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排序方式: 共有993条查询结果,搜索用时 546 毫秒
161.
A conceptual model and numerical simulations of bacterial U(VI) reduction in fractured subsurface sediments were developed to assess the potential feasibility of biomineralization at the fracture/matrix interface as a mechanism for immobilization of uranium in structured subsurface media. The model envisions flow of anaerobic groundwater, with or without acetate as an electron donor for stimulation of U(VI) reduction by dissimilatory metal-reducing bacteria (DMRB), within mobile macropores along a one-dimensional flow path. As the groundwater moves along the flow path, U(VI) trapped in the immobile mesopore and micropore domains (the sediment matrix) becomes desorbed and transferred to the mobile macropores (fractures) via a first-order exchange mechanism. By allowing bacterial U(VI) reduction to occur in the mesopore domain (assumed to account for 12% of total sediment pore volume) according to experimentally-determined kinetic parameters and an assumed DMRB abundance of 10(7) cells per cm3 bulk sediment (equivalent to 4 mg of cells per dm3 bulk sediment), the concentration of U(VI) in the macropore domain was reduced ca. 10-fold compared to that predicted in the absence of mesopore DMRB activity after a 6-month simulation period. The results suggest that input of soluble electron donors over a period of years could lead to a major redistribution of uranium in fractured subsurface sediments, converting potentially mobile sorbed U(VI) to an insoluble reduced phase (i.e. uraninite) in the mesopore domain that is expected to be permanently immobile under sustained anaerobic conditions. 相似文献
162.
Virkutyte J van Hullebusch E Sillanpää M Lens P 《Environmental pollution (Barking, Essex : 1987)》2005,138(3):517-528
The effect of electrokinetic treatment (0.15 mA cm(-2)) on the metal fractionation in anaerobic granular sludge artificially contaminated with copper (initial copper concentration 1000 mg kg(-1) wet sludge) was studied. Acidification of the sludge (final pH 4.2 in the sludge bed) with the intention to desorb the copper species bound to the organic/sulfides and residual fractions did not result in an increased mobility, despite the fact that a higher quantity of copper was measured in the more mobile (i.e. exchangeable/carbonate) fractions at final pH 4.2 compared to circum-neutral pH conditions. Also addition of the chelating agent EDTA (Cu2+:EDTA4- ratio 1.2:1) did not enhance the mobility of copper from the organic/sulfides and residual fractions, despite the fact that it induced a reduction of the total copper content of the sludge. The presence of sulfide precipitates likely influences the copper mobilisation from these less mobile fractions, and thus makes EDTA addition ineffective to solubilise copper from the granules. 相似文献
163.
A reaction-transport model for calcite precipitation and evaluation of infiltration fluxes in unsaturated fractured rock 总被引:1,自引:0,他引:1
The percolation flux in the unsaturated zone (UZ) is an important parameter addressed in site characterization and flow and transport modeling of the potential nuclear-waste repository at Yucca Mountain, NV, USA. The US Geological Survey (USGS) has documented hydrogenic calcite abundances in fractures and lithophysal cavities at Yucca Mountain to provide constraints on percolation fluxes in the UZ. The purpose of this study was to investigate the relationship between percolation flux and measured calcite abundances using reactive transport modeling. Our model considers the following essential factors affecting calcite precipitation: (1) infiltration, (2) the ambient geothermal gradient, (3) gaseous CO(2) diffusive transport and partitioning in liquid and gas phases, (4) fracture-matrix interaction for water flow and chemical constituents, and (5) water-rock interaction. Over a bounding range of 2-20 mm/year infiltration rate, the simulated calcite distributions capture the trend in calcite abundances measured in a deep borehole (WT-24) by the USGS. The calcite is found predominantly in fractures in the welded tuffs, which is also captured by the model simulations. Simulations showed that from about 2 to 6 mm/year, the amount of calcite precipitated in the welded Topopah Spring tuff is sensitive to the infiltration rate. This dependence decreases at higher infiltration rates owing to a modification of the geothermal gradient from the increased percolation flux. The model also confirms the conceptual model for higher percolation fluxes in the fractures compared to the matrix in the welded units, and the significant contribution of Ca from water-rock interaction. This study indicates that reactive transport modeling of calcite deposition can yield important constraints on the unsaturated zone infiltration-percolation flux and provide useful insight into processes such as fracture-matrix interaction as well as conditions and parameters controlling calcite deposition. 相似文献
164.
Kim E Hopke PK Edgerton ES 《Journal of the Air & Waste Management Association (1995)》2003,53(6):731-739
Data characterizing daily integrated particulate matter (PM) samples collected at the Jefferson Street monitoring site in Atlanta, GA, were analyzed through the application of a bilinear positive matrix factorization (PMF) model. A total of 662 samples and 26 variables were used for fine particle (particles < or = 2.5 microm in aerodynamic diameter) samples (PM2.5), and 685 samples and 15 variables were used for coarse particle (particles between 2.5 and 10 microm in aerodynamic diameter) samples (PM10-2.5). Measured PM mass concentrations and compositional data were used as independent variables. To obtain the quantitative contributions for each source, the factors were normalized using PMF-apportioned mass concentrations. For fine particle data, eight sources were identified: SO4(2-) -rich secondary aerosol (56%), motor vehicle (22%), wood smoke (11%), NO(3-) -rich secondary aerosol (7%), mixed source of cement kiln and organic carbon (OC) (2%), airborne soil (1%), metal recycling facility (0.5%), and mixed source of bus station and metal processing (0.3%). The SO4(2-) -rich and NO(3-) -rich secondary aerosols were associated with NH(4+). The SO4(2-) -rich secondary aerosols also included OC. For the coarse particle data, five sources contributed to the observed mass: airborne soil (60%), NO(3-)-rich secondary aerosol (16%), SO4(2-) -rich secondary aerosol (12%), cement kiln (11%), and metal recycling facility (1%). Conditional probability functions were computed using surface wind data and identified mass contributions from each source. The results of this analysis agreed well with the locations of known local point sources. 相似文献
165.
In this study we compared the contribution of individual congeners and the ratios of stable carbon isotopes of two technical toxaphene products. The former US-American product Toxaphene was from 1978 and the East-German product Melipax from 1979. Both technical products showed the known complexity in GC/ECD measurements. Contributions of 24 peaks to each of the technical products were determined by gas chromatography in combination high resolution electron capture negative ion mass spectrometry (GC/ECNI-HRMS). The percentages of the compounds studied in the technical mixtures ranged from approximately 0.05% to approximately 2.5% but showed some individual differences. 2,2,5,5,8,9,9,10,10-nonachlorobornane (B9-1025 or P-62) was identified as a major congener in both mixtures. 2-Endo,3-exo,5-endo,6-exo,8,8,10,10-octachlorobornane (B8-1413 or P26) and 2-endo,3-exo,5-endo,6-exo,8,8,9,10,10-nonachlorobornane (B9-1679 or P-50) were found at similar concentration in both technical products. Identical amounts of Melipax or Toxaphene were combusted to CO2 in an element analyzer and their delta13C values were determined relative to the international standard Vienna PeeDee belemnite (VPDB). The mean delta13C values of both products varied by 2.8% (determined at two different locations) which is roughly one order of magnitude more than the precision obtained in repetitive analyses of the individual products. Thus, both investigated products could be unequivocally distinguished by stable isotope ratio mass spectrometry (IRMS). IRMS analyses may thus be a suitable tool for tracing back toxaphene residues in environmental and food samples to the one or both of the products. 相似文献
166.
Chen JC Chen WH Chang NB Davila E Tsai CH 《Journal of the Air & Waste Management Association (1995)》2005,55(9):1356-1366
Conflicting goals affecting solid waste management are explored in this paper to find the best implementation of resource recovery with a small-scale waste-to-energy process. Recycling paper and plastic material often leaves a shortage of thermal energy to support incineration that forces operators to supplement the process with auxiliary fuels. Although there are considerable profits to be made from material recovery, the increase of fuel usage causes conflict given that it is cost prohibitive. A series of trials performed on a small-scale 1.5-t/day incineration plant with a cyclone heat recovery system found that material recycling can impede performance. Experimental results are expressed as empirical regression formulas with regard to combustion temperature, energy transfer, and heat recovery. Process optimization is possible if the waste moisture content remains <30%. To test the robustness of the optimization analysis, a series of sensitivity analyses clarify the extent of material recycling needed with regard to plastic, paper, and metal. The experiments also test whether the moisture in the waste would decrease when recycling paper because of its exceptional capacity to absorb moisture. Results show that recycling paper is strongly recommended when the moisture content is >20%, whereas plastic recycling is not necessary at that moisture condition. Notably, plastic recovery reduces the heat needed to vaporize the water content of the solid waste, thus it is recommended only when the moisture content is <10%. For above-normal incineration temperatures, plastic recycling is encouraged, because it removes excess energy. Metal is confirmed as an overall priority in material recycling regardless of the moisture content of the incoming waste. 相似文献
167.
Patrick F. Dowd Eric T. Johnson 《Mitigation and Adaptation Strategies for Global Change》2018,23(7):1063-1081
Warming climatic conditions can pose problems for crop production in many parts of the world, but detailed information on the expression of heat and drought stress resistance genes of potentially affected crop plants is lacking. This information is important to have in order to most efficiently guide the breeding of crops that are adapted to new climatic conditions. A maize (Zea mays) gene microarray, a method used worldwide to evaluate the expression of tens of thousands of genes at once, was used to investigate changes in expression of genes involved in resistance to heat and water stress in milk stage popcorn kernels from undamaged and insect-damaged ears. Popcorn is a form of maize that is more susceptible to heat and drought stress due to its smaller root system. In years of heat and drought stress, expression of many heat shock- and senescence-related proteins increased compared to the year when weather was closer to average conditions, but the expression of many genes related to drought stress resistance decreased in years of weather stress. A different complex of heat shock protein and water stress resistance protein genes had higher expression in kernels from undamaged compared to insect-damaged ears in years of heat and drought stress. These results indicate that the interaction of biotic components, such as insects, are important to consider in developing crop lines with adaptation to stress as this will help identify additional genes and their regulatory components involved in heat and drought stress resistance that might otherwise be overlooked, and will likely be an important strategy for the most effective development of climate stress-tolerant crops globally. 相似文献
168.
Kevin Shirley Eric Marland Jenna Cantrell Gregg Marland 《Mitigation and Adaptation Strategies for Global Change》2011,16(3):325-346
We recognize that carbon-containing products do not decay and release CO2 to the atmosphere instantaneously, but release that carbon over extended periods of time. For an initial production of a
stock of carbon-containing product, we can treat the release as a probability distribution covering the time over which that
release occurs. The probability distribution that models the carbon release predicts the amount of carbon that is released
as a function of time. The use of a probability distribution in accounting for the release of carbon to the atmosphere realizes
a fundamental shift from the idea that all carbon-containing products contribute to a single pool that decays in proportion
to the size of the stock. Viewing the release of carbon as a continuous probabilistic process introduces some theoretical
opportunities not available in the former paradigm by taking advantage of other fields where the use of probability distributions
has been prevalent for many decades. In particular, theories developed in the life insurance industry can guide the development
of pricing and payment structures for dealing with the costs associated with the oxidation and release of carbon. These costs
can arise from a number of proposed policies (cap and trade, carbon tax, social cost of carbon, etc), but in the end they
all result in there being a cost to releasing carbon to the atmosphere. If there is a cost to the emitter for CO2 emissions, payment for that cost will depend on both when the emissions actually occur and how payment is made. Here we outline
some of the pricing and payment structures that are possible which result from analogous theories in the life insurance industry.
This development not only provides useful constructs for valuing sequestered carbon, but highlights additional motivations
for employing a probability distribution approach to unify accounting methodologies for stocks of carbon containing products. 相似文献
169.
错流式膜-生物反应器处理生活污水及其生物学研究 总被引:11,自引:5,他引:6
用错流式膜-生物反应器(CrosflowMembraneBioReactor简称CMBR)进行处理生活污水试验并研究其生物动力学参数.结果表明:当HRT为5h,SRT为15d,膜面流速为4m/s,膜通量为75、150L/(m2·h)时,CMBR处理生活污水试验的去除率为:COD>97%、NH3-N>97%、浊度≥98%;对SS和总E.coli则达到100%,出水水质优于建设部生活杂用水回用标准CJ25.1-89.生物相分析表明,污泥中没有原、后生动物,只有菌胶团.推导了CMBR稳态运行时的生物浓度计算公式,进而求得表观产率因数Yg为0.65,衰减常数Kd为0.1d-1. 相似文献
170.
By scoring the chromosome number of developing embryos, we show that the sex ratio bias of the African social spider Stegodyphus dumicola Pocock is the result of an overproduction of female embryos. Only 17% of 585 embryos sexed from 14 egg sacs were male, a
significant departure from a 1:1 sex ratio. We also explored the possibility of direct control of the sex of individual offspring
in this species by examining the variance in the number of males per sac and the spatial distribution of male and female embryos
within the sacs. We postulated that a variance in the number of males per sac lower than binomial (i.e., underdispersed or
precise sex ratios) or a non-random distribution of male embryos within the sacs would suggest direct control of the sex of
individual offspring. We found that the variance in the number of males per sac was indistinguishable from binomial and significantly
larger than expected under exact ratios. Likewise, the spatial distribution of male embryos within three sacs examined was
no more clustered than expected by chance. The sex ratio biasing mechanism in this species, therefore, apparently only allows
control of the mean sex ratio but not of its variance. We present randomization and Monte Carlo methods that can be applied
to test for departures from a random spatial arrangement of male and female embryos in an egg mass and for departures from
binomial or exact ratios when not all members of a clutch have been sexed.
Received: 21 October 1998 / Received in revised form: 23 March 1999 / Accepted: 26 April 1999 相似文献