全文获取类型
收费全文 | 206篇 |
免费 | 3篇 |
国内免费 | 3篇 |
专业分类
安全科学 | 7篇 |
废物处理 | 13篇 |
环保管理 | 16篇 |
综合类 | 41篇 |
基础理论 | 42篇 |
污染及防治 | 57篇 |
评价与监测 | 20篇 |
社会与环境 | 14篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 2篇 |
2022年 | 5篇 |
2021年 | 5篇 |
2020年 | 5篇 |
2019年 | 6篇 |
2018年 | 11篇 |
2017年 | 9篇 |
2016年 | 13篇 |
2015年 | 18篇 |
2014年 | 12篇 |
2013年 | 21篇 |
2012年 | 9篇 |
2011年 | 13篇 |
2010年 | 10篇 |
2009年 | 11篇 |
2008年 | 8篇 |
2007年 | 10篇 |
2006年 | 7篇 |
2005年 | 15篇 |
2004年 | 10篇 |
2003年 | 5篇 |
2002年 | 4篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1992年 | 1篇 |
排序方式: 共有212条查询结果,搜索用时 31 毫秒
141.
Giovanna Armiento Fabio Bellatreccia Carlo Cremisini Giancarlo Della Ventura Elisa Nardi Renata Pacifico 《Environmental monitoring and assessment》2013,185(1):559-572
Beryllium is widely distributed in soils at low levels, but it can also occur naturally in higher concentrations in a variety of materials exploited for many industrial applications. Beryllium is also one of the most toxic natural elements and is known to be a human carcinogen. A concise account of the literature data on baseline concentrations of Be in soils illustrates the possibility of worldwide presence of areas with a high natural background concentration of Be (up to 300 mg/kg), the crustal abundance of which is generally estimated to be in the range 2–6 mg/kg. Nevertheless, the number of available data is rather limited in comparison with those about other toxic elements such as Pb, Cd and Cr. This has probably caused the choice of low values of concentration level as the reference for the definition of soil contamination: these values are not always realistic and are not applicable to large areas. As a case study, we report and analyse a diffuse, unusually high (up to 80 mg/kg, average approximately 20 mg/kg), natural occurrence of beryllium in loose and poorly consolidated pyroclastic layers related to the Pleistocene activity of the Vico volcano. Additionally, the analysis of Be leachability has been carried out, providing evidence of a not negligible mobility in contrast with the scarce data presented in the literature that usually indicate beryllium as an element with low mobility in oxidising surface environmental conditions. This research marks the beginning of a possible reappraisal of beryllium geochemical behaviour and background levels, providing more realistic reference values for risk assessment and land management. 相似文献
142.
Wegner Lilian Kinoshita Angela de Paiva Fabio Friol Guedes de Almeida Soares Pedro Negraes Santana William Pinto Edilson M. 《Journal of Material Cycles and Waste Management》2021,23(5):1831-1837
Journal of Material Cycles and Waste Management - The polysaccharide chitin (CHIT), extracted mainly from exoskeletons of crustaceans, can be obtained from shrimp fishery waste. It is the source of... 相似文献
143.
Fabio Gosetti Bianca Bolfi Ugo Chiuminatto Marcello Manfredi Elisa Robotti Emilio Marengo 《Environmental Chemistry Letters》2018,16(2):581-590
Alpha-cypermethrin is a broad-spectrum insecticide widely used in the treatment of rice crops, mainly commercialized as a CONTEST® formulation. The photodegradation of alpha-cypermethrin and of the commercial formulation has not yet been systematically investigated in paddy water under natural conditions. Here, paddy water solutions of alpha-cypermethrin and CONTEST® formulation at 5.0 mg L?1 were irradiated under simulated sunlight for 10 days. Hydrolysis experiments were carried out on the same solutions preserved in the dark. Analysis by ultra-high-performance liquid chromatography–tandem mass spectrometry was developed for the identification of photodegradation products. Results show that degradation of pure alpha-cypermethrin and the formulation counterpart produces both common and different photodegradation products. Five out eleven photodegradation products were identified for the first time, in particular three in the alpha-cypermethrin paddy water solution and four in the formulation. Our findings underline the importance of carrying out photodegradation experiments directly on the commercial formulation, since degradation products could be different from the pure insecticide. 相似文献
144.
Genetic and DNA-methylation changes induced by potassium dichromate in Brassica napus L 总被引:12,自引:0,他引:12
Labra M Grassi F Imazio S Di Fabio T Citterio S Sgorbati S Agradi E 《Chemosphere》2004,54(8):1049-1058
This study evaluated genetic and DNA methylation alteration induced by potassium dichromate in Brassica napus L. plants. Amplified fragment length polymorphism (AFLP) and selective amplification of polymorphic loci (SAMPL) tests revealed dose-related increases in sequence alterations in plantlets exposed to 10-200 mg/l potassium dichromate. Individual plantlets exposed to chromium under similar conditions showed different AFLP and SAMPL DNA profiles. These observations suggest random DNA mutation in response to potassium dichromate and argue against preferential sites for mutation. DNA methylation changes in response to chromium treatment were also evaluated. Two complementary approaches were applied: (i) immunolabelling, using a monoclonal antibody against 5-methylcytosine; and (ii) methylation-sensitive amplified polymorphism (MSAP). Immunolabelling showed cytosine-hypermethylation in the Brassica napus L. genome when plants were treated with potassium dichromate. MSAP analysis showed extensive methylation changes in CCGG-sequences, with the net result being genome-wide hypermethylation. These results showed a clear DNA alteration in plants as a response to chromium exposure and the effect was dose-dependent. DNA polymorphism detected by different markers supports the effectiveness of the use of these tools for the investigation of environmental toxicology and for evaluating the concentration of pollutants by DNA analysis in plants. 相似文献
145.
Radon levels were measured in 119 groundwater samples collected throughout the active volcanic area of Mt. Etna by means of a portable Lucas-type scintillation chamber. The measured activity values range from 1.8 to 52.7 Bq l(-1). About 40% of the samples exceed the maximum contaminant level of 11 Bq l(-1) proposed by the USEPA in 1991. The highest radon levels are measured in the eastern sector of the volcano, which is the seismically most active zone of the volcano. On the contrary the south-western sector, which is both seismically active and a site of intense magmatic degassing, display lower radon levels. This is probably due to the formation of a free gas phase (oversaturation of CO(2)) that strips the radon from the water. Comparison of the data gathered at Mt. Etna with those of other areas indicates that (222)Rn activity in groundwater is positively correlated with both the content of parent elements in the aquifer rocks and the temperature of the geothermal systems that interacts with the sampled aquifers. 相似文献
146.
Antonio?Piersanti Fabio?MonfortiEmail author Gabriele?Zanini 《Environmental Modeling and Assessment》2005,10(4):291-301
Three state of the art traffic–emission–dispersion models dealing with particulate matter have been tested and validated over
the Bologna metropolitan area with 2001 data and a future scenario has been developed in order to estimate expected PM concentrations
in 2010. The modelling system is composed by a traffic model (VISUM) evaluating vehicle fluxes as a function of mobility demand
and road network in the area, an emission model (Trefic) estimating pollutants emitted in atmosphere as a function of vehicle
fluxes amount and composition and of environmental conditions and a dispersion model (ADMS) evaluating PM concentrations on
the area, given the meteorological variables. The three models compose a cascade sequence and results of the previous one
feed the next one. PM concentrations computed by the model suite for the town of Bologna, in northern Italy, for the reference
period (January 2001) have been compared with air quality stations measurements suggesting the modelling system being especially
suitable for evaluating traffic induced PM. Qualitative and quantitative changes in the circulating vehicle fleet have been
supposed in order to obtain a realistic scenario for year 2010. Forecasted concentrations have been then compared with limits
fixed by current EU legislation for particulate matter. 相似文献
147.
Ivelize C. Tannure-Nascimento Fabio S. Nascimento José O. Dantas Ronaldo Zucchi 《Die Naturwissenschaften》2009,96(7):857-861
The capacity to distinguish colony members from strangers is a key component in social life. In social insects, this extends
to the brood and involves discrimination of queen eggs. Chemical substances communicate colony affiliation for both adults
and brood; thus, in theory, all colony members should be able to recognize fellow nestmates. In this study, we investigate
the ability of Dinoponera quadriceps workers to discriminate nestmate and non-nestmate eggs based on cuticular hydrocarbon composition. We analyzed whether cuticular
hydrocarbons present on the eggs provide cues of discrimination. The results show that egg recognition in D. quadriceps is related to both age and the functional role of workers. Brood care workers were able to distinguish nestmate from non-nestmate
eggs, while callow and forager workers were unable to do so.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
148.
A global evaluation of metabolic theory as an explanation for terrestrial species richness gradients 总被引:5,自引:0,他引:5
Hawkins BA Albuquerque FS Araujo MB Beck J Bini LM Cabrero-Sañudo FJ Castro-Parga I Diniz-Filho JA Ferrer-Castan D Field R Gómez JF Hortal J Kerr JT Kitching IJ León-Cortés JL Lobo JM Montoya D Moreno JC Olalla-Tárraga MA Pausas JG Qian H Rahbek C Rodríguez MA Sanders NJ Williams P 《Ecology》2007,88(8):1877-1888
We compiled 46 broadscale data sets of species richness for a wide range of terrestrial plant, invertebrate, and ectothermic vertebrate groups in all parts of the world to test the ability of metabolic theory to account for observed diversity gradients. The theory makes two related predictions: (1) In-transformed richness is linearly associated with a linear, inverse transformation of annual temperature, and (2) the slope of the relationship is near -0.65. Of the 46 data sets, 14 had no significant relationship; of the remaining 32, nine were linear, meeting prediction 1. Model I (ordinary least squares, OLS) and model II (reduced major axis, RMA) regressions then tested the linear slopes against prediction 2. In the 23 data sets having nonlinear relationships between richness and temperature, split-line regression divided the data into linear components, and regressions were done on each component to test prediction 2 for subsets of the data. Of the 46 data sets analyzed in their entirety using OLS regression, one was consistent with metabolic theory (meeting both predictions), and one was possibly consistent. Using RMA regression, no data sets were consistent. Of 67 analyses of prediction 2 using OLS regression on all linear data sets and subsets, two were consistent with the prediction, and four were possibly consistent. Using RMA regression, one was consistent (albeit weakly), and four were possibly consistent. We also found that the relationship between richness and temperature is both taxonomically and geographically conditional, and there is no evidence for a universal response of diversity to temperature. Meta-analyses confirmed significant heterogeneity in slopes among data sets, and the combined slopes across studies were significantly lower than the range of slopes predicted by metabolic theory based on both OLS and RMA regressions. We conclude that metabolic theory, as currently formulated, is a poor predictor of observed diversity gradients in most terrestrial systems. 相似文献
149.
This paper aims to assess the effectiveness of the so-called ‘Eco-Management and Audit Scheme (EMAS) cluster approach’ when applied to environmental policies, by focusing on the case history of the industrial paper production cluster located in the Province of Lucca (Italy). The Lucca cluster represents approximately 20% of Italian paper production, and Italy is the fourth leading paper producer in Europe. In the last 10 years, environmental policies have been developed under the common ‘umbrella’ of a strong public and private partnership based on stakeholder networking within the application of the EU EMAS Regulation. This article evaluates the outcome of such an approach, by comparing the environmental performance indicators for the Lucca’s paper industry using data collected from more than 40 plants before and after the adoption of this voluntary tool. The results show considerable improvements for many environmental performance indicators, consistently with the implementation of the cluster approach. 相似文献
150.
Fabio Ricci Roberto Cenciarini Alessandro Lorenzi Giorgio Famiglini Elisabetta Pierini Achille Cappiello 《Chemistry and Ecology》2016,32(1):88-102
The aim of this study was to monitor for the first time the oligosaccharide pattern in the northwestern Adriatic Sea. Oligosaccharides are components of the low-molecular-weight fraction of dissolved organic matter (DOM). They perform an important ecological function in the microbial loop prompting substrates for bacterial degradation. In particular, our investigation focused on maltooligosaccharides (glucose α 1–4 linked). The analyses were carried out using a dialysis-charcoal column sorption pre-concentration method, followed by liquid chromatography-tandem mass spectrometry analyses with a triple quadrupole mass spectrometer operating in multiple reaction monitoring mode. During the study period, the concentration of maltooligosaccharides with a low degree of polymerisation (ranging from maltose to maltotetraose) was higher than other maltooligosaccharides (maltopentaose and maltoeptaose) and all together they reached their highest concentration in June. This concentration was temporally shifted from a long period of diatom bloom (from January to April). Furthermore, the annual maltooligosaccharide trend was monitored together with several chemical, physical and biological parameters to investigate their potential role on the maltooligosaccharide accumulation. Our results suggested that the maltooligosaccharide accumulation could be related to the water column stratification. 相似文献