全文获取类型
收费全文 | 1581篇 |
免费 | 5篇 |
国内免费 | 6篇 |
专业分类
安全科学 | 10篇 |
废物处理 | 71篇 |
环保管理 | 80篇 |
综合类 | 523篇 |
基础理论 | 363篇 |
污染及防治 | 370篇 |
评价与监测 | 97篇 |
社会与环境 | 68篇 |
灾害及防治 | 10篇 |
出版年
2017年 | 14篇 |
2016年 | 20篇 |
2014年 | 21篇 |
2013年 | 69篇 |
2012年 | 24篇 |
2011年 | 47篇 |
2010年 | 44篇 |
2009年 | 48篇 |
2008年 | 66篇 |
2007年 | 51篇 |
2006年 | 46篇 |
2005年 | 45篇 |
2004年 | 41篇 |
2003年 | 39篇 |
2002年 | 48篇 |
2001年 | 59篇 |
2000年 | 54篇 |
1999年 | 34篇 |
1998年 | 20篇 |
1997年 | 30篇 |
1996年 | 28篇 |
1995年 | 30篇 |
1994年 | 28篇 |
1993年 | 26篇 |
1992年 | 19篇 |
1991年 | 36篇 |
1990年 | 50篇 |
1989年 | 23篇 |
1988年 | 27篇 |
1987年 | 20篇 |
1985年 | 21篇 |
1984年 | 21篇 |
1983年 | 16篇 |
1982年 | 30篇 |
1979年 | 18篇 |
1978年 | 13篇 |
1977年 | 15篇 |
1976年 | 13篇 |
1974年 | 17篇 |
1972年 | 17篇 |
1971年 | 13篇 |
1969年 | 11篇 |
1968年 | 12篇 |
1967年 | 23篇 |
1966年 | 19篇 |
1965年 | 13篇 |
1964年 | 12篇 |
1962年 | 13篇 |
1958年 | 14篇 |
1957年 | 12篇 |
排序方式: 共有1592条查询结果,搜索用时 15 毫秒
161.
Kollist-Siigur K Nielsen T Grøn C Hansen PE Helweg C Jonassen KE Jørgensen O Kirso U 《Journal of environmental quality》2001,30(2):526-537
Two different humic acids (HA) and a fulvic acid (FA) were chemically immobilized to a high performance liquid chromatography (HPLC) silica column material. The immobilization was performed by binding amino groups in HA/FA to the free aldehyde group in glutardialdehyde attached to the silica gel. The HPLC column materials were compared with a blank column material made by applying the same procedure but without immobilizing HA or FA. Also, a column was made by binding carbonyl groups in HA to amino groups attached to the silica gel. The humic substances were selected to secure appropriate variation of their structural features. The retention factors of 45 polycyclic aromatic compounds (PAC) to the four columns were determined by HPLC. The advantage of the technique is a large number of compounds can easily be studied. The binding procedure does not appear to cause a drastic selection between the HA molecules. The k' values obtained for the two Aldrich HA columns agree in general reasonably. The retention or sorption of the compounds increased with the size of the PAC and the number of lipophilic substituents, but decreased when polar substituents were present. The PAC retention was much stronger to the two HA columns than to the FA and blank column, both for hydrophobic polycyclic aromatic hydrocarbons (PAH) and the polar PAC. Other factors impacting the PAC binding may be specific interactions with HA and the ionic strength of the aqueous phase. The technique has been applied to do direct determinations of Koc. 相似文献
162.
The prospect of using wastewater containing high loads of soluble organic matter (OM) for removing residual agricultural chemicals (fertilizer, pesticide, or herbicide) in farm soil, although promising, could have adverse effects on soil agricultural quality as a result of development of redoximorphic features in the soil profile. In this study, the effect of organic carbon supplement for bioremediation of residual fertilizer nitrate on soil properties, redox potential (Eh), pH, and metal ion mobilization was studied using sandy soils packed in columns. The study was included in a general project, described elsewhere (Ugwuegbu et al., 2000), undertaken to evaluate use of controlled water table management (WTM) systems to supply organic carbon for creating a reduced environment conducive to denitrification of residual fertilizer nitrate leaching from the farm to subsurface water. The columns were subjected to subirrigation with water containing soluble organic carbon in the form of glucose. The work was carried out in two experimental setups and the long-term effect of a range of glucose concentrations on the Eh, pH, and soluble levels of Fe and Mn was investigated. From the results obtained, it could be concluded that excessive organic carbon supplement to soil can have adverse effects on soil quality and that Eh and soluble Fe are the two most practical parameters for monitoring soil health during treatment of farm chemicals. 相似文献
163.
Bossew P Ditto M Falkner T Henrich E Kienzl K Rappelsberger U 《Journal of environmental radioactivity》2001,55(2):187-194
Austria ranks among the countries that have been most strongly affected by the Chernobyl fallout. The mean contamination with 137Cs is 21.0 kBq/m2, of which 18.7 kBq/m2 is due to the Chernobyl accident, whereas global fallout contributes 2.3 kBq/m2. Maximum values of total 137Cs contamination are nearly 200 kBq/m2. Total deposition of Chernobyl 137Cs on Austrian territory is 1.6 PBq or a fraction of around 2% of the 137Cs released from the reactor. 2115 measurements were used to draw the Austrian "caesium map". The geographical pattern of fallout distribution shows regional differences of contamination as high as 1:100. 相似文献
164.
The optimized BCR sequential extraction procedure (proposed by the Standards, Measurements and Testing Programme (SM&T) of
the European Union) was applied to seven topsoil samples from refuse dump sites for the determination of Cu, Zn, Ni, Pb and
Cd. The metals were partitioned into four operationally defined chemical fractions: acid extractable, reducible, oxidizable
and residual, and analysed using flame atomic absorption spectrophotometry, FAAS.
The results were compared with total metal concentrations obtained using HNO3, HClO4 and HF digestion procedures. Results for total metal analysis ranged from - 15.55 to 43.45 for Cu, 37.15 to 222.35 for Zn,
5.15 to 12.10 for Ni, 10.30 to 93.05 for Pb and 0.35 to 3.75 for Cd in μgg−1 dry weight. The results of the partitioning study showed that zinc prevailed in the more soluble fractions and was distributed
between the acid-extractable (32.4%) and the reducible (40.3%) fractions, whereas Pb was distributed mainly in the reducible
fraction. Copper and nickel were predominantly associated with the reducible and residual fractions - 53.4, 33.3 and 51.1,
24.1% respectively. The ranking of the four fractions for the partitioning of cadmium was: reducible > residual > oxidizable
> acid extractable. The percentage recovery for all metals when comparing total metal concentration with the fractional sum
of the optimized BCR procedure, were of the order: Zn(93%) > Pb(83%) > Cu(78) > Cd > (68%) > Ni(63%). 相似文献
165.
Nancy U. Schultz Albert Wilmarth 《Journal of the American Water Resources Association》1978,14(2):275-287
ABSTRACT: Section 208 of the Federal Water Pollution Control Act Amendments of 1972 has provided the Southwestern Illinois Metropolitan and Regional Planning Commission (SIMAPC) with a unique opportunity for comprehensive planning of the region's water quality. SIMAPC initiated the 208 study by researching available technology for the analysis of point and nonpoint sources of pollution and establishing criteria by which to judge the various technniques. This led to SIMAPC'S choice of continuous simulation of stream and reservoir water quality as the most appropriate analytical tool for their needs. A continuous simulation model was calibrated and verified on three basins in the SIMPAC region. It was then used to produce load source analysis, pollution event frequency analysis, and pollution event duration analysis for ten pollutants under existing stream conditions and then under alternative future conditions. These results enabled the weighting of pollutant sources, analysis of the effectiveness of control measures, and quantitative analysis of the marginal benefit of each alternative. 相似文献
166.
CADMIUM ACCUMULATION AND TOXICITY IN SUBMERGED PLANT HYDRILLA VERTICILLATA (l.f.) ROYLE 总被引:2,自引:0,他引:2
P. Garg R. D. Tripathi U. N. Rai S. Sinha P. Chandra 《Environmental monitoring and assessment》1997,47(2):167-173
Cadmium accumulation and its toxicity in relation tochlorophyll, protein, cysteine contents and in vivo nitrate reductaseactivity were studied under controlled conditions in Hydrillaverticillata, a submerged commonly occurring macrophyte. Plants weresubjected to six different concentrations of Cd ranging from 1.0 to 25.0 µM for 24, 48, 72 and 168 h. Tissue Cd concentration was maximum (13.71 µmoles/g dw) at 25 µM background concentration. At this concentration, a decrease of approximately 79 and 72% was found in chlorophyll and protein content. In vivo nitrate reductase activity was stimulated at 1.0 µM; however, the activity gradually declined beyond this concentration. Exposure to various cadmium concentrations resulted in an increase in cysteine content of the plant. 相似文献
167.
R. Wassmann H. U. Neue M. C. R. Alberto R. S. Lantin C. Bueno D. Llenaresas J. R. M. Arah H. Papen W. Seiler H. Rennenberg 《Environmental monitoring and assessment》1996,42(1-2):163-173
Measurements of methane emission rates and concentrations in the soil were made during four growing seasons at the International Rice Research Institute in the Philippines, on plots receiving different levels of organic input. Fluxes were measured using the automated closed chambers system (total emission) and small chambers installed between plants (water surface flux). Concentrations of methane in the soil were measured by collecting soil cores including the gas phase (soil-entrapped methane) and by sampling soil solution in situ (dissolved methane). There was much variability between seasons, but total fluxes from plots receiving high organic inputs (16–24 g CH4 m–2) always exceeded those from the low input plots (3–9 g CH4 m–2). The fraction of the total emission emerging from the surface water (presumably dominated by ebullition) was greater during the first part of the season, and greater from the high organic input plots (35–62%) than from the low input plots (15–23%). Concentrations of dissolved and entrapped methane in the low organic input plots increased gradually throughout the season; in the high input plots there was an early-season peak which was also seen in emissions. On both treatments, periods of high methane concentrations in the soil coincided with high rates of water surface flux whereas low concentrations of methane were generally associated with low flux rates. 相似文献
168.
169.
Jesper Bosse Jønsson Peter W.U. Appel Raphael Tihelwa Chibunda 《Journal of Cleaner Production》2009,17(1):77-86
The mercury-based gold extraction processes prevalent within small-scale mining are both efficient and harmful. While ensuring relatively high levels of gold recovery, they cause environmental and health problems for people living within mining settlements. This mercury consumption can be minimized by using a simple mercury recycling device known as a retort. While mining legislation in Tanzania dictates the use of retorts for gold recovery, virtually no miners use them, indicating the inadequacy of previous introduction attempts. During action research, retorts were introduced in two mining settlements through a thorough and participatory approach. Twenty miners were given retorts and their attitudes and receptiveness to them were studied. Of the recipients, 18 used the retorts over a period of five months, recycling 10 kilos of mercury. Less mercury was spilled into the environment and miners saved money normally spent on purchasing mercury. The findings have implications for the strategies of development interventions targeting mercury-instigated problems within small-scale gold mining. 相似文献
170.
V. A. Romanenkov J. U. Smith P. Smith O. D. Sirotenko D. I. Rukhovitch I. A. Romanenko 《Regional Environmental Change》2007,7(2):93-104
The Model of Humus Balance was used to estimate the influence of climate effects and changing agricultural practices on carbon
(C) levels in soddy–podzolic soils in the Russian Federation for the years 2000–2050. The model was linked with a spatial
database containing soil, climate and farming management layers for identification of spatial change of C sequestration potential.
Analysis of relationships between C, soil texture and climate indicated that compared with a business-as-usual scenario, adaptation
measures could increase the number of polygons storing soil organic carbon (SOC) by 2010–2020. The rate of possible C loss
is sensitive to the different climate scenarios, with a maximum potential for SOC accumulation expected in 2030–2040, thereafter
decreasing to 2050. The effect is most pronounced for the arid part of the study area under the emission scenario with the
highest rate of increase in atmospheric CO2 concentration, supporting findings from the dynamic SOC model, RothC. C sequestration during the study period was permanent
for clay and clay loam soils with a C content of more than 2%, suggesting that C sequestration should be focused on highly
fertile, fine-textured soils. We also show that spatial heterogeneity of soil texture can be a source of uncertainty for estimates
of SOC dynamics at the regional scale.
Figures in color are available at 相似文献