The applications of chlorine have been broadly used in many industrial products, such as bleaching agents, synthetic rubbers, plastics, disinfectants, iron chlorides, fire refractory materials, insecticides, and anti-freezers, etc. According to the Taiwan Environmental Protection Administration (TEPA), more than 30 thousand tons were used in the year 2000. In addition, there were more than 12 reported incidents from 2000 to 2003—mostly on using chlorine as disinfectants (five) and as process agents (four).
This study investigated 15 chlorine operation plants in central Taiwan. These chlorine usages included bleaching agents, disinfectants, iron chloride, synthesizing rubber plastics, and others. Thirteen plants were located in the industrial parks and two were in or near residential zones. The consequence analysis were used three different methods to analyze the worst-case scenarios (WCSs) and alternative release case scenarios (ACSs) in order to compare impact zones for applying various active and passive mitigation systems, such as confined space, scrubber, water-spray, and so no. For two plants in or near residential zones, multi-layers mitigation systems and operation limits should be implemented in order to enforce more stringent protection measures. However, there was no specific regulation for chlorine plants operated at different locations, such as industrial parks or residential zones. In order to reduce chemical accidents and their impacts on public safety, our results suggest that source mitigation/management and warning systems should be adopted simultaneously. 相似文献
The Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) and the Mine Safety and Health Administration (MSHA) conducted joint research on dust explosions by studying post-explosion dust samples. The samples were collected after full-scale explosions at the PRL Lake Lynn Experimental Mine (LLEM), and after laboratory explosions in the PRL 20-L chamber and the Fike 1 m3 chamber. The dusts studied included both high- and low-volatile bituminous coals. Low temperature ashing for 24 h at 515 °C was used to measure the incombustible content of the dust before and after the explosions. The data showed that the post-explosion incombustible content was always as high as, or higher than the initial incombustible content. The MSHA alcohol coking test was used to determine the amount of coked dust in the post-explosion samples. The results showed that almost all coal dust that was suspended within the explosion flame produced significant amounts of coke. Measurements of floor dust concentrations after LLEM explosions were compared with the initial dust loadings to determine the transport distance of dust during an explosion. All these data will be useful in future forensic investigations of accidental dust explosions in coal mines, or elsewhere. 相似文献
Carbon dioxide is the major greenhouse gas responsible for global warming. Man-made CO2 emissions contribute approximately 63% of greenhouse gases and the cement industry is responsible for approximately 5% of CO2 emissions emitting nearly 900 kg of CO2 per 1000 kg of cement. CO2 from a cement plant was captured and purified to 98% using the monoethanolamine (MEA) based absorption process. The capture cost was $51 per tonne of CO2 captured, representing approximately 90% of total cost. Steam was the main operating cost representing 39% of the total capture cost. Switching from coal to natural gas reduces CO2 emissions by about 18%. At normal load, about 36 MW of waste heat is available for recovery to satisfy the parasitic heat requirements of MEA process; however, it is very difficult to recover. 相似文献
Innovations in water chain are discussed based on experiences in the Netherlands. The available and new technological options, as well as their dissemination in the Netherlands, are presented for the prevailing system with add-on technologies (elongation), and for the emerging separation system with technologies at the source. Numerous new options are available for both systems but these options are rarely used. The low use is explained using economic theories and with practical examples from the Netherlands. In order to foster innovations, the mainstream, evolutionary, and behavioral theories pinpoint respectively the pricing of common goods, broad support of concerted action, and support for innovators’ entry. These actions may all be needed. Experiences with a stakeholder cluster in water management suggest that markets for high value water use invoke innovations and low-cost technology adaptations. The systematic development of services that foster high value water-based activities is recommended. 相似文献
Multi-walled carbon nanotube(MWCNT) sheet was fabricated from a drawable MWCNT forest and then deposited on poly(methyl methacrylate) film. The film was further coated with a natural antimicrobial peptide nisin. We studied the effects of nisin coating on the attachment of Bacillus anthracis spores, the germination of attached spores, and the subsequent biofilm formation from attached spores. It was found that the strong adsorptivity and the super hydrophobicity of MWCNTs provided an ideal platform for nisin coating. Nisin coating on MWCNT sheets decreased surface hydrophobicity, reduced spore attachment, and reduced the germination of attached spores by 3.5 fold, and further inhibited the subsequent biofilm formation by 94.6% compared to that on uncoated MWCNT sheet. Nisin also changed the morphology of vegetative cells in the formed biofilm.The results of this study demonstrated that the anti-adhesion and antimicrobial effect of nisin in combination with the physical properties of carbon nanotubes had the potential in producing effective anti-biofilm formation surfaces. 相似文献