using concentrated mineral acids (HF, HNO3) by a programmable high-pressure microwave digestion system. The sample solution was loaded onto a preconditioned ion exchange column (Sr-resin) for chromatographic separation. Polonium-210 was eluted by 6 M HNO3 then spontaneously deposited onto polished silver discs to be measured using low-background alpha spectrometry. Lead-210 was sequentially eluted using 6 M HCl solution, precipitated as lead oxalate, dissolved in HNO3 solution, and mixed with scintillation cocktail to be measured by liquid scintillation counting (LSC). Performance of the developed procedure was tested using a reference soil (IAEA-326), with recommended isotope values, that was used as a quality control to assess separation and quantification efficiency (recovery %). The minimum detectable activities of 210Pb and 210Po were found to be 24 and 0.28 Bq kg(-1) for the measurements using LSC and alpha spectrometry, respectively. The recoveries (%) of 210Pb and 210Po were found to be 80 and 60%, respectively. To test the validity of the proposed LSC method, a comparative study was performed by measuring 210Pb activity concentration in test samples by nondestructive gamma-ray spectrometry.     

A Comparative Study of Doum fiber and Shrimp Chitin Based Reinforced Low Density Polyethylene Biocomposites

The aim of this paper was to study the effects of reinforcing low density polyethylene (LDPE) by using bio-fillers (Doum cellulose or Shrimp chitin) on the mechanical properties. Both, Doum cellulose extracted frsom Doum leaves and Shrimp chitin extracted from shrimp co-products were compounded with LPDE without and with compatibilizer. The biocomposites were prepared by melt blending in a twin-screw extruder. Torsion and flexural tests were performed to investigate the impact of each reinforcement on the biocomposite mechanical properties. The SEM was carried out to study the filler/polymer interface adhesion. The present study has demonstrated that Doum fibers and shrimp chitin succeed in improving the mechanical properties of LPDE bio-composites. The results also showed that the use of maleic anhydride-grafted polyethylene as a compatibilizer improves filler adhesion/matrix and mechanical properties. This study exhibits that polyethylene composites based on Doum fibers or shrimp chitin can be used to replace the polyethylene materials in several fields like packaging and automotive industries.     

Characterization of phosphate rock and phosphogypsum from Gabes phosphate fertilizer factories (SE Tunisia): high mining potential and implications for environmental protection

Environmental Science and Pollution Research - Since the establishment of the coastal industrial complex in Gabes city (Gulf of Gabes, SE Tunisia), hundred million tons of untreated phosphogypsum...     

Polynomial Surrogates for Open-Channel Flows in Random Steady State

Assessing epistemic uncertainties is considered as a milestone for improving numerical predictions of a dynamical system. In hydrodynamics, uncertainties in input parameters translate into uncertainties in simulated water levels through the shallow water equations. We investigate the ability of generalized polynomial chaos (gPC) surrogate to evaluate the probabilistic features of water level simulated by a 1-D hydraulic model (MASCARET) with the same accuracy as a classical Monte Carlo method but at a reduced computational cost. This study highlights that the water level probability density function and covariance matrix are better estimated with the polynomial surrogate model than with a Monte Carlo approach on the forward model given a limited budget of MASCARET evaluations. The gPC-surrogate performance is first assessed on an idealized channel with uniform geometry and then applied on the more realistic case of the Garonne River (France) for which a global sensitivity analysis using sparse least-angle regression was performed to reduce the size of the stochastic problem. For both cases, Galerkin projection approximation coupled to Gaussian quadrature that involves a limited number of forward model evaluations is compared with least-square regression for computing the coefficients when the surrogate is parameterized with respect to the local friction coefficient and the upstream discharge. The results showed that a gPC-surrogate with total polynomial degree equal to 6 requiring 49 forward model evaluations is sufficient to represent the water level distribution (in the sense of the \(\ell _2\) norm), the probability density function and the water level covariance matrix for further use in the framework of data assimilation. In locations where the flow dynamics is more complex due to bathymetry, a higher polynomial degree is needed to retrieve the water level distribution. The use of a surrogate is thus a promising strategy for uncertainty quantification studies in open-channel flows and should be extended to unsteady flows. It also paves the way toward cost-effective ensemble-based data assimilation for flood forecasting and water resource management.