Distribution and Statistical Analysis of Leachable and Total Heavy Metals in the Sediments of the Suez Gulf

The concentrations of nine heavy metals (Cd, Co, Cr, Cu, Fe, Mn, Ni, Pd and Zn) in the labile and total fractions of muddy and sandy sediment samples collected from twelve sites in Suez Gulf during April 1999 were studied to evaluate the pollution status of the Suez Gulf. The enrichment factors (EF) for each element were calculated. There are extremely high concentrations of Cd, Ni, Pb and slightly concentration of Cr and Cu in both muddy and sandy sediments. The concentration of Zn was moderately high and can be considered as seriously contaminate Metal pollution index (MPI) shows high values ranged between 46 to 156 and 40 to 232 for both sandy and muddy sediments, respectively. Concentrations of heavy metals were normalized against iron for total fraction in both of sandy and muddy sediments. Principal component analysis (PCA) was studied on the data matrix obtained and represented three-factor model explaining 92.22% for labile and 88.82% for total fractions of muddy sediment. The main source of contamination is the offshore oil fields and industrial wastes. This is largely a result of ineffective and inefficient operation equipment, illegal discharge of dirty ballast water from tankers and lack of supervision and prosecution of offenders.     

Economic feasibility of solar-powered reverse osmosis water desalination: a comparative systemic review

Environmental Science and Pollution Research - Due to disparities in the allocation of rainwater and drought, extreme exploitation of groundwater reservoirs has depleted water supplies in many...     

Maximum ground level concentration for Gaussian plume formula using standard and Briggs methods

This work aims to determine the maximum concentration and downwind distance at the earth's surface in two methods Briggs and standard for two conditions are slightly unstable and neutral by using the Gaussian equation at different effective heights and wind seeped at (8.9, 8.5 and 8 m/s) under lateral and vertical dispersion coefficient measurement.     

Green sol–gel synthesis of novel nanoporous copper aluminosilicate for the eradication of pathogenic microbes in drinking water and wastewater treatment

Environmental Science and Pollution Research - We used a green sol–gel synthesis method to fabricate a novel nanoporous copper aluminosilicate (CAS) material. Nanoporous CAS was characterized...     

Radiometric and environmental impacts of mill tailings at experimental plant processing unit,Allouga, Egypt

Abstract

Uranium mining and ore processing are known to be harmful to the environment and human health if the waste generated is not managed properly. The aim of the present study is to determine the radiological indices in the mill tailings and review the possible attempts to utilize and minimize its hazardous effect. The activity concentrations of natural radionuclides, ²³⁸U, ²³²Th, ²²⁶Ra, and ⁴⁰K have been measured by gamma spectrometry using HP-Ge detector. The average activity concentrations of ²³⁸U, ²³²Th, ²²⁶Ra, and ⁴⁰K in the tailings wastes were 2071.8, 59.92, 6921.262, and 445. 57?Bq/kg respectively which are higher than the international average limit. The ranges of hazard indices such as Radium equivalent activity (Ra_eq), external hazard index (H_ex), internal hazard index (H_in), γ-radiation hazard index I_γ, Dose rate (nGy/h) and annual effective dose equivalent (AED), were estimated. Uraniumm isotopic ratios in the ore –material and mill tailing samples indicate migration out of radionuclides to the surrounding environment causing contamination and many dangerous diseases. Fairly, all investigated tailing waste samples do not satisfy the universal standards, the studied wastes relatively still have high uranium contents and need reprocessing.     

Investigation of novel material for effective photodegradation of bezafibrate in aqueous samples

A novel composite with an enhanced photocatalytic activity was prepared and applied to study the removal of bezafibrate (BZF), a hypolypemic pharmaceutical, from an aqueous environment. For the enhancement of titanium dioxide photoactivity a fullerene derivative, 2-(ferrocenyl) fulleropyrrolidine (FcC₆₀), was synthesized and applied. Obtained composite was found to show a higher catalytic activity than pristine TiO₂. Therefore, high hopes are set in composites that are based on carbonaceous nanomaterials and TiO₂ as a new efficient photocatalysts.     

Brown rust disease control in winter wheat: I. Exploring an approach for disease progression based on night weather conditions

An empirical approach for simulating the infection and progress of leaf rust (caused by Puccinia triticina) during stem elongation on winter wheat was analysed for the 2000 to 2006 growing seasons. The approach was elaborated based on night weather conditions (i.e., air temperature, relative humidity and rainfall) and leaf rust occurrences. Data from three consecutive cropping seasons (2000–2002) at four representative sites of the Grand-Duchy of Luxembourg were used in the set-up phase. The capability to correctly simulate the occurrence expression of P. triticina infections on the upper leaf layers was then assessed over the 2003–2006 period. Our study revealed that the development of leaf rust required a period of at least 12 consecutive hours with air temperatures ranging between 8 and 16 °C, a relative humidity greater than 60 % (optimal values being 12–16 °C and up to 80 % for air temperatures and relative humidity, respectively) and rainfall less than 1 mm. Moreover, leaf rust occurrences and infections were satisfactorily simulated. The false alarm ratio was ranged from 0.06 to 0.20 in all the study sites. The probability of detection and critical success index for WLR infection were also close to 1 (perfect score).     

Cobalt separation from waste mobile phone batteries using selective precipitation and chelating resin

Separation of cobalt from mixed-waste mobile phone batteries containing LiCoO₂ cathodic active material was investigated using selective precipitation and chelating resin. Cobalt was recovered from the active powder materials containing 47 % Co oxide together with Mn, Cu, Li, Al, Fe, and Ni oxides. The metal ions were leached sufficiently using 4 M HCl. The metal ions detected spectrophotometrically were removed from the leaching solution by selective precipitation at pH 5.5, with cobalt loss of 27.5 %. Conditions for achieving a recovery of Co in the filtrate by chelating resin were determined experimentally by varying the pH and time of the reaction, as well as the initial resin-to-liquid ratio. The cobalt was efficiently determined by absorption spectrometry at λ _max 510 nm. Chelating polyamidoxime resin was synthesized by polymerization of acrylonitrile and followed by amidoximation reaction. Physically cross-linked gel of polyacrylonitrile was made by a cooling technique.     

Effect of dimethoate on the immune system of female mice

Abstract

The functional status of the immune system of female mice exposed to a single oral dose of dimethoate (16 mg / kg) was evaluated by assessing cell mediated and humoral immune responses, in addition to the effect of dimethoate on spleen and body weights after different time intervals. The data showed that dimethoate caused a time ‐ depended decrease in spleen weights in the absence of a change in body weights. The immunologic effect of dimethoate to female mice produced a dose‐dependent decrease in the number of the rosette forming cells (total and active erythrocyte rosette). The ability of splenocytes to proliferation in response to mitogens; phytohemagglutinin (PHA) for T cell and lipopolysaccharide (LPS) for B cell were significantly decreased at the different times. As compared to control, a significant decrease in serum total immunoglobulins (Ig) and IgM was found, while IgG was non‐significant deceased. Results of this study also revealed that dimethoate caused a significant decrease in the number of plaque forming cell (PFC / 10⁶ splenocytes) in a time dependent manner.