全文获取类型
收费全文 | 369篇 |
免费 | 1篇 |
国内免费 | 8篇 |
专业分类
安全科学 | 7篇 |
废物处理 | 14篇 |
环保管理 | 30篇 |
综合类 | 105篇 |
基础理论 | 69篇 |
环境理论 | 1篇 |
污染及防治 | 105篇 |
评价与监测 | 25篇 |
社会与环境 | 19篇 |
灾害及防治 | 3篇 |
出版年
2023年 | 7篇 |
2022年 | 4篇 |
2021年 | 18篇 |
2020年 | 10篇 |
2019年 | 6篇 |
2018年 | 17篇 |
2017年 | 17篇 |
2016年 | 18篇 |
2015年 | 13篇 |
2014年 | 16篇 |
2013年 | 29篇 |
2012年 | 26篇 |
2011年 | 29篇 |
2010年 | 11篇 |
2009年 | 18篇 |
2008年 | 17篇 |
2007年 | 25篇 |
2006年 | 23篇 |
2005年 | 9篇 |
2004年 | 15篇 |
2003年 | 13篇 |
2002年 | 3篇 |
2001年 | 6篇 |
2000年 | 2篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1988年 | 1篇 |
1979年 | 1篇 |
1975年 | 1篇 |
1967年 | 1篇 |
1962年 | 1篇 |
1961年 | 2篇 |
1957年 | 2篇 |
1956年 | 2篇 |
1954年 | 1篇 |
排序方式: 共有378条查询结果,搜索用时 31 毫秒
111.
Influence of resorcinol chemical oxidation on the removal of resulting organic carbon by activated carbon adsorption 总被引:1,自引:0,他引:1
Activated carbon adsorption and chemical oxidation followed by activated carbon adsorption of resorcinol in water has been studied. Three chemical oxidants have been used: hypochlorite, permanganate and Fenton's reagent. The influence of concentrations of resorcinol and activated carbon on adsorption removal rates has been investigated. Both isotherm and adsorption kinetics have been studied. Results are fit well by Freundlich isotherms and adsorption rates of resorcinol were found to follow a pseudo-second-order kinetic model. However, pyrogallol, an intermediate of resorcinol oxidation with permanganate and Fenton's reagent, showed an unfavourable isotherm type. At the conditions investigated, chemical oxidation allows slight reductions of TOC and intermediates formed were found to inhibit the adsorption rate of TOC in the case of permanganate and Fenton's reagent oxidation, likely due to formation of some polymer pyrogallol product. The adsorption process was found to be controlled by pore internal diffusion, which justifies the poor affinity of oxidation intermediates toward activated carbon since molecules of larger size should diffuse rapidly for the adsorption to be effective. 相似文献
112.
López E Schuhmacher M Domingo JL 《Environmental science and pollution research international》2008,15(3):278-288
BACKGROUND, AIM AND SCOPE: The volatile organic compounds Benzene, Toluene, Ethylbenzene and Xylene (BTEX) are commonly found in petroleum derivatives and, at relatively high levels, can be associated with human health risks. Due to industrial activities, accidental petroleum spills are the main route of soil and groundwater contamination. The aim of the present study was to evaluate the indoor health risks due to tap water consumption contaminated by BTEX. MATERIALS AND METHODS: BTEX indoor exposure can occur through three principal pathways: inhalation, ingestion and dermal absorption. A multiphase and multicomponent model was used to simulate BTEX transport in groundwater. For evaluation of human risks due to the use of contaminated tap water, a mathematical model was elaborated. RESULTS: BTEX concentrations in a drinking well were obtained as a function over time. These concentrations were used to obtain the exposure due to the use of water from the contaminated drinking well. In addition to showing the highest concentration in water, benzene was the compound that remained for a longer period before being completely degraded. For all the evaluated BTEX, oral ingestion was also the main pathway of exposure for adults, whereas the contribution of inhalation and oral exposition in children were seen to be of the same magnitude. The sensitivity analysis of BTEX total dose for adults showed that direct ingestion was the most significant factor, followed by shower time, volume of the shower room, inhalation rate, and shower flow rate. For children, the most significant variable was also direct ingestion, followed by shower time, volume of the shower room, and body weight. DISCUSSION: In the current design situation, there would not be any health risks by the use of BTEX-contaminated water to the general population living in the neighborhood of the petroleum spill. Therefore, no remediation measures in the area of the spill would be necessary. CONCLUSIONS: The present results indicate that the design of a good scenario can perform an accuracy risk assessment. This model can serve as a useful tool for predicting indoor exposure to substances for which no direct data are available, reducing monitoring efforts and observing how different processes affect outcomes. RECOMMENDATIONS AND PERSPECTIVES: These preliminary data allow the establishment of a basis for further investigations focusing on efficiently recovering petroleum from contaminated sites. 相似文献
113.
114.
115.
Hu J Eriksson L Bergman A Jakobsson E Kolehmainen E Knuutinen J Suontamo R Wei X 《Chemosphere》2005,59(7):1043-1057
Polybrominated diphenyl ethers (PBDEs) are widely used as flame retardants and are increasingly turning up in the environment. Their structural similarities to polychlorinated biphenyls and thyroid hormones suggest they may be a risk to human health. The present study examines the reactivity of brominated diphenyl ethers (BDEs) on the basis of the electronic structures as calculated by semiempirical AM1 self-consistent field molecular orbital (SCF-MO) method. Frontier orbital energies were used to elucidate the reactivity of BDEs in electrophilic, nucleophilic and photolytic reactions. From an examination of the frontier electron densities, the regioselectivity, or orientation, of metabolic reactions of BDEs was predicted. Furthermore, satisfactory quantitative structure-activity (property) relationship (QSAR and QSPR) models were derived to calculate gas chromatographic and ultraviolet spectral properties and luciferase induction activities from the AM1-computed electronic parameters. 相似文献
116.
Eva Linden B-E Bengtsson O Svanberg G Sundstrm National Swedish Environment Protection Board 《Chemosphere》1979,8(11-12)
The toxicity of 78 chemicals and pesticide formulations against the bleak, Alburnus alburnus (Pisces) and the harpacticoid Nitocra spinipes has been tested. The results are expressed as the 96 hr LC(I) 50 i.e. the initial concentration of a substance killing 50 per cent of the test organisms during 96 hours. Among the compounds tested are inorganic and organic compounds (metal salts, solvents and a few more complex compounds such as organotin compounds), pesticide formulations and other industrial chemicals (PCB-substitutes, phthalic acid esters and polychlorinated paraffins). 相似文献
117.
118.
Investigation of the Aerobic Biodegradability of Several Types of Cyclodextrins in a Laboratory-Controlled Composting Test 总被引:1,自引:0,他引:1
Steven Verstichel Bruno De Wilde Eva Fenyvesi József Szejtli 《Journal of Polymers and the Environment》2004,12(2):47-55
The biodegradation of several types of cyclodextrins (CDs) under laboratory-controlled composting conditions was investigated. CDs are used in a broad range of applications in food, pharmaceutical, medical, chemical, and textile industries because of their specific chemical characteristics related to their hydrophobic interior and hydrophilic exterior. The three naturally occurring cyclodextrins -CD, -CD, and -CD proved to be completely and readily biodegradable. Chemical modification of these basic compounds can have a major impact on the biodegradation rate and final biodegradation percentage. Fully acetylated -CD and -CD were found to be nonbiodegradable during 45 days of composting. Reducing the degree of acetylation had a positive effect on the biodegradation. Complete biodegradation was obtained for partially acetylated -CD with a degree of substitution (DS) of 7. The methylation (DS = 13) of -CD resulted in an undegradable compound during the 47 days composting, while (2-hydroxy)propyl--CD reached a plateau in biodegradation at a percentage of 20%. The incorporation of the antimicrobial agents imazalil and allyl-isothiocyanate into -CD had no negative impact on biodegradation, which makes these antimicrobial agents/CD complexes suitable for incorporation into biodegradable active packaging. 相似文献
119.
Christian Pansch Ivan Gómez Eva Rothäusler Karina Veliz Martin Thiel 《Marine Biology》2008,155(1):51-62
Chemical defense is assumed to be costly and therefore algae should allocate defense investments in a way to reduce costs
and optimize their overall fitness. Thus, lifetime expectation of particular tissues and their contribution to the fitness
of the alga may affect defense allocation. Two brown algae common to the SE Pacific coasts, Lessonia nigrescens Bory and Macrocystis integrifolia Bory, feature important ontogenetic differences in the development of reproductive structures; in L. nigrescens blade tissues pass from a vegetative stage to a reproductive stage, while in M. integrifolia reproductive and vegetative functions are spatially separated on different blades. We hypothesized that vegetative blades
of L. nigrescens with important future functions are more (or equally) defended than reproductive blades, whereas in M. integrifolia defense should be mainly allocated to reproductive blades (sporophylls), which are considered to make a higher contribution
to fitness. Herein, within-plant variation in susceptibility of reproductive and vegetative tissues to herbivory and in allocation
of phlorotannins (phenolics) and N-compounds was compared. The results show that phlorotannin and N-concentrations were higher
in reproductive blade tissues for both investigated algae. However, preferences by amphipod grazers (Parhyalella penai) for either tissue type differed between the two algal species. Fresh reproductive tissue of L. nigrescens was more consumed than vegetative tissue, while the reverse was found in M. integrifolia, thus confirming the original hypothesis. This suggests that future fitness function might indeed be a useful predictor of
anti-herbivore defense in large, perennial kelps. Results from feeding assays with artificial pellets that were made with
air-dried material and extract-treated Ulva powder indicated that defenses in live algae are probably not based on chemicals that can be extracted or remain intact after
air-drying and grinding up algal tissues. Instead, anti-herbivore defense against amphipod mesograzers seems to depend on
structural traits of living algae. 相似文献
120.
Despite widespread recognition that intersexual interactions shape reproductive strategies, studies of male competition do
not typically include effects imposed by females. In cannibalistic redback spiders, escalated fighting between rival suitors
is predicted, as males are unlikely to mate with more than one female, and strong first-male sperm precedence favours mating
with virgins. In staged competitions for matings between size mismatched rivals, smaller males adopted an alternative sneaking
strategy. However, despite initial agonistic interactions, larger males did not pursue or incapacitate smaller males. When
inter-male competition occurred, females struck at males frequently, although strikes were rarely seen when males courted
in the absence of a rival. After minimal fighting, larger males engaged in significant courtship (3 h) rather than killing
inferior rivals. Prolonged courtship was favoured by female behaviour, as males that attempted rapid copulation (smaller,
sneaking males) were cannibalised before mating was completed. This premature cannibalism significantly decreases paternity
in redback spiders. Thus, significant features of male competitive behaviour (i.e. prolonged courtship by larger males) may
be predicted with consideration of the female’s response to male reproductive strategies. Although the effect of females may
be more subtle in systems without the extreme reversed size-dimorphism of redbacks, these results suggest that female interests
should be explicitly considered when studying inter-male interactions. 相似文献