Adsorption of Pb, Cd to Fe, Mn oxides in natural freshwater surface coatings developed in different seasons

Metal oxides( Fe, Mn oxides) in natural surface coatings(biofilms and associated minerals) are believed to play a significant role n the fate and transport of trace metal in aquatic environments. Seasonal variation of Fe, Mn oxides and organic materials in surface oatings, which were developed periodically on glass slides in Nanhu Lake, Jilin Province, China over the time frame of three seasons,was investigated in order to understand the influence of metal oxides on Pb and Cd adsorption to heterogeneous surface coating materials(biofilm). Pb and Cd adsorption was measured under controlled laboratory conditions( mineral salts solution with defined speciation, ionic trength 0.05 mol/L, 25~C and pH 6.0). The classical Langmuir adsorption isotherm was applied to estimate equilibrium coefficients of Pb nd Cd adsorption to the surface coatings. In general, components in the surface coatings varied greatly with seasons altering and btained higher concentrations in summer while the content of iron oxides always exceeded that of manganese oxides. Correlation nalyses between the maximum adsorption of Pb and Cd and components in the surface coatings developed periodically indicated that Pb hase association with Mn oxides and Cd phase association with Fe oxides as well as Mn oxides were statistically significant. Effect of Mn xides on Cd adsorption was confirmed in view of its higher content in the surface coatings. The importance of ferromanganese oxides for b and Cd adsorption to the natural surface coatings developed in different seasons was evidenced.     

Use and knowledge of fuelwood in three rural caatinga (dryland) communities in NE Brazil

The woody species known, used, and preferred as fuelwood were examined in three rural communities within the county of Soledade, Paraíba State, NE Brazil. Ethnobotanical information was collected using semi-structured interviews with more than 90% of the local households (55 adult residents; 31 women, and 24 males). The interviewees cited 36 plant species as fuelwoods, distributed among 30 genera and 15 families, in addition to two unidentified plants. The plant families represented by the largest numbers of species were Euphorbiaceae, Anacardiaceae, Mimosaceae, Caesalpiniaceae, Sapotaceae, and Fabaceae. The species Caesalpinia pyramidalis Tul. (“catingueira”) was cited with the greatest frequency in all three communities. Within the communities we found significant differences on the number of plants cited and actually used (p < 0.05), indicating that the residents knew more fuelwood species than they effectively harvest. The different distances from the communities to the urban centers were not related to differences on the use or the size of the stocks of fuelwood. Additionally, the study revealed that the communities examined still maintain a significant knowledge of the use of energy-providing plants in spite of the widespread use of liquefied petroleum gas (LPG). Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue.     

Radiological maps for Trabzon, Turkey

The activity concentrations and absorbed gamma dose rates due to primordial radionuclides and ¹³⁷Cs have been ascertained in 222 soil samples in 18 counties of the Trabzon province of Turkey using a HPGe detector. The mean activity concentrations of ²³⁸U, ²³²Th, ⁴⁰K and ¹³⁷Cs in soil samples were 41, 35, 437 and 21 Bq kg⁻¹, respectively. Based on the measured concentrations of these radionuclides, the mean absorbed gamma dose in air was calculated as 59 nGy h⁻¹ and hence, the mean annual effective dose due to terrestrial gamma radiation was calculated as 72 μSv y⁻¹. In addition, outdoor in situ gamma dose rate (D) measurements were performed in the same 222 locations using a portable NaI detector and the annual effective dose was calculated to be 66 μSv y⁻¹ from these results. The results presented in this study are compared with other parts of Turkey. Radiological maps of the Trabzon province were composed using the results obtained from the study.     

快速城市化地区的土地利用时空动态变化研究 --以南京市为例

20年来,在中国城市化快速发展的过程中,一系列与城市化相关的环境问题随之产生。六朝古都——南京,作为我国经济最发达的长江流域四大中心城市之一,其快速的城市化过程也不可避免地带来了同样的环境问题。为了研究南京市的城市化和土地利用变化规律及其对水文过程的影响,利用1987、1998、2000年的三期遥感数据,通过分层分类的方法对各土地利用类型进行专题信息提取,结合GIS技术,获得研究区1987~1998,1998~2000年两个时段的土地利用变化转移矩阵。据此全面分析了南京市的土地利用时空变化特征。结果表明：南京市13年来,城乡居民及建设用地以大量蚕食耕地而显著增加,年均增幅达到1.92％;耕地和未利用地则明显减少,年均减幅分别为0.62％ 和1.21％;林地和水域有所增加,主要来自未利用地的转变,剩余12.35％的未利用地则转化为城乡居民及建设用地。引起这一土地利用变化的主要驱动力是人口的增长和经济的发展以及政策制度的激励和导向作用。     

Regulation of nuclear radiation exposures in India

India has a long-term program of wide spread applications of nuclear radiations and radioactive sources for peaceful applications in medicine, industry, agriculture and research and is already having several thousand places in the country where such sources are being routinely used. These places are mostly outside the Department of Atomic Energy (DAE) installations. DAE supplies such sources. The most important application of nuclear energy in DAE is in electricity generation through nuclear power plants. Fourteen such plants are operating and many new plants are at various stages of construction. In view of the above mentioned wide spread applications, Indian parliament through an Act, called Atomic Energy Act, 1964 created an autonomous body called Atomic Energy Regulatory Board (AERB) with comprehensive authority and powers. This Board issues codes, guides, manuals, etc., to regulate such installations so as to ensure safe use of such sources and personnel engaged in such installations and environment receives radiation exposures within the upper bounds prescribed by them. Periodic reports are submitted to AERB to demonstrate compliance of its directives. Health, Safety and Environment Group of Bhabha Atomic Research Centres, Mumbai carries out necessary surveillance and monitoring of all installations of the DAE on a routine basis and also periodic inspections of other installations using radiation sources. Some of the nuclear fuel cycle plants like nuclear power plants and fuel reprocessing involve large radioactive source inventories and have potential of accidental release of radioactivity into the environment, an Environmental Surveillance Laboratory (ESL) is set up at each such site much before the facility goes into operation. These ESL's collect baseline data and monitor the environment throughout the life of the facilities including the decommissioning stage. The data is provided to AERB and is available to members of the public. In addition, a multi-tier system of AERB permissions is in place to ensure that all aspects of safety have been considered before permission to operate is granted. The stages where permission of AERB is essential are site selection, design data, and several stages during construction and operation. The details required by AERB include provision for treatment and storage of radioactive waste, de-commissioning procedures and provision of costs. In addition to AERB, nuclear power plants have to comply with the requirements of Ministry of Environment and Forests and get their clearance. This is given on the basis of Environmental Impact Assessment Report which should satisfy the authorities that no ecological damage will be caused and the facility will not have adverse effect on the environment. In addition, the State Pollution Control Board where the facility is to be located has to permit the site of the plant for its proposed discharges into the environment. It is largely due to the above comprehensive regulatory controls that none of the plants in India had any accident during the last 34 decades of operation. The type of measurements carried out by the ESL's and results from a few typical ESL's will be presented.     

Mitigating Greenhouse Gas Emissions from Rice-Wheat Cropping Systems in Asia

The rice-wheat belt comprises nearly 24–27 million ha in South and East Asia. Rice is generally grown in flooded fields whereas the ensuing wheat crop requires well-drained soil conditions. Consequently, both crops differ markedly in nature and intensity of greenhouse gas (GHG) fluxes, namely emission of (1) methane (CH₄) and (2) nitrous oxide (N_2O) as well as the sequestration of (3) carbon dioxide. Wetland rice emits large quantities of CH₄; strategies to CH₄ emissions include proper management of organic inputs, temporary (mid-season) field drainage and direct seeding. As for the wheat crop, the major GHG is N_2O that is emitted in short-term pulses after fertilization, heavy rainfall and irrigation events. However, N_2O is also emitted in larger quantities during fallow periods and during the rice crop as long as episodic irrigation or rainfall result in aerobic-anaerobic cycles. Wetland rice ensures a relatively high content of soil organic matter in the rice-wheat system as compared to permanent upland conditions. In terms of global warming potential, baseline emissions of the rice-wheat system primarily depend on the management practices during the rice crop while emissions from the wheat crop remain less sensitive to different management practices. The antagonism between CH₄ and N_2O emissions is a major impediment for devising effective mitigation strategies in rice-wheat system - measures to reduce the emission of one GHG often intensify the emission of the other GHG.     

Inhalation dose assessment of indoor radon progeny using biokinetic and dosimetric modeling and its application to Jordanian population

High indoor radon concentrations in Jordan result in internal exposures of the residents due to the inhalation of radon and its short-lived progeny. It is therefore important to quantify the annual effective dose and further the radiation risk to the radon exposure. This study describes the methodology and the biokinetic and dosimetric models used for calculation of the inhalation doses exposed to radon progeny. The regional depositions of aerosol particles in the human respiratory tract were firstly calculated. For the attached progeny, the activity median aerodynamic diameters of 50 nm, 230 nm and 2500 nm were chosen to represent the nucleation, accumulation and coarse modes of the aerosol particles, respectively. For the unattached progeny, the activity median thermodynamic diameter of 1 nm was chosen to represent the free progeny nuclide in the room air. The biokinetic models developed by the International Commission on Radiological Protection (ICRP) were used to calculate the nuclear transformations of radon progeny in the human body, and then the dosimetric model was applied to estimate the organ equivalent doses and the effective doses with the specific effective energies derived from the mathematical anthropomorphic phantoms. The dose conversion coefficient estimated in this study was 15 mSv WLM⁻¹ which was in the range of the values of 6-20 mSv WLM⁻¹ reported by other investigators. Implementing the average indoor radon concentration in Jordan, the annual effective doses were calculated to be 4.1 mSv y⁻¹ and 0.08 mSv y⁻¹ due to the inhalation of radon progeny and radon gas, respectively. The total annual effective dose estimated for Jordanian population was 4.2 mSv y⁻¹. This high annual effective dose calculated by the dosimetric approach using ICRP biokinetic and dosimetric models resulted in an increase of a factor of two in comparison to the value by epidemiological study. This phenomenon was presented by the ICRP in its new published statement on radon.     

Transport and fate of radionuclides in aquatic environments--the use of ecosystem modelling for exposure assessments of nuclear facilities

In safety assessments of nuclear facilities, a wide range of radioactive isotopes and their potential hazard to a large assortment of organisms and ecosystem types over long time scales need to be considered. Models used for these purposes have typically employed approaches based on generic reference organisms, stylised environments and transfer functions for biological uptake exclusively based on bioconcentration factors (BCFs). These models are of non-mechanistic nature and involve no understanding of uptake and transport processes in the environment, which is a severe limitation when assessing real ecosystems. In this paper, ecosystem models are suggested as a method to include site-specific data and to facilitate the modelling of dynamic systems. An aquatic ecosystem model for the environmental transport of radionuclides is presented and discussed. With this model, driven and constrained by site-specific carbon dynamics and three radionuclide specific mechanisms: (i) radionuclide uptake by plants, (ii) excretion by animals, and (iii) adsorption to organic surfaces, it was possible to estimate the radionuclide concentrations in all components of the modelled ecosystem with only two radionuclide specific input parameters (BCF for plants and Kd). The importance of radionuclide specific mechanisms for the exposure to organisms was examined, and probabilistic and sensitivity analyses to assess the uncertainties related to ecosystem input parameters were performed. Verification of the model suggests that this model produces analogous results to empirically derived data for more than 20 different radionuclides.     

Intra-cultivar variability of the soil-to-grain transfer of fallout 137Cs and 90Sr for winter wheat

Differences between the root uptake of fallout radionuclides by different cultivars ('inter-cultivar' variability) growing on the same field may be influenced not only by genetic differences of the cultivars, but also by the spatial variability of the soil-to-grain transfer within the cultivation area of each cultivar. This 'intra-cultivar' variability was investigated in 2001 and 2002 for 137Cs and 90Sr using three winter wheat cultivars with four replicates for each cultivar at three different sites in Bavaria, Germany. The intra-cultivar variability proved to be in the same range as the inter-cultivar variability which was determined earlier at the same sites for both radionuclides. An ANOVA of the 137Cs data set revealed that the variability of the 137Cs soil-to-grain transfer was caused by the soil and climate (year) at the field sites and the interaction of cultivar and field. A significant contribution of the factor 'cultivar' alone to the variability could not be detected. This may be due to the complex environmental conditions to which plants are exposed in field experiments. To find wheat cultivars with minimal uptake of fallout radionuclides it may be better to examine the molecular mechanisms of their root uptake in order to identify targets for breeding "safer" plants.     

Nationwide survey on the natural radionuclides in industrial raw minerals in South Korea

A Nationwide survey on the natural radioactivity in industrial raw mineral commodities (17 kinds of domestic and 18 kinds of imported) that are representative minerals used in production and consumption in South Korea was conducted. The target industrial minerals can be categorized into two groups. The first group covers non-metallic and metallic raw minerals with low levels of radioactivity such as clay, silica sand, carbonates, bituminous and anthracite coal, iron ores, ilmenite, rutile, and phosphate ore. The other group comprises minerals with high levels of radioactivity including zircon and monazite. One hundred and sixty-four domestic and imported samples were analysed by gamma-ray spectroscopy using an HPGe detector. The (40)K content ranges from <0.00131 to 2.69Bq g(-1), and (226)Ra and (232)Th range over <0.0006 to 0.630 and <0.0008 to 0.474Bq g(-1), respectively. There was no anthropogenic radioactive signal in any of the samples.