Mercury cleanup: The commercial application of a new mercury removal/recovery technology

Efficient, economical treatment of mercury-contaminated soils and industrial wastes requires a treatment process that reduces mercury content to near background levels (<1 ppm) and recovers the removed mercury in pure recyclable form without producing liquid, solid, or gaseous secondary wastes. This article reviews the results achieved using a medium-temperature thermal desorption process developed and commercialized by Mercury Recovery Services, Inc. (MRS) that has successfully achieved these goals.     

A hierarchical approach to fisheries planning and modeling in the Columbia River Basin

The Columbia River Basin is the scene of a massive effort to restore populations of Pacific salmon (Oncorhynchus spp.) and steelhead (O. mykiss). Efficient restoration is confounded by a high level of complexity, competing sociopolitical goals and values, and uncertainty about key system properties. Simulation models and other tools of systems analysis are important to development of a comprehensive, regionally acceptable strategy. Hierarchy theory provides a useful paradigm for organized complexity within the Columbia Basin and the basis for a trilevel hierarchical structure for organizing and integrating models. Life-stage models compose the most basic simulation units at the lowest level in the proposed hierarchical modeling structure. Each life-stage model simulates a distinct period in the life cycle of anadromous salmonids. Population models at the intermediate level simulate the complete life cycles of salmon and steelhead populations. At the highest level in the hierarchy, interpopulation models simulate extensive, long-term processes that affect multiple species and stocks. A hierarchical system of models is preferable to a single model or to a group of models lacking formal structure. A principal advantage is that models have the correct spatial and temporal resolution for analyzing questions at different scales. A hierarchical structure also facilitates the flow of information among models, and aids in understanding the impacts of uncertainty. Constructing a hierarchy of models should involve both bottom-up and top-down perspectives that maintain logical consistency among models, while allowing unique model structures appropriate for each level in the hierarchy.     

An approach for analysing the potential for material efficiency improvement

Material efficiency improvement saves energy and reduces the consumption of primary resources and reduces the volume of waste. In this article an approach for analysing the potential for material efficiency improvement is proposed and discussed. In this approach the product functions performed by the materials and various improvement measures are taken into account. The potential for material saving and associated energy saving is assessed and evaluated economically. In this paper the approach is tested in an analysis of the potential for material efficiency improvement with respect to plastic packaging in the Netherlands. The technical reduction potential is found to be 34 ± 7% (157 ± 30 ktonne virgin plastics). Realization of this potential would improve the energy efficiency of the lifecycle of plastic packaging by 31% (10 PJ in 1988). From our study we conclude that our approach can indeed be used to investigate the potential for material efficiency improvement. However, a reliable technical and particularly an economical assessment of reduction measures cannot be made until more detailed data become available.     

Deep-Sea Mining: The Consequences of Failure to Agree at UNCLOS III

In July 1982 the US Government announced that it would not sign the new Convention on the Law of the Sea adopted at the eleventh session of the Third United Nations Conference on the Law of the Sea in April 1982. This article investigates the possible consequences of the failure to achieve a consensus between the Group of 77 and the western industrialised States on a regime to govern the deep-sea mining of manganese nodules. After considering the range of possible outcomes, the author identifies the benefits and costs involved in operating under the two alternative regimes, that provided by the new Convention and related Conference resolutions and the alternative Reciprocating States Regime based on unilateral legislation co-ordinated by a Mini-Treaty. En juillet 1982, le gouvernement des Etats-Unis a annoncé qu'il ne signerait pas la nouvelle Convention sur le droit de la mer qui a été adoptée à la llème session de la troisième Conférence des Nations Unies sur le droit de la mer en avril 1982. Cet article étudie les conséquences possibles de l'absence d'un consensus entre le Groupe des 77 et les nations industrielles occidentales sur un régime devant gouverner l'exploitation des nodules de manganèse que l'on trouve sur les fonds marins profonds. Après avoir consideéré tout un éventail de résultantes éventuelles, l'auteur dresse un état des avantages et désavantages que présentent les deux régimes possibles, c'est-à-dire le régime prévu par la nouvelle Convention et les résolutions concomitantes adoptées par la Conférence et le régime de réciprocité entre états basé sur une législation unilatérale et sanctionné par un mini-traité. En julio de 1982 el gobierno de los Estados Unidos anunció que no firmaría la nueva Convención sobre el Derecho del Maradoptada en la undécima sesión de la Tercera Conferencia de las Naciones Unidas sobre el Derecho del Mar en abril de 1982. Este artículo investiga las posibles consecuencias de la falta de consenso entre el Grupo de los 77 y los estados industriales occidentales sobre el régimen que gobierna la extracción de nódulos de manganeso en mares profundos. Después de considerar el posible rango de consecuencias el autor evalúa los costos y beneficios resultantes de operar bajo dos regímenes alternativos, aquel definido por la nueva convención y las resoluciones relacionadas y el Régimen de Reciprocidad entre Estados basado en legislación unilateral coordinados por el Mini-Tratado.     

Modeling channel management impacts on river migration: a case study of Woodson bridge state recreation area,Sacramento river,California, USA

Understanding how hydraulic factors control alluvial river meander migration can help resource managers evaluate the long-term effects of floodplain management and bank stabilization measures. Using a numerical model based on the mechanics of flow and sediment transport in curved river channels, we predict 50 years of channel migration and suggest the planning and ecological implications of that migration for a 6.4-km reach (river miles 218–222) of the Sacramento River near the Woodson Bridge State Recreation Area, California, USA. Using four different channel management scenarios, our channel migration simulations suggest that: (1) channel stabilization alters the future channel planform locally and downstream from the stabilization; (2) rock revetment currently on the bank upstream from the Woodson Bridge recreation area causes more erosion of the channel bank at the recreation area than if the revetment were not present; (3) relocating the channel to the west and allowing subsequent unconstrained river migration relieves the erosion pressure in the Woodson Bridge area; (4) the subsequent migration reworks (erodes along one river bank and replaces new floodplain along the other) 26.5 ha of land; and (5) the river will rework between 8.5 and 48.5 ha of land in the study reach (over the course of 50 years), depending on the bank stabilization plan used. The reworking of floodplain lands is an important riparian ecosystem function that maintains habitat heterogeneity, an essential factor for the long-term survival of several threatened and endangered animal species in the Sacramento River area.     

Kinetics and mechanism of oxidation of tetrachloroethylene with permanganate

The kinetics, reaction pathways and product distribution of oxidation of tetrachloroethylene (PCE) by potassium permanganate (KMnO4) were studied in phosphate-buffered solutions under constant pH, isothermal, completely mixed and zero headspace conditions. Experimental results indicate that the reaction is first-order with respect to both PCE and KMnO4 and has an activation energy of 9.3+/-0.9 kcal/mol. The second-order rate constant at 20 degrees C is 0.035+/-0.004 M(-1) s(-1), and is independent of pH and ionic strength (I) over a range of pH 3-10 and I approximately 0-0.2 M, respectively. The PCE-KMnO4 reaction may proceed through further oxidation and/or hydrolysis reaction pathways, greatly influenced by the acidity of the solution, to yield CO2(g), oxalic acid, formic acid and glycolic acid. Under acidic conditions (e.g., pH 3), the further oxidation pathway will dominate and PCE tends to be directly mineralized into CO2 and chloride. Under neutral (e.g., pH 7) and alkaline conditions (e.g., pH 10), the hydroxylation pathway dominates the reaction and PCE is primarily transformed into oxalic acid prior to complete PCE mineralization. Moreover, all chlorine atoms in PCE are rapidly liberated during the reaction and the rate of chloride production is very close to the rate of PCE degradation.