Automotive Exhaust Emission Levels by Geographic Area and Vehicle Make A Nationwide Survey

Gross average automotive exhaust emissions data collected by the Atlantic Richfield Clean Air Caravan during the summer of 1970 showed only slight geographical variations when the specific makes were ignored. When considering specific makes, significant differences were found on an average emissions basis. Vehicle population—emission distributions showed wide variations in the 50% population levels and in the percent of vehicles with emissions greater than specified values. Hydrocarbon (HC) and carbon monoxide (CO) data are given on a gross basis for the 1970, 1968-69, 1966-67, and pre-1966 model year group vehicles. Average HC and CO emissions and vehicle population-Idle emissions distribution curves are included for specific make vehicles in selected areas.     

Soil and biodiversity

It is shown that the soil diversity-biodiversity system in terrestrial ecosystems operates in spatiotemporal unity, which manifests itself at different hierarchical levels of their structural-functional organization: successional-evolutionary, zonal geographic, landscape, biogeocenotic, soil-type, horizon-layer, geochemical, and the levels of elementary soil processes and soil fertility. Arguments confirming the functional relationship between organisms and soils are considered. Effective biodiversity conservation is possible on the basis of an ecosystems approach involving simultaneous conservation of soil diversity.     

The use of XAD-resins for the detection of mutagenic activity in water: I. Studies with surface water

A study of the effects of different XAD-resins, bed volume, flow rate, pH and type of eluent on the extraction of organic mutagens from surface water is presented. XAD-4/8 is as effective as XAD-2 in concentrating organic mutagens from surface water and dimethylsulfoxide (DMSO) is as efficient as acetone in eluting the adsorbed organic mutagens. The latter allows direct testing up to 0.5 ml of DMSO concentrate in the Ames test. Variation of the pH of the water after passing the XAD-4/8, followed by readsorption, shows that the majority of the mutagenic activity due to dissolved organics is adsorbed at neutral pH. Only a minor fraction is readsorbed at pH 3. Further a XAD-4/8 concentrate and a similar concentrate prepared by freeze drying gives similar mutagenic activity. This indicates that many of the organic mutagens are recovered in the XAD-4/8 concentrate.It is concluded that adsorption on XAD-4/8, followed by direct testing of the DMSO eluates in the Ames test, presents a rapid and relatively simple way to detect low concentrations of organic mutagens in surface water. The general suitability of the method is shown for different types of surface water.     

Assessment of hazards associated with pesticide container disposal and of rinsing procedures as a means of enabling disposal of pesticide containers in sanitary landfills

To study problems associated with pesticide container disposal, a small vegetable production area in southwestern Ontario, the Thedford Marsh, was selected as the site for a model study. A container collection system was organized during the 1981 growing season, with collections being made from the ca. 50 growers on the marsh twice each month. In addition to the regular collection program a cleanup service for empty pesticide containers stored on farms or discarded on public lands also was initiated. More than 3600 containers were collected and disposed of at an authorized landfill site. Ca. 2/3 were herbicide containers, ca. 1/4 were insecticide containers, and 3% were fungicide containers. Unrinsed containers contained as much as 5 1/2% of the original contents with an average of 1%. Containers rinsed by the triple rinse method or using rinsing devices (E-Z Rinse, JET Rinse) generally contained less than 0.1% of the original content. Some formulations presented rinsing problems due to settling and caking. The results indicated that, while unacceptable quantities of pesticide residues remain in unrinsed containers, most rinsed pesticide containers will be acceptable for disposal at municipal sanitary landfill sites.