CaCu3Ti4O12, an efficient catalyst for ibuprofen removal by activation of peroxymonosulfate under visible-light irradiation

Environmental Chemistry Letters - Contamination of waters by pharmaceuticals is a major health issue. Therefore, there is a need for efficient techniques to remove pharmaceutical pollutants. Here,...     

Synthesis of a three-dimensional network sodium alginate–poly(acrylic acid)/attapulgite hydrogel with good mechanic property and reusability for efficient adsorption of Cu2+ and Pb2+

Environmental Chemistry Letters - Water pollution caused by heavy metals has dramatically impacted ecosystems in recent years. For instance, 45.4% of lakes in China are in the category of moderate...     

A fiber-optic redox sensor for the iron(III)–iron(II) transition

A phenosafranine-containing Nafion film attached to the distal end of a fiber-optic probe forms a functional redox-sensitive optical sensor. The synthetic cationic photoactive dye phenosafranine, 3,7-diamino-5-phenylphenazinium chloride, responds with changes in light absorbance between its oxidized and reduced forms. This optical property persists when phenosafranine is sorbed into Nafion, a perfluorosulfonate anionic film. Optical properties of the sensor are similar to those seen by others in solution. At high redox conditions, such as an open nitrogen-purged aqueous pH 6.5 solution, optical absorbance of phenosafranine is high, while at low redox conditions, such as an aqueous pH 6.5 iron(II) solution, optical absorbance of phenosafranine is low. Titration of a closed pH 6.5 aqueous solution with a standard iron(II) solution lowers redox potential in a predictable manner and can be followed by the optical redox sensor in parallel with a commercial redox potential electrode.     

The viticultural system and climate change: coping with long-term trends in temperature and rainfall in Roussillon,France

Mediterranean viticulture could suffer from hotter and drier growing seasons over the coming decades. The present article focuses on the wine-producing area Côtes-du-Roussillon-Villages near Perpignan, in southern France. We used observational daily data (1925–2010) from Perpignan weather station and daily outputs (2001–2060) of the regional climate model ARPEGE-RETIC-V4 from Météo-France with scenarios A2, A1B and B1, to assess the exposure of the regional wine system to changes in temperature and precipitation, both in the recent past and the coming decades (1925–2060). Temperatures during the growing season and summer temperature extremes have been increasing continuously since the mid-1980s and are projected to increase faster from the mid-2040s. Precipitation is highly variable and very low in summer, and projections suggest greater uncertainty, and more extreme drought events could be expected. The analysis of climate data was complemented by thirty-two in-depth interviews with local actors of the wine industry to assess the impacts of climate change on their activities and potential adaptive options. Producers reported negative impacts of recent changes in climate in conjunction with a difficult economic situation. Analyses of historical, social and economic backgrounds are important to fully conceptualize the nature and extent of climate change risks in the region. This case study provides important insights into the roles of non-climatic factors in the generation of vulnerability for Mediterranean agricultural systems facing rapid climate change.     

Conventional and non-conventional adsorbents for wastewater treatment

Environmental Chemistry Letters - The removal of contaminants from wastewaters is a major challenge in the field of water pollution. Among numerous techniques available for contaminant removal,...     

Prediction of CO2 absorption by physical solvents using a chemoinformatics-based machine learning model

Environmental Chemistry Letters - The rising atmospheric CO2 level is partly responsible for global warming. Despite numerous warnings from scientists during the past years, nations are reacting...     

Development of a rotorcraft dust-emission parameterization using a CFD model

Flights of rotorcraft over the desert floor can result in significant entrainment of particulate matter into the atmospheric boundary layer. Continuous or widespread operation can lead to local and regional impacts on visibility and air quality. To account for this pollutant source in air quality models, a parameterization scheme is needed that addresses the complex vertical distribution of dust ejected from the rotorcraft wake into the atmospheric surface layer. A method to parameterize the wind and turbulence fields and shear stress at the ground is proposed here utilizing computational fluid dynamics and a parameterized rotor model. Measurements taken from a full scale experiment of rotorcraft flight near the surface are compared to the simulation results in a qualitative manner. The simulation is shown to adequately predict the forward detachment length of the induced ground jet compared to the measured detachment lengths. However, the simulated ground vortex widths and vorticity deviate substantially from the measured values under a range of flight speeds. Results show that the method may be applicable for air quality modeling assuming slow airspeeds of the rotorcraft, with advance ratios of 0.005–0.02.