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631.
Volatile organic compounds (VOCs) have been determined to be human risk factors in urban environments, as well as primary contributors to the formation of photochemical oxidants. Ambient air quality measurements of 54 VOCs including hydrocarbons, halogenated hydrocarbons and carbonyls were conducted in or near 13 urban locations in the United States during September 1996 to August 1997. Air samples were collected and analyzed in accordance with US Environmental Protection Agency-approved methods. The target compounds most commonly found were benzene, toluene, xylene and ethylbenzene. These aromatic compounds were highly correlated and proportionally related in a manner suggesting that the primary contributors were mobile sources in all the urban locations studied. Concentrations of total hydrocarbons ranged between 1.39 and 11.93 parts per billion, by volume (ppbv). Ambient air levels of halogenated hydrocarbons appeared to exhibit unique spatial variations, and no single factor seemed to explain trends for this group of compounds. The highest halogenated hydrocarbon concentrations ranged from 0.24 ppbv for methylene chloride to 1.22 ppbv for chloromethane. At participating urban locations for the year of data considered, levels of carbonyls were higher than the level of the other organic compound groups, suggesting that emissions from motor vehicles and photochemical reactions strongly influence ambient air concentrations of carbonyls. Of the most prevalent carbonyls, formaldehyde and acetaldehyde were the dominant compounds, ranging from 1.5-7.4 ppbv for formaldehyde, to 0.8-2.7 ppbv for acetaldehyde. 相似文献
632.
Mohamed El Alaoui 《International Journal of Green Energy》2020,17(11):644-651
ABSTRACT The energy consumed around the world and especially in Morocco is dominated by oil products. The latter; whether in the global or the national context; are mainly due to diesel, whose climate impacts are well established, suggesting the search for a greener alternative. Despite its virtues, biodiesel is struggling to impose itself for purely economic reasons. Thus, in order to offer a sustainable solution, while keeping in mind the unpredictable fluctuations (price, demand …). This work proposes a generalization of fuzzy goal programming into fully fuzzy goal programming and a relative application, where the aim is to have a final product at a competitive price. 相似文献
633.
Susana L. H. Rebelo A. Melo R. Coimbra M. Emília Azenha Mariette M. Pereira Hugh D. Burrows Mohamed Sarakha 《Environmental Chemistry Letters》2007,5(1):29-33
The photodegradation of the herbicides atrazine and ametryn with visible light in aerated neutral aqueous solutions and 5,
10, 15, 20-tetrakis (2,6-dichloro-3-sulfophenyl) porphyrin or 5, 10, 15, 20-tetrakis (4-sulfophenyl) porphyrin as sensitizers
are reported for the first time. Our findings show that the degradation percentage reached 30% for atrazine and 63% for ametryn.
The final photoproducts were characterized as dealkylated s-triazines. Photolysis of the pesticides in the presence of a singlet oxygen quencher showed only a minor contribution of
this type of mechanism, while a bimolecular quenching reaction between the triplet state of the sensitizer and the pesticides
is excluded by flash photolysis studies. It is proposed that the mechanism may involve the formation of a superoxide radical
anion from the triplet state of the sensitizer and molecular oxygen, followed by a radical decomposition pathway.
Selected article from 1st International Meeting on Photochemistry, Photocatalysis and Environmental Applications, Agadir,
2006, organised by Prof. Dr. Ait Ichou, University Ibn Zohr, Agadir, Morocco 相似文献
634.
Highly efficient photodegradation of the pesticide metolcarb induced by Fe complexes 总被引:1,自引:1,他引:1
Here we show the efficient photoinduced degradation of the pesticide metolcarb, in less than 400 min, using iron(III) aquacomplexes and 365 nm light. The degradation is mainly due to the formation of hydroxyl radical. It was complete when molecular oxygen was present. The analytical study gives evidence for the primary formation of several byproducts formed from 1) the scission of the O–C bond, 2) the hydroxylation of the aromatic moiety and 3) the attack of the two methyl groups. Under prolonged irradiation and in aerated solutions, efficient mineralization was evidenced by the study of total organic carbon evolution as a function of irradiation time. 相似文献
635.
636.
Remediation of heavy metal contaminated soils via integrated electrochemical processes 总被引:1,自引:0,他引:1
A.M.O. Mohamed 《Waste management (New York, N.Y.)》1996,16(8):741-747
The thrust of this study is to develop an in-situ method/technique capable of modifying the contaminated soil environment and maximizing contaminant extraction. Contaminated soils were compacted in electrokinetic cells to densities similar to natural field conditions. Conditioning fluids were used during the application of a direct current to solubilize the precipitated forms of heavy metals. Mobilization of contaminants as a function of time was quantified by analysing metal ion concentrations in the extracted effluents at both the anode and cathode and in the compacted specimens. For each conditioning fluid used, the removal efficiencies were evaluated based on both effluent and soil concentrations. 相似文献
637.
Kinetic adsorption of application of carbon nanotubes for Pb(Ⅱ) removal from aqueous solution 总被引:2,自引:0,他引:2
Nassereldeen A Kabbashi Muataz A Atieh Abdullah Al-Mamun Mohamed E S Mirghami MD Z Alam Noorahayu Yahya 《环境科学学报(英文版)》2009,(4)
The capability of carbon nanotubes (CNTs) to adsorb lead (Pb) in aqueous solution was investigated. Batch mode adsorption experiment was conducted to determine the effects of pH, agitation speed, CNTs dosage and contact time. The removal of Pb(Ⅱ) reached maximum value 85% or 83% at pH 5 or 40 mg/L of CNTs, respectively. Higher correlation coeffcients from Langmuir isotherm model indicates the strong adsorptions of Pb(Ⅱ) on the surface of CNTs (adsorption capacity Xm = 102.04 mg/g). The results indicates tha... 相似文献
638.
639.
Helen Carnaghan Catherine P. James Paul B. Charlesworth Marco Ghionzoli Susana Pereira Mohamed Elkhouli David Baud Paolo De Coppi Greg Ryan Prakesh S. Shah Mark Davenport Anna L. David Agostino Pierro Simon Eaton Gastroschisis Study Group 《黑龙江环境通报》2020,40(8):991-997