全文获取类型
收费全文 | 11334篇 |
免费 | 79篇 |
国内免费 | 83篇 |
专业分类
安全科学 | 283篇 |
废物处理 | 500篇 |
环保管理 | 1431篇 |
综合类 | 2460篇 |
基础理论 | 2563篇 |
环境理论 | 5篇 |
污染及防治 | 2952篇 |
评价与监测 | 684篇 |
社会与环境 | 563篇 |
灾害及防治 | 55篇 |
出版年
2022年 | 91篇 |
2021年 | 96篇 |
2019年 | 69篇 |
2018年 | 149篇 |
2017年 | 130篇 |
2016年 | 224篇 |
2015年 | 172篇 |
2014年 | 243篇 |
2013年 | 820篇 |
2012年 | 304篇 |
2011年 | 429篇 |
2010年 | 337篇 |
2009年 | 395篇 |
2008年 | 428篇 |
2007年 | 491篇 |
2006年 | 430篇 |
2005年 | 352篇 |
2004年 | 367篇 |
2003年 | 373篇 |
2002年 | 332篇 |
2001年 | 428篇 |
2000年 | 312篇 |
1999年 | 205篇 |
1998年 | 115篇 |
1997年 | 123篇 |
1996年 | 108篇 |
1995年 | 154篇 |
1994年 | 148篇 |
1993年 | 123篇 |
1992年 | 130篇 |
1991年 | 150篇 |
1990年 | 119篇 |
1989年 | 127篇 |
1988年 | 132篇 |
1987年 | 114篇 |
1986年 | 85篇 |
1985年 | 101篇 |
1984年 | 124篇 |
1983年 | 125篇 |
1982年 | 124篇 |
1981年 | 97篇 |
1980年 | 93篇 |
1979年 | 107篇 |
1978年 | 89篇 |
1977年 | 84篇 |
1976年 | 78篇 |
1975年 | 90篇 |
1974年 | 101篇 |
1972年 | 69篇 |
1965年 | 74篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
941.
Iron and steel manufacture has been ranked as the largest industrial source of environmental contamination in the USA; the wastes generated in their production processes contain heavy elements that can be a source of contamination, and natural radionuclides that can produce an occupational and/or public radiological impact. In this work the potential occupational effective dose rate (μSv/y) due to inhalation in four integrated steel-making factories from Egypt has been evaluated, by assuming a well defined scenario and with basis in the 210Pb and 210Po activity concentrations determined in ore and wastes collected in the aforementioned factories. Activity concentrations, in Bq/kg, of 210Pb and 210Po, and leachable Pb and Fe were measured using gamma-ray spectrometry based on HPGe detector, alpha particle spectrometry based on PIPS detector, and inductively coupled plasma-mass spectrometry (ICP-MS). Levels of 210Pb and 210Po in the range of <DL-4238 and 1-5660 Bq/kg, respectively, were found. According to the assumed scenarios, the occupational exposures by inhalation are much lower than the recommended annual effective dose limit, although the environmental impact due to waste storage and/or use should be considered based on case by case evaluation. 相似文献
942.
This study was conducted to identify the principle selenate carrier phases for two selected soils, by comparing their reactivity with selenate to that of pure phases of the solids. Silica, calcium carbonate, aluminium hydroxide, goethite, bentonite and humic acid were selected as the main soil carrier phases. Comparisons were made first on the parameter values obtained with the best fit of a kinetic sorption model which can discriminate instantaneous sorption from kinetically limited sorption. Then comparisons were made of the ability for each solid to stabilise selenate by measuring the ratio of the partition coefficient for sorption (Kdsorption) over that of the desorption (Kddesorption). Kinetics and stabilisation were used to help elucidate the nature of interactions with the test solid phases for a large range of selenate concentrations. The experiments were conducted over 165 h in batch reactors, the solid being isolated from the solution by dialysis tubing, at two pH (5.4 and 8) and three selenate concentrations (1 × 10−3, 1 × 10−6 and 1 × 10−8 mol L−1). The results obtained showed that only aluminium hydroxide can sorb selenate throughout the studied pH range (pH 5.4 to 8.0). The sorption capacity on this mineral was high (Kdsorption > 100 to 1 × 104 L kg−1) and the selenate was mainly stabilized by the formation of inner sphere complexes. The sorption on goethite occurred at pH 5.4 (Kdsorption 52 L kg−1), mainly as outer sphere complexes, and was null at pH 8. On silica, a weak sorption was observed only at pH 5.4 and at 165 h (Kdsorption 4 L kg−1). On bentonite, calcium carbonate and humic acid no significant sorption was observed. Concerning the two soils studied, different behaviours were observed for selenate. For soil Ro (pH 5.4), Kdsorption was low (8 L kg−1) compared to soil Bu (pH 8) (70 L kg−1). The sorption behaviour of selenate on soil Ro was mainly due to outer sphere complexes, as for goethite, whereas for soil Bu the sorption was mainly attributed to inner sphere complexes followed by reduction mechanisms, probably initiated by microorganisms, in which no steady state was reached at the end of the 165 h experiments. The sorption of selenate decreased when concentrations reached 1 × 10−3 mol L−1, due to solid saturation, except for aluminium hydroxide. Reduction of selenate seemed also to occur on goethite and soil Ro, for the same concentration, but without preventing a decrease in sorption. Thus, this work shows that the comparison of selenate behaviour between soil and pure phases helps to elucidate the main carrier phases and sorption mechanisms in soil. 相似文献
943.
Herranz M Romero LM Idoeta R Olondo C Valiño F Legarda F 《Journal of environmental radioactivity》2011,102(11):987-994
In this paper the inventory of 90Sr in 34 points distributed along the Spanish peninsular territory is presented. Obtained values range between 173 Bq/m2 and 2047 Bq/m2. From these data set and those 137Cs data obtained in a previous work the 137Cs/90Sr activity ratio has been established, laying this value between 0.9 and 3.6. Also the migration depth of both radionuclides has been analysed obtaining for 137Cs an average value 57% lower than that obtained for 90Sr.Additionally, this paper presents the results obtained in 11 sampling points in which the activity vertical profile has been measured. These profiles have been analysed to state the behaviour of strontium in soils and after, by using a convective-diffusive model, the parameters of the model which governs the vertical migration of 90Sr in the soil, v (apparent convection velocity) and D (apparent diffusion coefficient) have been evaluated. Mean values obtained are 0.20 cm/year and 3.67 cm2/year, respectively. 相似文献
944.
Petreas M Nelson D Brown FR Goldberg D Hurley S Reynolds P 《Environment international》2011,37(1):190-197
We measured major PBDEs and PCBs in breast adipose tissues of California women participating in a breast cancer study in the late 1990s. Samples were analyzed using gas chromatography with electron impact ionization and tandem mass spectrometry detection. The congener profile observed was: BDE47>BDE99>BDE153>BDE100>BDE154 and PCB153>PCB180>PCB138>PCB118. Whereas high correlations were observed within each chemical class, very weak correlations appeared between classes, pointing to different exposure pathways. Weak negative associations were observed for PBDE congeners and age. Our PBDE data are among the highest reported, exceeding data from the National Health and Nutrition Examination Survey and consistent with the high use of PBDEs in California. These data may be helpful in establishing a baseline for PBDE body burdens to gauge changes over time as a result of restrictions in the use of PBDE formulations. 相似文献
945.
The Syracuse, NY, AUDIT (Assessment of Urban Dwellings for Indoor Toxics) study was designed to quantify asthma agent levels in the inner-city homes of a birth cohort whose mothers had a diagnosis of asthma. Risk of exposure to particulate matter (PM), particle number and tobacco smoke was assessed in 103 infants' homes. Repeat measurements were made in 44% of the homes. Infants also were examined on a quarterly basis during the first year of life to monitor their respiratory health and urine cotinine levels. Overall geometric mean (GM) values for PM(2.5) of 21.2 μg/m(3) and for PM(10) of 31.8 μg/m(3) were recorded in homes at visit 1. GM values for PM(2.5) and PM(10) in smoking homes were higher at 26.3 and 37.7 μg/m(3), while values in non-smoking homes were 12.7 and 21.2 μg/m(3) respectively. Fifty-four percent of mothers (55/103) smoked at some point in pregnancy (39% smoked throughout pregnancy). Environmental tobacco smoke (ETS) exposure occurred in 68% of homes during the infants' first year. Significant to this study was the size- and time-resolved monitoring of PM at 140 home visits and the classification of PM count data. PM number counts ranged from continuously low levels (little indoor activity) to continuously high counts (constant indoor activity), and recorded apparent instances of prolonged repeated cigarette smoking. Wheezing in the first year of life was recorded for 38% of the infants (39/103). Adjusted logistic regression modeling demonstrated that elevated levels of indoor PM(2.5) (≥ 15 μg/m(3)) were a significant risk factor for infant wheezing after controlling for infant gender, mothers' age and education level, season of home visit and presence of carpeting (OR 4.21; 95% CI 1.36-13.03; p=0.013). An elevated level of the nicotine metabolite cotinine in infant urine also was associated with infant wheezing after adjusting for infant gender, mothers' age and education level (OR 5.10; 95% CI 0.96-27.24; p=0.057). ETS exposure was pervasive in the AUDIT cohort and a risk for developing infants in this urban population. 相似文献
946.
de Nazelle A Nieuwenhuijsen MJ Antó JM Brauer M Briggs D Braun-Fahrlander C Cavill N Cooper AR Desqueyroux H Fruin S Hoek G Panis LI Janssen N Jerrett M Joffe M Andersen ZJ van Kempen E Kingham S Kubesch N Leyden KM Marshall JD Matamala J Mellios G Mendez M Nassif H Ogilvie D Peiró R Pérez K Rabl A Ragettli M Rodríguez D Rojas D Ruiz P Sallis JF Terwoert J Toussaint JF Tuomisto J Zuurbier M Lebret E 《Environment international》2011,37(4):766-777
947.
Ligero RA Feria F Casas-Ruiz M Corredor C 《Journal of environmental radioactivity》2006,87(3):325-334
The potential radiological impact of the increase of radioactive substances in the environment makes interesting the study of the migration of the contaminant radionuclides in soils and sediments, which are the last receiver system of these substances. By using a battery of sedimentary columns controlled in the laboratory, the diffusion of the (226)Ra and (40)K radionuclides has been studied, assessing their respective effective diffusion coefficients in a similar sedimentary medium. A decreasing temporal evolution is obtained, associated to the progressive 'fixation' of the radionuclides by the clay minerals of the sediment, followed by a constant tendency. A timescale of the 'fixation' by the sediment is determined, being of the order of days for (226)Ra and of the order of months for (40)K, so the progressive 'fixation' of (40)K by the clay minerals of the sediments is slower than in the case of (226)Ra. 相似文献
948.
A method by inductively coupled plasma mass spectrometry (ICP-MS) was developed which allows the measurement of (236)U at concentration ranges down to 3 x 10(-14)g g(-1) and extremely low (236)U/(238)U isotope ratios in soil samples of 10(-7). By using the high-efficiency solution introduction system APEX in connection with a sector-field ICP-MS a sensitivity of more than 5,000 counts fg(-1) uranium was achieved. The use of an aerosol desolvating unit reduced the formation rate of uranium hydride ions UH(+)/U(+) down to a level of 10(-6). An abundance sensitivity of 3 x 10(-7) was observed for (236)U/(238)U isotope ratio measurements at mass resolution 4000. The detection limit for (236)U and the lowest detectable (236)U/(238)U isotope ratio were improved by more than two orders of magnitude compared with corresponding values by alpha spectrometry. Determination of uranium in soil samples collected in the vicinity of Chernobyl nuclear power plant (NPP) resulted in that the (236)U/(238)U isotope ratio is a much more sensitive and accurate marker for environmental contamination by spent uranium in comparison to the (235)U/(238)U isotope ratio. The ICP-MS technique allowed for the first time detection of irradiated uranium in soil samples even at distances more than 200 km to the north of Chernobyl NPP (Mogilev region). The concentration of (236)U in the upper 0-10 cm soil layers varied from 2 x 10(-9)g g(-1) within radioactive spots close to the Chernobyl NPP to 3 x 10(-13)g g(-1) on a sampling site located by >200 km from Chernobyl. 相似文献
949.
Di Bella G Licata P Bruzzese A Naccari C Trombetta D Lo Turco V Dugo G Richetti A Naccari F 《Environment international》2006,32(6):705-710
The aim of this study is to assess the accumulation of OCs and PCBs in Thunnus thynnus and to elucidate the suitability of this species as a bioindicator for monitoring contaminations of these compounds in the marine ecosystems of the Straits of Messina. This investigation was conducted on fat, liver and muscle samples of 14 T. thynnus collected during April 2004. Quantitative determination of OCs and PCBs in the various samples examined has been carried out using GC-ECD and GC-MS. The results obtained show the presence of low concentrations of p,p'-DDE and PCB congeners (138, 153 and 180) in all fat, liver and muscle samples caught in the Straits of Messina. Concentrations of p,p'-DDE and PCB congeners (138, 153 and 180) in all the samples examined were below MRLs (CE n. 97/41, 1999/65 and 1999/71). 相似文献
950.
A dynamic model for assessing the transfer of tritium in a food chain was applied to the Loire River, where 14 nuclear power plants situated on five different sites operate. The model considers several potential exposure pathways in the aquatic and terrestrial ecosystems: transfer of tritium through the aquatic food chain (especially fish); use of river water for agricultural purposes (irrigation) and transfer of radionuclides through the terrestrial food chain (vegetables, meat, milk); subsequent internal exposure of humans due to ingestion of contaminated foodstuffs. For biological environmental compartments, the transfer of tritium to organic matter (i.e. OBT) was simulated. For each of the parameters introduced in this model, a probability density function, allowing further uncertainty and sensitivity analyses, was proposed. Uncertainty/sensitivity analyses were performed to determine a confidence interval for the mean annual dose to critical groups and to identify the parameters responsible for the uncertainty and subsequent research priorities. 相似文献