Effects of sewage sludge amendments on pesticide sorption and leaching through undisturbed Mediterranean soils

The Gharb region in Morocco is an important agricultural zone where soils receive pesticide treatments and organic amendments to increase yields. The groundwater aquifer in the Gharb region is relatively shallow and thus vulnerable. The objective of this work was to study the influence of organic amendments on diuron, cyhalofop-butyl and procymidone leaching through undisturbed soil columns. Two soils were sampled from the Gharb region, a Dehs (sandy soil) and a R'mel (loamy clay soil). Following elution (124.5 mm), the amount of pesticide residues in the leachates of the sandy soil (0.06-0.21 %) was lower than in those of the loamy clay soil (0.20-0.36 %), which was probably due to preferential flow through the loamy clay soil. The amount of procymidone leached through the amended soil columns was greater than the control for the sandy soil only. The organic amendments did not significantly influence diuron and cyhalofop-butyl leaching in either of the soils. The application of organic amendments affected the amounts of dissolved organic matter (DOM) eluted and thus pesticide leaching as a function of soil-type. Nevertheless, in some case, the formation of pesticide-DOM complexes appeared to promote pesticide leaching, thus increasing groundwater contamination risks.     

Hidden demographic impacts of fishing and environmental drivers of fecundity in a sea turtle population

Fisheries bycatch is a critical threat to sea turtle populations worldwide, particularly because turtles are vulnerable to multiple gear types. The Canary Current is an intensely fished region, yet there has been no demographic assessment integrating bycatch and population management information of the globally significant Cabo Verde loggerhead turtle (Caretta caretta) population. Using Boa Vista island (Eastern Cabo Verde) subpopulation data from capture–recapture and nest monitoring (2013–2019), we evaluated population viability and estimated regional bycatch rates (2016–2020) in longline, trawl, purse-seine, and artisanal fisheries. We further evaluated current nesting trends in the context of bycatch estimates, existing hatchery conservation measures, and environmental (net primary productivity) variability in turtle foraging grounds. We projected that current bycatch mortality rates would lead to the near extinction of the Boa Vista subpopulation. Bycatch reduction in longline fisheries and all fisheries combined would increase finite population growth rate by 1.76% and 1.95%, respectively. Hatchery conservation increased hatchling production and reduced extinction risk, but alone it could not achieve population growth. Short-term increases in nest counts (2013–2021), putatively driven by temporary increases in net primary productivity, may be masking ongoing long-term population declines. When fecundity was linked to net primary productivity, our hindcast models simultaneously predicted these opposing long-term and short-term trends. Consequently, our results showed conservation management must diversify from land-based management. The masking effect we found has broad-reaching implications for monitoring sea turtle populations worldwide, demonstrating the importance of directly estimating adult survival and that nest counts might inadequately reflect underlying population trends.     

Green construction for low-carbon cities: a review

Environmental Chemistry Letters - The construction industry is a major user of non-renewable energy and contributor to emission of greenhouse gases, thus requiring to achieve net-zero carbon...     

Strategies to save energy in the context of the energy crisis: a review

Environmental Chemistry Letters - New technologies, systems, societal organization and policies for energy saving are urgently needed in the context of accelerated climate change, the Ukraine...     

Optimizing hydrogen production by alkaline water decomposition with transition metal-based electrocatalysts

Burning fossil fuels account for over 75% of global greenhouse gas emissions and over 90% of carbon dioxide emissions, calling for alternative fuels such as hydrogen. Since the hydrogen demand could reach 120 million tons in 2024, efficient and large-scale production methods are required. Here we review electrocatalytic water splitting with a focus on reaction mechanisms, transition metal catalysts, and optimization strategies. We discuss mechanisms of water decomposition and hydrogen evolution. Transition metal catalysts include alloys, sulfides, carbides, nitrides, phosphides, selenides, oxides, hydroxides, and metal-organic frameworks. The reaction can be optimized by modifying the nanostructure or the electronic structure. We observe that transition metal-based electrocatalysts are excellent catalysts due to their abundant sources, low cost, and controllable electronic structures. Concerning optimization, fluorine anion doping at 1 mol/L potassium hydroxide yields an overpotential of 38 mV at a current density of 10 mA/cm². The electrocatalytic efficiency can also be enhanced by adding metal atoms to the nickel sulfide framework.

     

Planting trees to combat global warming

Environmental Chemistry Letters -     

Appraisal of the groundwater balance components from multi-remote sensing datasets in a semi-arid region

Semi-arid regions across the globe are fronting water crises, signaling a challenge to ensure future water security. Given the high inter-seasonal rainfall variability and unrestrained groundwater extraction, the precise quantification of groundwater flow components in an aquifer system is a priority. To address this challenge, we used high-resolution remote sensing (RS) data (Landsat and IRS) and GIS modeling (SEBAL, ArcCN) to spatially quantify major groundwater balance (GWB) components, viz., evapotranspiration (ET), rainfall recharge (R), surface runoff (Q), groundwater extraction (PG), irrigation return flow (IRF), and ultimately changes in groundwater storage (ΔS) in a small semi-arid crystalline representative watershed. Results show that a total of ~?230 mm of groundwater is extracted during 2008–2009, creating a negative impact on the groundwater resource, which is further enhanced by limited recharge and high ET. A decrease of approximately 65 mm in groundwater storage is observed in a single hydrological year, and given a very low specific yield, this decrease will introduce large water level decline. The study establishes that declining groundwater level in the watershed is a direct result of over-extraction, and owing to this scenario, efficient irrigation and land use policies are suggested as potential approaches to minimize extraction specifically in the dry season. Our methodology provides a systematic assessment of vital GWB components at a high spatial resolution and an insight on various sustainable mitigation methods. This methodology is useful in the planning and management of groundwater resources, particularly in water-stressed areas.     

Multimarker approach analysis in common carp Cyprinus carpio sampled from three freshwater sites

The aim of this study is to assess the response of a multimarker approach in common carp Cyprinus carpio sampled from three Tunisian dam lakes selected according to different environmental and ecological characteristics. Glutathione-S-transferase (GST) activity was analyzed in carp liver and used as a phase II detoxification enzyme, hepatic metallothionein content (MTs) was used as a metallic stress indicator, and cholinesterase activities were analyzed in muscle and brain and used as neurotoxicity biomarker. Micronucleus frequency test (MN) as a genotoxicity marker. GST and MT levels showed an increase in fish from the Bir Mcherga site and a decrease in Sidi Saâd site with respect to fish from Nebhana site. Results showed a strong inhibition of cholinesterase activities in fish from Bir Mcherga and Sidi Saâd sites compared to Nebhana site. Relatively high level of MN is reported specially in fish blood from the Bir Mcherga site.     

Evaluation of the host-specificity and prevalence of enterococci surface protein (esp) marker in sewage and its application for sourcing human fecal pollution

The suitability of the enterococci surface protein (esp) marker to detect human fecal pollution was evaluated by testing 197 fecal samples from 13 host groups in Southeast Queensland, Australia. Overall, this marker was detected in 90.5% of sewage and septic system samples and could not be detected in any fecal samples from 12 animal host groups. The sensitivity of the esp primer to detect the human-specific esp marker in sewage and septic samples was 100 and 67%, respectively. The overall specificity of this marker to distinguish between human and animal fecal pollution was 100%. Its prevalence in sewage was also determined by testing samples from the raw sewage, secondary effluent, and treated effluent of a sewage treatment plant (STP) over five consecutive days. Of the 15 samples tested, 12 (80%) were found to be positive for this marker. In contrast, it was not found in three samples from the treated effluent and these samples did not contain any culturable enterococci. The PCR limit of detection of this marker in freshwater samples was up to dilution 1 x 10(-4) and the number of culturable enterococci at this dilution was 4.8 x 10(1) +/- 7.0 x 10 degrees colony forming unit (CFU). The utility of this marker was evaluated by testing water samples from three non-sewered catchments in Pine Rivers in Southeast Queensland. Of the 13 samples tested, eight were positive for this marker with the number of enterococci ranging between 1.8 x 10(3) to 8.5 x 10(3) CFU per 100 mL of water. Based on the results, it can be concluded that the esp marker appears to be sewage specific and could be used as a reliable marker to detect human fecal pollution in surface waters in Southeast Queensland, Australia.     

The impact of coastal flooding on conservation areas: A study of the Clyde Estuary, Scotland

This study examines the impact of flooding on land of high conservation value located along part of the southern shoreline of the River Clyde Estuary in western Scotland. This paper hypothesizes that, over the next 50 years, the frequency and extent of coastal flooding will increase due to the gradual effect of global warming and the consequent rise in sea-level and increase in storminess. It is argued that because of the great cost of constructing new flood defence systems it will not be possible to protect all land areas to an equal extent from flooding. A means of ranking different land use will be necessary so that society can make a rational judgement concerning which sections of coastline will be worth protecting. This study provides a methodology that combines an objective ranking of conservation areas using non-economic indicators with a GIS model of flood potential, and permits accurate forecasts of flood losses to conservation areas of different ecological value. The conservation case study used in this paper proposes the use of an ecological weighting value based on five ecological variables each of 10 categories. Tables and maps identify the sites that have been highlighted as consisting of the most ‘valuable’ conservation sites. The methodology makes extensive use of geographical information systems (GIS) to model the predicted areas of flooding and to calculate conservation weighting values of the land areas.