Enhancing the performance of data-driven models for monthly reservoir evaporation prediction

Environmental Science and Pollution Research - The accuracy level for reservoir evaporation prediction is an important issue for decision making in the water resources field. The traditional...     

Biological silicon nanoparticles improve Phaseolus vulgaris L. yield and minimize its contaminant contents on a heavy metals-contaminated saline soil

The synthesis of biological silicon nano-particles (Bio-Si-NPs) is an eco-friendly and low-cost method. There is no study focusing on the effect of Bio-Si-NPs on the plants grown on saline soil contaminated with heavy metals. In this study, an attempt was made to synthesis Bio-Si-NPs using potassium silica florid substrate, and the identified Aspergillus tubingensis AM11 isolate that separated from distribution systems of the potable water. A two-year field trial was conducted to compare the protective effects of Bio-Si-NPs (2.5 and 5.0 mmol/L) and potassium silicate (10 mmol/L) as a foliar spray on the antioxidant defense system, physio-biochemical components, and the contaminants contents of Phaseolus vulgaris L. grown on saline soil contaminated with heavy metals. Our findings showed that all treatments of Bio-Si-NPs and potassium silicate significantly improved plant growth and production, chlorophylls, carotenoids, transpiration rate, net photosynthetic rate, stomatal conductance, membrane stability index, relative water content, free proline, total soluble sugars, N, P, K, Ca²⁺, K⁺/Na⁺, and the activities of peroxidase, catalase, ascorbic peroxidase and superoxide oxide dismutase. Application of Bio-Si-NPs and potassium silicate significantly decreased electrolyte leakage, malondialdehyde, H₂O₂, O₂^??, Na⁺, Pb, Cd, and Ni in leaves and pods of Phaseolus vulgaris L. compared to control. Bio-Si-NPs were more effective compared to potassium silicate. Application of Bio-Si-NPs at the rate of 5 mmol/L was the recommended treatment to enhance the performance and reduce heavy metals content on plants grown on contaminated saline soils.     

Insight into the Adsorption Properties of Chitosan/Zeolite-A Hybrid Structure for Effective Decontamination of Toxic Cd (II) and As (V) Ions from the Aqueous Environments

Chitosan/zeolite-A hybrid structure (CS/Z.A) was synthesized and characterized as a multifunctional and environmental adsorbent for the Cd (II) and As (V) ions. The adsorption capacities of CS/ZA for Cd (II) and AS (V) are 170 mg/g and 125 mg/g, respectively which are higher values than several adsorbents in literature. The kinetic study demonstrates Pseudo-First-order behavior for the Cd (II) adsorption process and Pseudo-second order for the As (V) uptake reactions. The Cd (II) and As (V) uptake reactions follow the Freundlich equilibrium behavior with heterogeneous and multilayer adsorption properties. The kinetic and equilibrium studies in addition to the Gaussian energy {6.35 kJ/mol [Cd (II)] and 9.44 kJ/mol [As (V)]} demonstrate physical properties for the Cd (II) adsorption mechanism and more chemical behavior for the As (V) adsorption mechanism. The thermodynamic study declares exothermic, spontaneous, and favorable adsorption reactions for Cd (II) and As (V) by CS/Z.A composite. The CS/Z.A is of significant capacity for Cd (II) and As (V) ions in the existence of other competitive dissolved anions (PO₄^3?, NO₃^?, and SO₄^2?) and other metals [Zn (II), Co (II), and Pb (II)]. Finally, the CS/Z.A composite is a recyclable product and can be applied in effective Cd (II) and As (V) decontamination processes for five runs.

     

Forest protected area governance in Bangladesh:a focus on the legal and policy framework

In the context of renewed interest in collaboration in natural resource management,the collaborative governance approach has lately been introduced to the forest Protected Areas(PAs)in Bangladesh.The adoption of this co-management approach is seen as an attempt to influence the governance process towards a transformation from the conventional custodian system to a more participatory management regime.Recognition of rights and responsibilities,effective participation,and equitable distribution of benefits amongst the key stakeholders working under a facilitative policy and legal framework are believed to address the broader goals of sustainable development Notwithstanding the resurgence of interest in governance of forest PAs through the co-management approach,academic research on the subject remains limited.This article attempts to review selected key information and milestones on the forest PAs governance with special reference to the major policies and legal documents.With a brief introductory section,this article focuses on the genesis and selected major features of the Forest PAs in the country.The discussion then dwells on the policy and legal framework and provides a critique on its relevance for promoting community participation.The existing institutional arrangements for community engagement in protected area governance are also analyzed in light of the national and international commitment and policy obligations on the part of the country.The salient observations and key findings of the study include the following:(1)despite its limitations,comanagement as concept and practice has gradually taken roots in Bangladesh;(2)the degree and level of active community participation remain low and limited,and there is also clear weakness in conscientizing and orientating the local community on the key legal and policy issues related to PA governance in the country;and(3)policy makers,practitioners,and other local stakeholders related to PA governance need to be oriented on international commitment and national de     

The contribution of mediated oxidation mechanisms in the electrolytic degradation of cyanuric acid using diamond anodes

In this work, the contribution of mediated oxidation mechanisms in the electrolytic degradation of cyanuric acid using boron-doped diamond(BDD) anodes was investigated in different electrolytes. A complete mineralization of cyanuric acid was obtained in Na Cl;however lower degrees of mineralization of 70% and 40% were obtained in Na2SO4 and Na Cl O4, respectively. This can be explained by the nature of the oxidants electrogenerated in each electrolyte. It is clear that the contribution of active chlorine(Cl2, HCl O, Cl O-)electrogenerated from oxidation of chlorides on BDD is much more important in the electrolytic degradation of cyanuric acid than the persulfate and hydroxyl radicals produced by electro-oxidation of sulfate and water on BDD anodes. This could be explained by the high affinity of active chlorine towards nitrogen compounds. No organic intermediates were detected during the electrolytic degradation of cyanuric acid in any the electrolytes, which can be explained by their immediate depletion by hydroxyl radicals produced on the BDD surface. Nitrates and ammonium were the final products of electrolytic degradation of cyanuric acid on BDD anodes in all electrolytes. In addition, small amounts of chloramines were formed in the chloride medium. Low current density(≤ 10 m A/cm2) and neutral medium(p H in the range 6–9) should be used for high efficiency electrolytic degradation and negligible formation of hazardous chlorate and perchlorate.     

Mathematical modeling of sustainable development goals of India agenda 2030: a Neutrosophic programming approach

Environment, Development and Sustainability - Since 2015, the United Nations sustainable development goals (SDGs) agenda 2030 has been designed with 17 goals, 169 targets, and 232 unique indicators...     

Toward environmental sustainability: how do urbanization,economic growth,and industrialization affect biocapacity in Brazil?

The South American country Brazil is one of the richest countries in terms of natural resources, representing 14 percent of the world’s total biocapacity. However, the biocapacity (biosphere’s ability to generate resources and sequester waste) per capita in Brazil has shown a massive decline over the last five decades, while economic growth and urbanization have rapidly increased for the same period. Brazil is one of the largest creditors of biocapacity to the world, and biocapacity loss in Brazil can lead to devastating environmental consequences. Therefore, this work empirically investigates the influence of urbanization, economic growth, and industrialization on biocapacity controlling human capital from 1961 to 2016 in Brazil. The Bayer and Hack cointegration test, the Autoregressive Distributed Lag (ARDL) technique, and Hacker and Hatemi-J (J Econ Stud 39:144–160, 2012) causality tests are employed. The findings unfolded a U-shaped relationship between economic growth and biocapacity, evidencing that economic growth reduces biocapacity, but after achieving a threshold level, it promotes biocapacity. Urbanization has a negative relationship with biocapacity per capita, indicating that urbanization is a significant driver of the biocapacity loss in Brazil. Further, urbanization and economic growth Granger cause biocapacity. Lastly, relevant policy implications are proposed to overcome the reduction in biocapacity.

     

Comparative assessment of respiratory and other occupational health effects among elementary workers

Objective. This study was conducted to assess hazards faced by elementary workers. Methods. A questionnaire survey and a respiratory function test (spirometry) were carried out on 150 respondents. Results. Major hazards identified related to sharp objects, heavy weight lifting, thermally harsh conditions, working at height, whole body vibration, chemicals, pathogens, increased noise levels and confined space entry. Workers suffered from upper and lower respiratory disorder symptoms, digestive problems, optical and musculoskeletal issues, etc. Spirometric measurement showed obstructive lung disorders to be highest among construction workers (CW) (48%) followed by sanitation workers (SW) (32%) and solid waste pickers (SWP) (28%). Restrictive lung pattern was dominant among SW (56%) followed by SWP (46%) and CW (42%). The observed FEV₁/FVC in diseased SWP, SW and CW ranged from 51 to 96%, from 52 to 98% and from 31 to 99% respectively while observed mean FEV₁ was 2.15, 1.79 and 1.70 L, respectively. Conclusion. The study findings show that occupational exposure can significantly influence respiratory system impairment and contribute to other ailments among elementary workers. The study recommends use of appropriate protective equipment and regular medical examination for early recognition of any health risk so that timely interventions for effective management may be undertaken.     

Pb in medicinal plants from Jordan

This is the first report on Pb in medicinal herbs from Jordan. Medicinal herbs may present a health risk due to the presence of toxic metals. Seventy-nine dry medicinal plant samples were collected from herbalist shops in Jordan. The plants were digested with acids and analyzed for total Pb concentration using atomic absorption spectrometry. Mean Pb concentration was 15.9 μg/g on a dry weight basis. Our results show that Pb concentrations in Jordan medicinal plants are higher than published data in other countries. The highest level of 33.4 μg Pb/g was determined in Inula viscosa, and the lowest level of 3.0 μg Pb/g was found in Nigella sativa. Calculated daily intakes of Pb of most analyzed herbs were high; most of them are higher than recommended values by the world health organization (WHO). Fortunately, the herbs that contain the highest Pb levels are the less commonly used medicinal herbs in Jordan. The mean Pb levels in the most commonly, commonly and less commonly used herbs in Jordan are 13.9, 13.1 and 16.9 μg Pb/g, respectively. The average dietary intake of Pb through a mixture of these medicinal herbs consumption, assuming 5.0 g herbs is consumed daily, is 79.5 μg Pb/day, which is higher than the maximum daily limit allowed by WHO. We conclude that most of the medicinal plants consumed in Jordan contain significant amount of Pb, and therefore, people of Jordan should not consume large amounts of these herbs.