全文获取类型
收费全文 | 1509篇 |
免费 | 107篇 |
国内免费 | 407篇 |
专业分类
安全科学 | 102篇 |
废物处理 | 82篇 |
环保管理 | 145篇 |
综合类 | 848篇 |
基础理论 | 281篇 |
污染及防治 | 400篇 |
评价与监测 | 59篇 |
社会与环境 | 58篇 |
灾害及防治 | 48篇 |
出版年
2023年 | 11篇 |
2022年 | 73篇 |
2021年 | 58篇 |
2020年 | 61篇 |
2019年 | 51篇 |
2018年 | 53篇 |
2017年 | 50篇 |
2016年 | 59篇 |
2015年 | 67篇 |
2014年 | 99篇 |
2013年 | 126篇 |
2012年 | 145篇 |
2011年 | 139篇 |
2010年 | 98篇 |
2009年 | 97篇 |
2008年 | 121篇 |
2007年 | 106篇 |
2006年 | 88篇 |
2005年 | 67篇 |
2004年 | 70篇 |
2003年 | 60篇 |
2002年 | 50篇 |
2001年 | 35篇 |
2000年 | 34篇 |
1999年 | 30篇 |
1998年 | 18篇 |
1997年 | 23篇 |
1996年 | 36篇 |
1995年 | 30篇 |
1994年 | 21篇 |
1993年 | 14篇 |
1992年 | 8篇 |
1991年 | 9篇 |
1990年 | 8篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有2023条查询结果,搜索用时 171 毫秒
551.
采用以农业废弃物核桃壳为原料,天然软锰矿为添加剂共混制成的新型柱状活性炭进行了不同水蒸气含量下的烟气脱硫实验,利用Bangham和Elovich 2种模型对实验结果进行模拟与比较。实验结果表明,随着水蒸气含量的增加,穿透硫容和时间逐渐增加,并在水蒸气含量为10%时达到最大点,此时硫容为243.0 mg/g。模拟结果表明,2种模型均可以较好地模拟烟气脱硫实验结果,其中Elovich模型具有更高的拟合相关度和准确性。在对Elovich模型加以改进以包含水蒸气影响后,可以更好地描述烟气在不同水蒸气含量下的新型柱状活性炭脱硫情况。 相似文献
552.
分别采用低浓度和高浓度剩余污泥对剩余污泥中微生物絮凝剂(MBF)的多种提取方法(超声法、树脂法、超声-树脂法、树脂-超声法、超声-树脂-超声法和树脂-超声-树脂法等)进行了比较研究.结果表明,各种复合形式的提取效果均优于超声法或树脂法单独使用的提取效果.在各种复合形式中,以树脂-超声法所提取MBF的含量最高且絮凝效果最好.此外,所提取的MBF浓度与污泥浓度正相关.从剩余污泥中直接提取MBF,在降低MBF生产成本的同时实现了污泥的资源化利用. 相似文献
553.
Fan Li Yue Zhan Dandan Liu Dongbo Liu Hongmei Xia Shan Chen 《Journal of Polymers and the Environment》2013,21(4):1143-1149
The fermentation conditions for poly(l-lactide) (PLA)-degrading enzyme production by Amycolatopsis orientalis ssp. orientalis were statistically optimized by response surface methodology. The optimal value of the most important factors was 0.39 % PLA and 0.34 % gelatin for 2.81 days of cultivation. Under these conditions, the model predicted a PLA-degrading activity of 155.30 U/l. The verification showed the production amount of 154.2 U/l. The crude enzyme from A. orientalis ssp. orientalis showed potent PLA-degrading ability, which is efficient for the biological recycling of PLA. Up to 4,000 mg/l of PLA granule was completely degraded within 5 days at 45 °C by the crude enzyme. l-lactic acid (600 mg/l) was obtained as a degradation product of PLA after only 2 h of incubation. The results indicated that the crude PLA-degrading enzyme from A. orientalis ssp. orientalis has the potential to degrade PLA to lactic acid for the recycling of PLA industry and waste disposal. 相似文献
554.
ALAD genotypes and blood lead levels of neonates and children from e-waste exposure in Guiyu,China 总被引:1,自引:0,他引:1
Xia Huo Lin Peng Bo Qiu Liangkai Zheng Taofeek Akangbe Yekeen Xijin Xu 《Environmental science and pollution research international》2014,21(10):6744-6750
Extensive e-waste recycling activity in Guiyu, China, has been conducted using primitive techniques for the last 20 years, resulting in serious heavy metal environmental contamination. A polymorphic variant of the δ-aminolevulinic acid dehydratase (ALAD) gene has been found to influence lead uptake and, thus, may influence an individual’s susceptibility to lead toxicity. We therefore explored whether the ALAD gene polymorphism affects blood lead levels of newborns and children in Guiyu. A total of 273 newborns and 504 children, and a combination of 2004/2005 and 2006 independent recruitments were used for this study. Umbilical cord blood from newborns (Guiyu/exposed group 189 vs. Chaonan/reference group 84) and venous blood from children (exposed group, 319 vs. Chendian/reference group 185) were collected. Blood lead levels (BLLs) were measured via graphite furnace atomic absorption spectrometry (GFAAS) for all samples, while ALAD genotyping was performed using PCR-RFLP for 273 neonate cord blood and 246 children’s blood. The median BBLs of neonates in exposed group vs. the reference group were 10.50 (2.36–40.78) vs. 7.79 (0.8–19.51) for 2004/2005 and 9.41 (9.28–47.60) vs. 5.49 (0.35–18.68) for 2006, while child mean BLLs were 15.31?±?5.79 vs. 9.94?±?4.05 for 2004/2005 and 13.17?±?5.98 vs. 10.04?±?4.85 for 2006. The genotype frequencies in newborns were 98.90 % for the ALAD-1/ALAD-1 homozygote and 1.10 % for the ALAD-1/ALAD-2 heterozygotes, while the values were 95.93 and 4.07 %, respectively, in children. The allele frequencies of the ALAD-1 and ALAD-2 were 99.45 and 0.55 % for newborns, but 97.97 and 2.03 % for children, respectively. No significant differences in blood lead levels were found between ALAD-1/ALAD-1 and ALAD-1/ALAD-2 either in newborns or in children. The frequency distribution of the ALAD-2 allele in newborns from the exposed group was lower than that of the reference group. There were no significant differences, between the two different ALAD genotypes in the lead load of newborns and children. The frequency distribution of ALAD gene does not influence the blood lead levels of newborns and children in this case, which means that the higher lead burden in the exposed children was possibly influenced by e-waste recycling, but not ALAD genotypes. 相似文献
555.
Xiang Tan Xiaoling Xia Qiaoling Zhao Quanfa Zhang 《Environmental science and pollution research international》2014,21(1):434-444
Benthic diatoms are the main component in many aquatic ecosystems such as streams, creeks and rivers, and they function as important primary producers and chemical modulators for other organisms in the ecosystems. In this study, the composition of benthic diatoms was investigated and further explored the primary physicals and chemicals affecting their temporal variations in the upper Han River, China. There were seasonal variations in physical and chemical variables in waters over the sampling period of 2007–2010. Water temperature (t), chemical oxygen demand, total nitrogen, dissolved organic carbon (DOC), silica and fluoride were much higher in the high flow season (i.e., July or August) than these in the base flow season. Three species Achnanthidium minutissimum (composed of 10.7 % of the total diatom abundance), Achnanthidium pyrenaicum (11.9 %), and Achnanthidium subatomus (12.7 %) accounting for more than 5 % of the total diatom abundance were persistently dominant in all seasons, while the other two prostrate and motile species including Eolimna minima and Nitzschia dissipata also dominant in the base flow season. The species richness always peaked in autumn with significant difference with summer (p?<?0.01), and density of benthic diatom varied and peaked in April. Analyses indicated that the temporal variation in benthic diatom communities was strongly related to t, nitrogen, organic pollutants (indicated by COD and DOC), and hydrological regime. The research will expand the understanding of water chemistry monitoring, and improve watershed- scale management and conservation efforts in the upper Han River, China. 相似文献
556.
One of the chemical breakdown products of nonylphenol ethoxylates, 4-nonylphenol (4-NP), accumulates in organisms and is of concern as an environmental pollutant due to its endocrine disrupting effects. We measured 4-NP levels in the seawater, sediment, and twelve organisms within the California estuary, Morro Bay, and examined biomagnification of 4-NP using stable isotope abundances (δ15N and δ13C) to quantify trophic position. 4-NP concentrations in organisms from Morro Bay included 25000 ± 8600 ng g−1 lw in liver of California sea lion, 14000 ± 5600 ng g−1 lw in liver of harbor porpoise, 138000 ± 55000 ng g−1 lw in liver of sea otters, 15700 ± 3600 ng g−1 lw in liver of seabirds, 36100 ± 6100 ng g−1 lw in arrow goby fish, 62800 ± 28400 ng g−1 lw in oysters, and 12700 ± 1300 ng g−1 lw in mussels. 4-NP levels generally showed a pattern of trophic dilution among organisms in Morro Bay, with exceptions of biomagnification observed between three trophic links: mussel to sea otter (BMF 10.9), oyster to sea otter (BMF 2.2), and arrow goby to staghorn sculpin (BMF 2.7). Our examination of other west coast estuaries of USA and Canada revealed that mean 4-NP concentrations in gobies and mussels from Morro Bay were significantly higher than those from a more urbanized estuary, San Francisco Bay (goby: 11100 ± 3800 ng g−1 lw) and from a remote estuary, Bamfield Inlet, Canada (goby: 9000 ± 900 ng g−1 lw, mussel: 6100 ± 700 ng g−1 lw). Relative to other estuaries worldwide, 4-NP levels in seawater (0.42 ± 0.16 μg L−1) and sediment (53 ± 14 ng g−1 dw) of Morro Bay are low, but gobies and oysters have higher 4-NP levels than comparable fauna. 相似文献
557.
558.
不同混合比牛粪玉米秸中温干发酵产沼性能 总被引:4,自引:1,他引:3
设置5组牛粪和玉米秸的混合物(干物质比为0∶1、1∶0、1∶1、1∶2、2∶1),研究其在中温35℃下干发酵产沼性能,以产沼性能最好实验组的实验数据为基础,对比研究了两类产气模型。研究结果显示:玉米秸与牛粪的混合干发酵运行效果较好;其中,牛粪和玉米秸干物质比为2∶1时产沼效果最好,产气量最高为81 209 mL,干物质产气率为0.312 m3/kg,整个发酵过程中产气量和甲烷的含量比较稳定,CH4含量最高达56.59%,总固体、挥发性固体的去除率相对较高,分别为26.11%和34.27%。一级动力学模型与多项式函数方程2个产气模型拟合检验结果显示,应用简单的多项式函数即可对产气情况进行相对准确的预测。 相似文献
559.
Pt and Pd in sediments from the Pearl River Estuary,South China: background levels,distribution, and source 总被引:1,自引:0,他引:1
Zhong LF Yan W Li J Tu XL Liu BM Xia Z 《Environmental science and pollution research international》2012,19(4):1305-1314
Purpose
This study assessed the concentrations of platinum (Pt) and palladium (Pd) in surface sediments and sedimentary cores collected from the Pearl River Estuary with a view of evaluating the distribution, background levels, possible sources, and contamination level of anthropogenic Pt and Pd. 相似文献560.
生物絮凝剂产生菌群发酵特性及动力学 总被引:2,自引:0,他引:2
从土壤中分离、筛选得到2株具有协同发酵的微生物絮凝剂产生菌。通过单因素实验考察了碳源、氮源、不同C/N等多种发酵条件对复合菌株产絮的影响,并对复合菌株的生长动力学进行了研究。当碳源为蔗糖、氮源为草酸铵、C/N为30∶1,pH=7.0、在30℃,160 r/min的摇床速度下培养24 h,其发酵液对4 g/L的高岭土的悬浊液的絮凝率达到99.3%。根据Logistic方程,得到复合型生物絮凝剂产生菌群的生长动力学模型与实验数据能较好地拟合,基本反映了复合菌群生长的动力学特征。 相似文献