Evaluation of the Effect of Chemical or Enzymatic Synthesis Methods on Biodegradability of Polyesters

This work compares the biodegradability of polyesters produced by an esterification reaction between glycerol and oleic di-acid (D 18:1) issued from green chemical pathways, via either classical thermo-chemical methods, or an enzymatic method using the immobilized lipase of Candida antartica B (Novozym 435). An elastomeric polymer synthesized by enzymatic catalysis is more biodegradable than an elastomeric thermo-chemical polyester synthesized by a standard chemical procedure. This difference lies in percentage of the dendritic motifs, in values of the degree of substitution, and certainly in cross-links inducing an hyper-branched structure less accessible to the lipolytic enzymes in a waste treatment plant. However, when the elastomeric polymer synthesized by enzymatic catalysis is processed at high temperature as required for certain industrial applications, it presents an identical rate of biodegradation than the chemical polyester. The advantages of the thermo-chemical methods are greater speed and lower cost. Enzymatic synthesis appears be suited to producing polyesters, devoid of metallic catalysts, which must be used without processing at high temperature to keep a high biodegradability.     

Technology improvements and value changes for sustainable happiness: a cross-development analytical model

This paper develops an analytical model to calculate the amount by which individuals are expected to modify their values (the relationship between lifestyle and happiness, as measured by subjective well-being, SWB) and to adopt innovative technologies (to increase the sustainability of production and consumption, measured by the ecological footprint, EF) to allow current and future generations to achieve sustainable happiness (the pursuit of happiness that does not exploit other people, the environment, or future generations). The paper also examines the dependence of these changes on an individual’s concern for future generations and on their country’s current state of economic development. It is shown that individuals in better-off developed countries and individuals in worse-off developing countries can achieve sustainability with a reasonable level of value change (0–30 %) and a feasible degree of technological innovation (10–40 %), respectively. In contrast, individuals in better-off developing countries and individuals in worse-off developed countries must rely to an impractical degree of technological innovation (50–70 %) and to an unreasonable level of value change (40–70 %), respectively. Finally, individuals in developing countries differ from individuals in developed countries in terms of their potential to achieve sustainable happiness, by achieving sustainability at a low SWB (about 10 % of its maximum) and a high SWB (about 80 % of its maximum), respectively.     

Study of the spontaneous ignition of stoichiometric tetrafluoroethylene–air mixtures at elevated pressures

The Ignition Temperature (IT) of stoichiometric tetrafluoroethylene–air mixtures on hot walls was determined in a 3-dm³-reactor. Tests at elevated pressure conditions were performed, namely at 5, 15 and 25 bar(a), showing a decrease of the IT with the initial pressure. Furthermore, the measured ignition temperatures of stoichiometric tetrafluoroethylene–air mixtures were lower than the ignition temperatures required for the decomposition pure tetrafluoroethylene (Minimum Ignition Temperature of Decomposition, MITD) reported in previous works.Equations from the Semenov thermal explosion theory on spontaneous ignition were used to identify approximate combustion kinetics of tetrafluoroethylene from the experimental results. The determined kinetics was used for the prediction of the IT of stoichiometric tetrafluoroethylene-air by simplified calculation methods. A very good agreement with the experimental results was observed.     

Characterization of municipal solid waste temporary storage sites: Risks posed to surrounding areas as a consequence of fire incidents

In this study temporary storage sites of municipal solid waste were characterized based on their potential social, health and environmental impacts as a consequence of spontaneous fires, by employing Boolean as well as weighted-linear-combination approaches in connection with various fuzzy set functions of population density around the storage sites. Sweden was used as the case study and data from 105 storage sites were analysed; of these, 38 were identified to be posing high risk for downwind residing population. Furthermore, during the past 10 years, the fire frequency and the average population residing within a radius of 1, 2, and 3 km were found to be comparatively higher for storage sites owned by private companies than for those owned by municipalities. The study provided first-cut information of poorly sited temporary storage sites and can help in formalizing the comprehensive risk analysis in the future.     

Traffic Parameters Estimation to Predict Road Side Pollutant Concentrations using Neural Networks

The analysis aims to evaluate which is the most important among traffic parameters (flows, queues length, occupancy degree, and travel time) to forecast CO and C₆H₆ concentrations. The study area was identified by Notarbartolo Road and bounded by Libertà Street and Sciuti Street in the urban area of Palermo in Southern Italy. In this area, various loop detectors and one pollution-monitoring site were located. Traffic data related to the pollution-monitoring site immediately near the road link were estimated by Simulation of Urban MObility (SUMO) traffic microsimulator software using as input the flows measured by loop detectors on other links of road network. Traffic and weather data were used as input variables to predict pollutant concentrations by using neural networks. Finally, after a sensitivity analysis, it was showed that queues length were the mostly correlated traffic parameters to pollutant concentrations. An erratum to this article can be found at     

Embryo/larval toxicity and transcriptional effects in zebrafish (Danio rerio) exposed to endocrine active riverbed sediments

Environmental Science and Pollution Research - Sediment toxicity plays a fundamental role in the health of inland fish communities; however, the assessment of the hazard potential of contaminated...     

Relevant organic components in ambient particulate matter collected at Svalbard Islands (Norway)

n-Alkanes, polynuclear aromatic hydrocarbons and n-alkanoic acids present in the inhalable fraction of airborne particles have been determined at the Italian scientific base sited in the area of Ny Alesund, Spitzbergen Island, Norway. Both the profiles of n-alkane and polynuclear aromatic congeners among the respective classes showed that anthropogenic sources were responsible for the presence of particulate organics in the atmosphere there, since the monomodal distribution of aliphatics and the fresh-emission shape of PAH fraction were observed. The total contents of n-alkanes and PAH ranged from 19 to 97 ng m⁻³ and from 0.6 to 2.0 ng m⁻³, respectively; n-alkanoic acids reached 6 ng m⁻³. The occurrence of nitrated-PAH of photochemical origin at trace extent (i.e. nitrated-fluoranthenes and nitropyrenes) has been also observed. Since the occurrence of OH radicals is required together with NO_x for the processes leading to the generation of 2-nitrofluoranthene and 2-nitropyrene would start, the detection of these nitrated species revealed the occurrence of photochemical processes in that region.     

HPLC-MSn to investigate the oxidative destruction pathway of aromatic sulfonate wastes

The article concerns the problem of destruction and remediation of industrial wastes containing aromatic sulfonates. The effects of an oxidation process induced by thermally activated persulfate in the degradation of 1,5-naphthalenedisulfonate (NDS) are investigated by the use of UV-Vis spectrophotometry, high performance liquid chromatography-mass spectrometry (HPLC-MS) and HPLC-MS(n) techniques. The results obtained indicated that thermal activation (80 degrees C) of a solution containing NDS and sodium persulfate in a molar ratio equal to 1 leads to the cleavage of the naphthalene structure. Estimated chemical oxygen demand (COD) indicates that when the excess of persulfate is equal to 100, NDS undergoes a mineralization of the order of 90%. A degradation pathway undergone by NDS when thermally activated in the presence of persulfate is proposed.     

Development and calibration of a portable radon sampling system for groundwater Rn activity concentration measurements

The assembling of a system for field sampling and activity concentration measurement of radon dissolved in groundwater is described. Special attention is given in presenting the calibration procedure to obtain the radon activity concentration in groundwater from the raw counting rate registered in a portable scintillation detector and in establishing the precision of the activity concentration measurements. A field procedure was established and the system tested during one year of monthly observations of ²²²Rn activity concentration in groundwater drawn from two wells drilled on metamorphic rocks exposed at Eastern São Paulo State, Brazil. The observed mean ²²²Rn activity concentrations are 374 Bq/dm³ in one well and about 1275 Bq/dm³ in the other one. In both wells the ²²²Rn activity concentrations showed a seasonal variation similar to variations previously reported in the literature for the same region.     

Is an environmental management system able to influence environmental and competitive performance? The case of the eco-management and audit scheme (EMAS) in the European union

The EMAS Regulation (Reg 761/01 EC) is EU scheme implemented by the European Commission since 1993 and it is for the implementation of an Environmental Management System (EMS) by any organization. The EMS was originally proposed by the European Commission and by the ISO as the frontrunner of a series of policy tools that enable companies to simultaneously pursue environmental objectives and competitive targets in a synergetic way.Based on the unique dataset of the EVER project, this paper investigates whether or not an EMS implemented within the EMAS Regulation has any effect on firm performance both from an environmental and a competitive point of view. Our econometric analysis shows the positive impact of a well-designed environmental management system on environmental performance and, as a consequence, on technical and organizational innovations. Effects on other competitive variables such as market performance, resource productivity and intangible assets are not strongly supported.