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81.
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83.
Elisa Chiarati Daniela Canestrari Marta Vila Ruben Vera Vittorio Baglione 《Behavioral ecology and sociobiology》2011,65(9):1791-1800
Offspring delayed dispersal is the principal mechanism leading to formation of kin-based societies. It has been suggested
that parents promote offspring philopatry by providing them with preferential access to the food resources of the territory
and that parental tolerance may be affected by territory quality. However, few studies have addressed this hypothesis in kin-living
vertebrate species. Here, we show that in cooperative breeding groups of carrion crows (Corvus corone corone) containing retained offspring and immigrants, dominant breeding males behaved nepotistically on an experimental source of
food by (1) attacking immigrants with more frequency and intensity than offspring and (2) associating preferentially with
their offspring on the feeding spot and sharing food with them. This parental facilitation allowed the offspring to spend
more time feeding than higher-rank immigrants. We also found that a year-round experimental food supplementation neither increased
breeding males’ tolerance nor relented the overall aggressiveness in the groups. This indicates that higher natal philopatry
observed on fed territories compared to unfed ones is not a consequence of a more benign social environment. Rather, it suggests
that offspring value territory resource wealth and adjust the timing of dispersal accordingly. 相似文献
84.
Giovanna Armiento Fabio Bellatreccia Carlo Cremisini Giancarlo Della Ventura Elisa Nardi Renata Pacifico 《Environmental monitoring and assessment》2013,185(1):559-572
Beryllium is widely distributed in soils at low levels, but it can also occur naturally in higher concentrations in a variety of materials exploited for many industrial applications. Beryllium is also one of the most toxic natural elements and is known to be a human carcinogen. A concise account of the literature data on baseline concentrations of Be in soils illustrates the possibility of worldwide presence of areas with a high natural background concentration of Be (up to 300 mg/kg), the crustal abundance of which is generally estimated to be in the range 2–6 mg/kg. Nevertheless, the number of available data is rather limited in comparison with those about other toxic elements such as Pb, Cd and Cr. This has probably caused the choice of low values of concentration level as the reference for the definition of soil contamination: these values are not always realistic and are not applicable to large areas. As a case study, we report and analyse a diffuse, unusually high (up to 80 mg/kg, average approximately 20 mg/kg), natural occurrence of beryllium in loose and poorly consolidated pyroclastic layers related to the Pleistocene activity of the Vico volcano. Additionally, the analysis of Be leachability has been carried out, providing evidence of a not negligible mobility in contrast with the scarce data presented in the literature that usually indicate beryllium as an element with low mobility in oxidising surface environmental conditions. This research marks the beginning of a possible reappraisal of beryllium geochemical behaviour and background levels, providing more realistic reference values for risk assessment and land management. 相似文献
85.
86.
Analysis of Mosses and Soils for Quantifying Heavy Metal Concentrations in Sicily: A Multivariate and Spatial Analytical Approach 总被引:1,自引:0,他引:1
Gramatica P Battaini F Giani E Papa E Jones RJ Preatoni D Cenci RM 《Environmental science and pollution research international》2006,13(1):28-36
- DOI: http://dx.doi.org/10.1065/espr2006.01.006
Background The use of vegetal organisms as indicators of contamination of the environment is partially replacing traditional monitoring
techniques. Amongst the vegetal organisms available, mosses appear to be good bioindicators and are used for monitoring anthropogenic
and natural fall-out on soils. This study has two objectives: the evaluation of the concentrations of heavy metals in soils
and mosses of the Sicily Region, in Italy and the identification of the origin of fall-out of heavy metals.
Methods Mosses and the surface soil were sampled at 28 sites, only the youngest segments of Hylocomium splendens and Hypnum cupressiforme,
corresponding to the plant tissues produced during the last 3 years, were taken. The elements Cd, Cu, Ni, Pb and Zn were analysed
by ICP-MS and Hg by AAS. Statistical analysis was by PCA and spatial representation by GIS.
Results and Discussion In the mosses sampled in Sicily, the highest concentrations of Cd were found around the cities of Palermo and Messina. The
highest concentrations of Hg were recorded in the northern part of the island between Trapani and Messina, similar to the
distribution of Cu. Different areas with the highest concentrations of Ni were found near the south coast, in the vicinity
of Palermo and around the Volcano Etna. The highest concentrations of Pb were found in the south-west coast near Agrigento,
where important chemical plants and petroleum refineries are located. Except for a few locations, Zn fall-out was found to
be evenly distributed throughout Sicily.
Conclusion The sites where the concentrations of heavy metals cause greatest concern have been revealed by the PCA analysis and portrayed
using GIS. Also of some concern is the diffuse and anthropogenic origin of Hg and Cd. The combined approach of using soil
and mosses, together with pedological interpretation and application of multivariate statistical techniques has provided valuable
insight into the environmental aspects of heavy metal deposition in a region of southern Europe.
Recommendations and Outlook Further insight into the deposition of heavy metals will require more detailed sampling of soils and mosses in both new and
previous study areas. This needs to be complemented by detailed pedological investigations in the study areas. Future research
programmes will address these issues. 相似文献
87.
Fabio Gosetti Bianca Bolfi Ugo Chiuminatto Marcello Manfredi Elisa Robotti Emilio Marengo 《Environmental Chemistry Letters》2018,16(2):581-590
Alpha-cypermethrin is a broad-spectrum insecticide widely used in the treatment of rice crops, mainly commercialized as a CONTEST® formulation. The photodegradation of alpha-cypermethrin and of the commercial formulation has not yet been systematically investigated in paddy water under natural conditions. Here, paddy water solutions of alpha-cypermethrin and CONTEST® formulation at 5.0 mg L?1 were irradiated under simulated sunlight for 10 days. Hydrolysis experiments were carried out on the same solutions preserved in the dark. Analysis by ultra-high-performance liquid chromatography–tandem mass spectrometry was developed for the identification of photodegradation products. Results show that degradation of pure alpha-cypermethrin and the formulation counterpart produces both common and different photodegradation products. Five out eleven photodegradation products were identified for the first time, in particular three in the alpha-cypermethrin paddy water solution and four in the formulation. Our findings underline the importance of carrying out photodegradation experiments directly on the commercial formulation, since degradation products could be different from the pure insecticide. 相似文献
88.
The metabolism of biphenyl, naphthalene, anthracene, phenanthrene, pyrene and benzo[a]pyrene by Cyclothyrium sp. CBS 109850, a coelomycete isolated for the first time in Brazil from industrially polluted estuarine sediment, was studied. The metabolites were extracted and separated by high performance liquid chromatography (HPLC) and characterized by UV spectral analyses and mass, and proton nuclear magnetic resonance ((1)H NMR) spectrometry. Cyclothyrium sp. transformed biphenyl to 4-hydroxybiphenyl and anthracene to anthracene trans-1,2-dihydrodiol. This isolate metabolized 90% of [9-(14)C]phenanthrene, producing phenanthrene trans-9,10-dihydrodiol as a major metabolite, phenanthrene trans-3,4-dihydrodiol, 1-hydroxyphenanthrene, 3-hydroxyphenanthrene, 4-hydroxyphenanthrene, and a novel metabolite, 2-hydroxy-7-methoxyphenanthrene. Circular dichroism spectra analyses indicated that the major enantiomers of phenanthrene trans-9, 10-dihydrodiol, phenanthrene trans-3,4-dihydrodiol and pyrene trans-4,5-dihydrodiol, a pyrene metabolite produced previously by Cyclothyrium sp. CBS 109850, were predominantly in the (R,R) configuration, revealing a high stereoselectivity for initial monooxygenation and enzymatic hydration of phenanthrene and pyrene by Cyclothyrium sp. CBS109850. The results also show a high regioselectivity since the K-regions of phenanthrene and pyrene were the major sites of metabolism. 相似文献
89.
Pilar D. S. C. Mariani Antonio P. Vinagre Neto José P. da Silva Jr. Elke J. B. N. Cardoso Elisa Esposito Lucia H. Innocentini-Mei 《Journal of Polymers and the Environment》2007,15(1):19-24
The biodegradability properties of poly(ɛ-caprolactone) (PCL) and modified adipate-starch (AS) blends, using Edenol-3203 (E)
as a starch plasticizer, were investigated in laboratory by burial tests of the samples in previously analyzed agricultural
soil. The biodegradation process was carried out using the respirometric test according to ASTM D 5988-96, and the mineralization
was followed by both variables such as carbon dioxide evolution and mass loss. The results indicated that the presence of
AS-E accelerated the biodegradation rate as expected. 相似文献
90.
14C]Pentachlorophenol mineralization in the rice rhizosphere with established oxidized and reduced soil layers 总被引:2,自引:0,他引:2
Flooded soils with rooted aquatic macrophytes have adjacent aerobic and anaerobic zones at the soil-water interface and rhizosphere where many common soil constituents undergo sequential oxidation and reduction reactions. To investigate whether pentachlorophenol (PCP) mineralization would also be enhanced under these conditions, a laboratory study was conducted to determine the conversion of [14C]PCP to 14CO2, 14CH4 and [14C]humic substances in soil microcosms with established aerobic-anaerobic zones at the soil-water interface and rice (Oryza sativa) rhizosphere. Contrary to what was expected, PCP was least rapidly degraded in rhizosphere-soil microcosms that contained the most extensive amounts of aerobic-anaerobic interfaces (63% PCP loss in 82 d) and was most rapidly degraded in soil microcosms that lacked redox interfaces in the soil profile (94% PCP loss in 82 d). Decreased PCP mineralization in the presence of aerobic-anaerobic interfaces was explained by (i) lack of sufficient O2 for aerobic PCP mineralization, due to the oxidation of other soil constituents in aerobic zones, and (ii) lack of an adequate supply of electron equivalents for reductive dechlorination of PCP, due to the reduction of other alternate electron acceptors in anaerobic zones. It was concluded that PCP mineralization is inhibited in flooded soils that contain extensive amounts of aerobic-anaerobic interfaces, due to redox cycling of other soil constituents that occur in these zones. 相似文献