Effect of humic acid and metal ions on the debromination of BDE209 by nZVM prepared from steel pickling waste liquor

As a promising in situ remediation technology, nanoscale zero-valent iron (nZVI) can remove polybrominated diphenyl ethers such as decabromodiphenyl ether (BDE209) effectively, However its use is limited by its high production cost. Using steel pickling waste liquor as a raw material to prepare nanoscale zero-valent metal (nZVM) can overcome this deficiency. It has been shown that humic acid and metal ions have the greatest influence on remediation. The results showed that nZVM and nZVI both can effectively remove BDE209 with little difference in their removal efficiencies, and humic acid inhibited the removal efficiency, whereas metal ions promoted it. The promoting effects followed the order Ni²⁺>Cu²⁺>Co²⁺ and the cumulative effect of the two factors was a combination of the promoting and inhibitory individual effects. The major difference between nZVM and nZVI lies in their crystal form, as nZVI was found to be amorphous while that of nZVM was crystal. However, it was found that both nZVM and nZVI removed BDE209 with similar removal efficiencies. The effects and cumulative effects of humic acid and metal ions on nZVM and nZVI were very similar in terms of the efficiency of the BDE209 removal.     

Detecting and quantifying reductive dechlorination under monitored natural attenuation conditions

Field sampling and testing were used to investigate the relationship between baseline geochemical and microbial community data and in situ reductive dechlorination rates at a site contaminated with trichloroethene (TCE) and carbon tetrachloride (CTET). Ten monitoring wells were selected to represent conditions along groundwater flow paths from the contaminant source zone to a wetlands groundwater discharge zone. Groundwater samples were analyzed for a suite of geochemical and microbial parameters; then push‐pull tests with fluorinated reactive tracers were conducted in each well to measure in situ reductive dechlorination rates. No exogenous electron donors were added in these tests, as the goal was to assess in situ reductive dechlorination rates under natural attenuation conditions. Geochemical data provided preliminary evidence that reductive dechlorination of TCE and CTET was occurring at the site, and microbial data confirmed the presence of known dechlorinating organisms in groundwater. Push‐pull tests were conducted using trichlorofluoroethene (TCFE) as a reactive tracer for TCE and, in one well, trichlorofluoromethane (TCFM) as a reactive tracer for CTET. Injected TCFE was transformed to cis‐ and trans‐dichlorofluoroethene and chlorofluoroethene, and, in one test, injected TCFE was completely dechlorinated to fluoroethene (FE). In situ TCFE transformation rates ranged from less than 0.005 to 0.004/day. In the single well tested, injected TCFM was transformed in situ to dichlorofluoromethane and chlorofluoromethane; the TCFM transformation rate was estimated as 0.001/day. The results indicate that it is possible to use push‐pull tests with reactive tracers to directly detect and quantify reductive dechlorination of chlorinated ethenes and ethanes under monitored natural attenuation conditions, which has not previously been demonstrated. Transformation rate estimates obtained with these techniques should improve the accuracy of contaminant transport modeling. © 2012 Wiley Periodicals, Inc.     

Forestry administration and policies in the Philippines

This article begins by summarizing the importance of the forestry sector in the Philippine economy It provides an overview of the multiplicity of Philippine governmental institutions involved in forestry in 1982 Then it discusses forestry laws in the country and concludes by examining fifteen critical forest policy issues: sustained yield management; area-specific logging bans; increased use of wood wastes; revision of forest charges; unprocessed log export ban; rationalization of the forest industry, acceleration of reforestation; protection of watersheds; recognition of the social dimensions of slash- and-burn agriculture; fuelwood supply; public land classification for forestry and agriculture, development of plantations for dendrothermal electricity; multiple-use management; preservation of mangrove areas, and improvements in administration and implementation.Research for this paper was supported by the East-West Center Environment and Policy Institute. The author would like to acknowledge the assistance of the Natural Resources Management Center of the Philippine Ministry of Natural Resources.     

Results of a program to control phosphorus discharges from dairy operations in south-central Florida,USA

During 1987–1992, a mandatory program to control phosphorus discharges was implemented at dairy operations located to the north of Lake Okeechobee, Florida, USA. Thirty of 48 dairies participated in this program and implemented best management practices (BMPs), which included the construction of intensive animal waste management systems. Eighteen dairies closed their milkproducing operations under a government-funded buyout program. In this paper, we compare trends in runoff total phosphorus (TP) concentrations among the dairies that remained active and implemented BMPs. A central feature of the dairy waste management system is the high intensity area (HIA), defined as the milking barn and adjacent vegetation-free land, encircled by a drainage ditch and dike. Animal waste from the HIA is diverted into anaerobic lagoons and storage ponds, from which water is periodically removed and used for irrigation of field crops. The impacts of BMP construction on runoff TP concentrations were immediate and, in most cases, dramatic. Average TP concentrations declined significantly (P < 0.001), from 9.0 to 1.2 mg TP liter^–1 at dairies in one basin (Lower Kissimmee River), and from 2.6 to 1.0 mg TP liter^–1 in another (Taylor Creek/Nubbin Slough). Some sites experienced greater declines in TP than others. To elucidate possible causes for the difference in response, a multivariate statistical model was utilized. Independent variables included soil pH, soil drainage characteristics, spodic horizon depth, and the areas of different BMP components (pasture, HIA, spray fields). The analysis significantly separated dairies with the highest and lowest runoff TP concentrations. Lowest TP occurred at dairies having particular soil characteristic (shallow spodic horizon) and certain BMP features (large HIA and small heard pastures).     

POTENTIAL IMPACTS OF CLIMATE CHANGE ON CALIFORNIA HYDROLOGY1

ABSTRACT: Previous reports based on climate change scenarios have suggested that California will be subjected to increased wintertime and decreased summertime streamflow. Due to the uncertainty of projections in future climate, a new range of potential climatological future temperature shifts and precipitation ratios is applied to the Sacramento Soil Moisture Accounting Model and Anderson Snow Model in order to determine hydrologic sensitivities. Two general circulation models (GCMs) were used in this analysis: one that is warm and wet (HadCM2 run 1) and one that is cool and dry (PCM run B06.06), relative to the GCM projections for California that were part of the Third Assessment Report of the Intergovernmental Panel on Climate Change. A set of specified incremental temperature shifts from 1.5°C to 5.0°C and precipitation ratios from 0.70 to 1.30 were also used as input to the snow and soil moisture accounting models, providing for additional scenarios (e.g., warm/dry, cool/wet). Hydrologic calculations were performed for a set of California river basins that extend from the coastal mountains and Sierra Nevada northern region to the southern Sierra Nevada region; these were applied to a water allocation analysis in a companion paper. Results indicate that for all snow‐producing cases, a larger proportion of the streamflow volume will occur earlier in the year. The amount and timing is dependent on the characteristics of each basin, particularly the elevation. Increased temperatures lead to a higher freezing line, therefore less snow accumulation and increased melting below the freezing height. The hydrologic response varies for each scenario, and the resulting solution set provides bounds to the range of possible change in streamflow, snowmelt, snow water equivalent, and the change in the magnitude of annual high flows. An important result that appears for all snowmelt driven runoff basins, is that late winter snow accumulation decreases by 50 percent toward the end of this century.     

ESTIMATING EVAPORATION FROM UTAH'S GREAT SALT LAKE USING THERMAL INFRARED SATELLITE IMAGERY1

ABSTRACT: Water surface temperatures can be obtained from satellite thermal remote sensing. Landsat and other satellites sense emitted thermal infrared radiation on a regular basis over much of the earth's surface. Evaporation is accomplished by the net transport of mass from the water surface to the atmosphere. The evaporative transfer predominantly determines the water surface temperature. Hence, there should be good correlations between evaporation and surface temperatures. Previous investigations on Utah Lake with satellite-derived temperatures and pan- and model-derived evaporation values have produced good correlations. However, more study was required with additional satellite data and evaporation measurements for saltwater conditions. The applicability of this method for estimating evaporation on Utah's Great Salt Lake was of particular interest at this time because of the unprecedented rise of this terminal lake. Satellite thermal data and evaporation data from four different years were obtained for the Great Salt Lake and the surrounding region. More than 350 correlation and linear regression analyses were performed on the temperature and evaporation data. The lake salt concentrations were also factored into the analyses in several different ways. The correlation results were generally very good and a methodology for using satellite-derived water surface temperatures along with salt concentrations was developed to estimate evaporation.     

PROBLEMS AND METHODS INVOLVED IN RELATING LAND USE TO GROUND-WATER QUALITY1

ABSTRACT: Efforts to relate shallow ground-water quality to the land use near a well lead to several statistical difficulties. These include potential uncertainty in land-use categorical data due to misclassification, data closure, distributional skewing, and spatial autocorrelation. Methods of addressing these problems are, respectively, the establishment of limits on minimum buffer radius, the estimation of contrasts, rank-based tests of association, and sub-sampling to prevent buffer overlap. Relations between the presence of purgeable organic compounds in ground water and land use are used to illustrate these problems and methods.     

Evaluating cumulative effects on wetland functions: A conceptual overview and generic framework

This article outlines conceptual and methodological issues that must be confronted in developing a sound scientific basis for investigating cumulative effects on freshwater wetlands. We are particularly concerned with: (1) effects expressed at temporal and spatial scales beyond those of the individual disturbance, specific project, or single wetland, that is, effects occurring at the watershed or regional landscape level; and (2) the scientific (technical) component of the overall assessment process. Our aim is to lay the foundation for a research program to develop methods to quantify cumulative effects of wetland loss or degradation on the functioning of interacting systems of wetlands. Toward that goal we: (1) define the concept of cumulative effects in terms that permit scientific investigation of effects; (2) distinguish the scientific component of cumulative impact analysis from other aspects of the assessment process; (3) define critical scientific issues in assessing cumulative effects on wetlands; and (4) set up a hypothetical and generic structure for measuring cumulative effects on the functioning of wetlands as landscape systems.We provide a generic framework for evaluating cumulative effects on three basic wetland landscape functions: flood storage, water quality, and life support. Critical scientific issues include appropriate delineations of scales, identification of threshold responses, and the influence on different functions of wetland size, shape, and position in the landscape.The contribution of a particular wetland to landscape function within watersheds or regions will be determined by its intrinsic characteristics, e.g., size, morphometry, type, percent organic matter in the sediments, and hydrologic regime, and by extrinsic factors, i.e., the wetland's context in the landscape mosaic. Any cumulative effects evaluation must take into account the relationship between these intrinsic and extrinsic attributes and overall landscape function. We use the magnitude of exchanges among component wetlands in a watershed or larger landscape as the basis for defining the geographic boundaries of the assessment. The time scales of recovery for processes controlling particular wetland functions determine temporal boundaries. Landscape-level measures are proposed for each function.     

Redistributive state planning: toward an operational framework for an effective spatial development planning

The paper starts from an assessment of regional policy inspired by considerations of social justice. An effort is made to sketch the outline of a top‐down and bottom‐up approach and provide a new profile for regional planning, and for professional planners within the context of contemporary politico‐economic transformations. The planner, from having been a pure technician who does not question the nature of problems faced, must become actively engaged in, and committed to the problems and conflicts of the area, and to the specific proposals put forward.     

EFFECTS OF VARIABLE DISCHARGE SCHEMES ON DISSOLVED OXYGEN AT A HYDROELECTRIC STATION1

ABSTRACT: The effects of variable discharges during the summer on the dissolved oxygen (DO) content and water temperature upstream and downstream of the Conowingo Hydroelectric Power Station were investigated. The DO dynamics are controlled primarily by meteorological factors that are independent of the mode of hydrostation operation. DO stratification occurred during the summer in Conowingo Pond, but thermal stratification was not observed. The magnitude and duration of off-peak discharges including a run-of-the-river operation did not affect DO stratification in Conowingo Pond; little vertical mixing occurred. However, strong winds and/or high river flows temporarily destroyed DO stratification. The run-of-the-river operation or off-peak continuous discharge schemes did not provide better DO conditions downstream of the hydrostation than the peaking operation with intermittent off-peak releases. A statistical model predicted that a DO of 5 ppm occurs 0.6 miles downstream of the powerhouse when the natural river flow is consistently greater than 15,000 cfs and water temperature is less than 80°F. A mean daily DO of at least 4 ppm was predicted to occur over 80 percent of the time during the 92-day summer period. Farther downstream (1.3 miles from the powerhouse) a mean daily DO of at least 4 ppm was predicted to occur 90 percent of the time in summer.